Through Quantum Dot to Quantum Crystal : Creation and Development of 2D, 3D Nanoparticle Crystal

• Project/Area Number: 16101003
• Research Category: Grant-in-Aid for Scientific Research (S)
• Allocation Type: Single-year Grants
• Research Field: Nanostructural science
• Research Institution: University of Hyogo
• Principal Investigator: KIMURA Keisaku University of Hyogo, 大学院・物質理学研究科, 教授 (70106160)
• Co-Investigator(Kenkyū-buntansha): MAKOSI Kenji 兵庫県立大学, 大学院・物質理学研究科, 教授 (10116098) ; 八尾 浩史 兵庫県立大学, 大学院・物質理学研究科, 准教授 (20261282) ; 佐藤 井一 兵庫県立大学, 大学院・物質理学研究科, 助教 (90326299)
• Co-Investigator(Renkei-kenkyūsha): YAO Hiroshi 兵庫県立大学, 大学院物質理学研究科, 准教授 (20261282) ; SATO Seiichi 兵庫県立大学, 大学院物質理学研究科, 助教 (90326299)
• Project Period (FY): 2004 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥110,630,000 (Direct Cost: ¥85,100,000、Indirect Cost: ¥25,530,000); Fiscal Year 2008: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000); Fiscal Year 2007: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000); Fiscal Year 2006: ¥21,190,000 (Direct Cost: ¥16,300,000、Indirect Cost: ¥4,890,000); Fiscal Year 2005: ¥56,160,000 (Direct Cost: ¥43,200,000、Indirect Cost: ¥12,960,000); Fiscal Year 2004: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
• Keywords: ナノ粒子結晶 / 量子サイズ効果 / 自己組織化超格子 / 金クラスター / ナノ粒子 / 単分子自己集積膜 / 自己集積超格子 / 量子結晶 / 超格子構造 / 自己集積膜

Research Abstract

表面を有機分子で覆い、精密に分子レベルで制御した水溶性の金、銀ナノ粒子を大量に合成し、これを材料にしてナノ粒子の結晶化をおこなった。結晶化条件の適切な選択により、また表面配位子の選択により各種形状の結晶や5回対称の結晶体を得ることができた。気液界面上に作製した高品位の粒子結晶において、表面プラズモン吸収の尖鋭化現象を発見した。これら無歪みのナノ粒子結晶において、電子線回折、X線回折を用いて、結晶全体にわたり原子が配向していることを明らかにした。

Research Products

• [Journal Article] Kimura : Charge Transport Behavior of N-(2-Mercaptopropionylglycine)Protected Gold Clusters with Temperature (2009)
  • Author(s): A. S. Nair, K. Kimura
  • Journal Title: Langmuir 25 Pages: 1750-1756
  • Peer Reviewed
• [Journal Article] Charge transport behavior of N-(2-Mercaptopropionyl glycine)-protected gold clusters with temperature (2009)
  • Author(s): A. Sreekumaran Nair, Keisaku Kimura
  • Journal Title: Langmuir 25 Pages: 1750-1756
  • Peer Reviewed
• [Journal Article] Organic Styiyl Dye Naaoparticles : Synthesis and Unique Spectroscopic Properties (2009)
  • Author(s): Hiroshi Yao, Minami Yamashita, Keisaku Kimura
  • Journal Title: Langmuir 25 Pages: 1131-1137
  • Peer Reviewed
• [Journal Article] Chiral Functionalization of Optically Inactive Monolayer-Protected Silver Nanoclusters by Chiral Ligand-Exchange Reactions (2008)
  • Author(s): N. Nishida, H. Yao, K. Kimura
  • Journal Title: Langmuir 24 Pages: 2759-2766
  • Peer Reviewed
• [Journal Article] Fluorescent Gold Nanoparticle Superlattices (2008)
  • Author(s): N. Nishida, E. S. Shibu, H. Yao, T. Oonishi, K. Kimura, T. Pradeep
  • Journal Title: T. Pradeep, Adv. Mater. 20 Pages: 4719-4723
  • Peer Reviewed
• [Journal Article] Investigation of Charge Transport in Mercaptosuccinic Acid-passivated Gold Clusters (2008)
  • Author(s): A. S. Nair, K. Kimura
  • Journal Title: J. Chem. Phys 129
  • Peer Reviewed
• [Journal Article] Asymmetric Transfonnation of Monolayer-Protected Gold Nanoclustersvia Chiral Phase Transfer (2008)
  • Author(s): Hiroshi Yao, Toshiyuki Fukui, Keisaku Kimura
  • Journal Title: J. Phys. Chem. C 112 Pages: 16281-16285
  • Peer Reviewed
• [Journal Article] Investigation of charge transport in mercaptosuccinic acid-passivated gold clusters (2008)
  • Author(s): A. Sreekumaraa Nair, Keisaku Kimura
  • Journal Title: J. Chem. Phys. 129
  • Peer Reviewed
• [Journal Article] Fluorescent Gold Nanoparticle Superlatdces (2008)
  • Author(s): Naoki Nishida, Edakkattuparambil S. Shibu, Hiroshi Yao, Tsuguo Oonishi, Keisaku Kimura, Thalappil Pradeep
  • Journal Title: Adv. Mater. 20 Pages: 4719-4723
  • Peer Reviewed
• [Journal Article] Proof of Partial Flattening of Meso Substituents in Tetracationic Porphyrin at a Mica/Solution Interface (2008)
  • Author(s): Hiroshi Yao, Shogo Kobayashi, Keisaku Kimura
  • Journal Title: Chem. Lett 37 Pages: 594-595
  • NAID: 10021081029
  • Peer Reviewed
• [Journal Article] Chiral Functionalization of Optically Inactive Monolayer-Protected Silver Nanoclusters by Chiral Ligand-Exchange Reactions (2008)
  • Author(s): Naoki Nishida, Hiroshi Yao, Keisaku Kimura
  • Journal Title: Langmuir 24 Pages: 2759-2766
  • Peer Reviewed
• [Journal Article] Surface Charge Driven Size Evolution during Formation of Self-assembled Nanostructures from Discrete Hydrophilic Silver Nanoparticles (2007)
  • Author(s): Y. Yang, K. Kimura
  • Journal Title: Nanotechnology 18
  • Peer Reviewed
• [Journal Article] Three-Dimensional Gold Nanoparticle Superlattices : Structures and Optical Absorption Characteristics (2007)
  • Author(s): T. Oonishi, S. Sato, H. Yao, K. Kimura
  • Journal Title: J. Appl. Phys 101
  • Peer Reviewed
• [Journal Article] Three-dimensional gold nanoparticle superlattices:Stuctures and optical a bsorption characteristics (2007)
  • Author(s): T.Oonishi, S.Sato, H, Yao, and K.Kimura
  • Journal Title: J.Appl.Phys 101 Pages: 114314-114318
  • Peer Reviewed
• [Journal Article] Chemometric and Microscopic Analyses for the Size Growth of Monolayer-Protected Gold Nanoparticles during Their Superlattice Formation (2007)
  • Author(s): Hiroshi Yao, Keita Moriyama, Keisaku Kimura
  • Journal Title: Langmuir 23 Pages: 13151-13157
  • Peer Reviewed
• [Journal Article] Surfae charge driven size evolution during for mation of self-assembled anostructures from discrete hydropilic silcer nanoparticles (2007)
  • Author(s): Yang Yang, Keisaku Kimura
  • Journal Title: Nanotechnology 18
  • Peer Reviewed
• [Journal Article] Synthesis and Chiroptical Study of D/L-Penicillamine-Capped Silver Nanoclusters (2007)
  • Author(s): Naoki Nishida, Hiroshi Yao, Tomoyasu Ueda, Akito Sasaki, and Keisaku Kimura
  • Journal Title: Chem.Mater 19 Pages: 2831-2841
  • Peer Reviewed
• [Journal Article] Chiroptical Responses of D-/L-Penicillamine-Capped Gold Clusters under Perturbations of Temerature Change and Phase Transfer (2007)
  • Author(s): Hiroshi Yao, Toshiyuki Fukui, Keisaku Kimura
  • Journal Title: J.Phys.Chem.C 111 Pages: 14968-14976
  • Peer Reviewed
• [Journal Article] Atomic Aligriment in Panicle Crystals of Au Nanoparticles Grown at an Air/Water Interface (2007)
  • Author(s): S.Sato, S.Wang, K.Kimura
  • Journal Title: J.Phys.Chem.C 111 Pages: 13367-13371
  • Peer Reviewed
• [Journal Article] ナノ粒子からナノ粒子量子結晶へ (2007)
  • Author(s): 木村 啓作
  • Journal Title: 化学と工業 60 Pages: 116-119
  • NAID: 10018521945
  • Peer Reviewed
• [Journal Article] Organic Nnoparticles of Cyanine in aqueous Solution (2007)
  • Author(s): Zhong-min Ou, Hiroshi Yao, Keisaku Kimura
  • Journal Title: Bull.Chem.Soc.Jpn 80(2) Pages: 295-302
• [Journal Article] Superlattice Formation from Polydisperse AgNanoparticles by a Vapor Diffusion Method (2006)
  • Author(s): Y. Yang, S. Liu, K. Kimura
  • Journal Title: Angew. Chem. Int. Ed 45 Pages: 5662-5665
  • Peer Reviewed
• [Journal Article] Fivefold Symmetry in Superlattices of Monolayer-Protected Gold Nanoparticles (2006)
  • Author(s): H. Yao, T. Minami, A. Hori, M. Koma, K. Kimura
  • Journal Title: J. Phys. Chem. B 110 Pages: 14040-14045
  • Peer Reviewed
• [Journal Article] FiveFold Symmetry in Superlat of Mlnolayer-Protected Gold Nanoparticles (2006)
  • Author(s): H.Yao, T.Minami, A.Hori, M.Koma, Keisaku Kimura
  • Journal Title: J.Phys.Chem. B110 Pages: 14040-14045
• [Journal Article] Optical Evaluation of Silicon Nanoparticles Prepared by Arc Discharge Method in Liquid Nitrogen (2006)
  • Author(s): M.Kobayasi, S.Liu, S.Sato, H.Yao, K.Kimura
  • Journal Title: Jpn.J.Apple.Phys. 45 Pages: 6146-6152
  • NAID: 40007382098
• [Journal Article] Superlattice Formation from Pokydisperse Ag Nanoparticles by a Vapor diffusion Method (2006)
  • Author(s): Yang Yang, Shu-Man Liu, Keisaku Kimura
  • Journal Title: Angewandte Chemie Int.Ed. 45 Pages: 5662-5665
• [Journal Article] Cyclodextrin as a capturing agent for redundant surfactants on Ag nanoparticle in phase transfer process (2006)
  • Author(s): Yang Yang, Shu-Man Liu, Keisaku Kimura
  • Journal Title: Colloids and Surfaces 290(1-3) Pages: 143-149
• [Journal Article] Highly Ordered Superlattice from Polydisperse Ag Nanoparticles : A Comparative Study of Fractionation and Self-Correction (2006)
  • Author(s): Yang Yang, Keisaku Kimura
  • Journal Title: J.Phys.Chem. B110(48) Pages: 24442-24449
• [Journal Article] Preparation of Ag Nanoparticle Assemblies at Air-Water Interface by Electrostatic Interaction (2006)
  • Author(s): Yang Yang, Keisaku Kimura
  • Journal Title: Chem.Lett. 35 Pages: 296-297
  • NAID: 10017273450
• [Journal Article] Stepwise Size-selective Extraction of Aqueous Silver Nanoparticles by a Series of Organic Solvents (2006)
  • Author(s): Yang Yang, Keisaku Kimura
  • Journal Title: Chem.Lett. 35 Pages: 462-463
  • NAID: 10018126063
• [Journal Article] Synthesis of Silicon Nanowires and Nanoparticles by Arc-Discharge in Water (2005)
  • Author(s): S. Liu, M. Kobayashi, S. Sato, K. Kimura
  • Journal Title: Chem. Commun. Pages: 4690-4692
  • Peer Reviewed
• [Journal Article] Large Optical Activity of Gold Nanocluster Enantiomers Induced by a Pair of Optically Active Penicillamines (2005)
  • Author(s): H. Yao, K. Miki, N. Nishida, A. Sasaki, K. Kimura
  • Journal Title: J. Am. Chem. Soc. 127 Pages: 15536-15543
  • Peer Reviewed
• [Journal Article] 2D and 3D ordered structure of silver nanoparticles from hydrosol (2005)
  • Author(s): M.Watanabe, S.Sato, H.Yao, K.Kimura
  • Journal Title: Int.J.Mod.Phys.B 19 Pages: 2699-2703
• [Journal Article] Large Optical Activity of Gold Nanocluster Enantiomers Induced by a Pair of Optically Active Penicillamines (2005)
  • Author(s): H.Yao, K.Miki, N.Nishida, A.Sasaki, K.Kimura
  • Journal Title: J.Amer.Chem.Soc. 127 Pages: 15536-15543
• [Journal Article] Synthesis of silicon nanowires and Nanoparticles by arc-discharge in water (2005)
  • Author(s): S.Liu, M.Kobayashi, S.Sato, K.Kimura
  • Journal Title: Chem.Commun. Pages: 4690-4692
• [Journal Article] Synthesis of Well-dispersed CuI Nanoparticles from an Available Solution Precursor (2005)
  • Author(s): Y.Yang, S.Liu, Keisaku Kimura
  • Journal Title: Chem.Lett. 34 Pages: 1158-1159
  • NAID: 10016649367
• [Journal Article] Magic-Numbered Aun Clusters Protected by Glutatione Monolayers (n=18,21,25,28,32,39) : Isolation and Spectroscopic Characterization (2004)
  • Author(s): Y.Negishi, Y.Takasugi, S.Sato, H.Yao, K.Kimura, T.Tsukuda
  • Journal Title: J.Amer.Chem.Soc. 126(1) Pages: 6518-6519
• [Journal Article] Inclusion-Water-Clusters in a Three Dimentional Superlattice of Gold Nanoparticles (2004)
  • Author(s): S.Wang, H.Yao, S.Sato, K.Kimura
  • Journal Title: J.Amer.Chem.Soc. 126(3) Pages: 7438-7439
• [Journal Article] Interparticle Spacing Control in the Superlattices of Carboxylic Acid-Capped Gold Nanoparticles by Hydrogen-Bonding Mediation (2004)
  • Author(s): H.Yao, H.Kojima, S.Sato, K.Kimura
  • Journal Title: Langmuir 20 Pages: 10317-10323
• [Journal Article] Molecular orbital cluster calculation study of electron correlation and local latice instability in La2-2xSr1+2xMn7
  • Author(s): S.Miyaki, S.Uzuhara, K.Terada, K.Makoshi, H.Koizumi
  • Journal Title: Phys.Rev. B71(in press)
• [Presentation] Gold Nanoparticle Superlattices : Self-assembled at a Solid/Liquid Interface (2008)
  • Author(s): H. Yao, M. Kurokami, K. Kimura
  • Organizer: 34th Intemational Conference on Micro and Nano Engineering
  • Place of Presentation: Athens, Greece
  • Year and Date: 2008-09-16
• [Presentation] Influence of Achiral/Chiral Phase Transfer on the Chiroptical Response of Ligand-Protected Gold Nanoclusters (2008)
  • Author(s): H. Yao (Invited talk), T. Fukui, K. Kimura
  • Organizer: Intemational Symposium on Monolayer-Protected Clusters ; ISMPC08
  • Place of Presentation: Jyvaskyla, Finland
  • Year and Date: 2008-09-13
• [Presentation] Chiral Functionalization of Monolayer-Protected Silver Nanoclusters by Chiral Ligand-Exchange Reactions (2008)
  • Author(s): N. Nishida, H. Yao, K. Kimura
  • Organizer: Nano Ostrava 2008
  • Place of Presentation: Cheko, Ostrava
  • Year and Date: 2008-09-02
• [Presentation] Atomic Alignment over Superlattices of Water Soluble Au Nanoparticles (2008)
  • Author(s): Keisaku Kimura, Seiichi Sato, Sufua Wang
  • Organizer: Nano Ostrava 2008
  • Place of Presentation: Cheko, Ostrava
  • Year and Date: 2008-09-02
• [Presentation] Synthesis and optical Characterization of Surface Modified Si Nanocrys tals with Organic Surfactants (2008)
  • Author(s): S. Sato, K. Yamaguchi, H. Yao, K. Kimvira
  • Organizer: Intemational Symposium on Organosilicon Chemistry
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2008-06-03
• [Presentation] Influence of Achiral/Chiral Phase Transfer on the Chiroptical Responses of Ligand-Protected Gold Nanoclusters (2008)
  • Author(s): H. Yao, T. Fukui, K. Kimura
  • Organizer: International Symposium on Monolayer-Protected Clusters ; ISMPC08
  • Place of Presentation: Jyvaskyla, Finland, Invited
• [Presentation] Controlling the Behavior of Silicon Nanoclusters in Suspensions (2007)
  • Author(s): S. Sato, H. Yao, K. Kimura
  • Organizer: Nanomeeting-2007
  • Place of Presentation: Minsk, Belarus Invited
• [Presentation] Three-Dimensional Superlattices of N-Acetylglutathione-Protected Gold Nanoparticles:Emergence of Fivefold Symmetry (2007)
  • Author(s): Hiroshi Yao, Takayuki Minami, Akihiko Hori, Masaya Koma, Ke isaku Kimura
  • Organizer: TNT2007
  • Place of Presentation: San Sebastian,Spain
• [Presentation] Atomic Alignment over Superlattices of Water Soluble Au Nanoparticles (2007)
  • Author(s): Keisaku Kimura, Seiichi Sato, Sufua Wang
  • Organizer: TNT2007
  • Place of Presentation: San Sebastian, Spain
• [Presentation] Synthesis and Chiroptical Study of Optically Active Thiolate-Capped Silver Nanoclusters (2007)
  • Author(s): Naoki Nishida, Hiroshi Yao, Tomoyasu Ueda, Akito Sasaki, Keisaku Kimura
  • Organizer: TNT2007
  • Place of Presentation: San Sebastian,Spain
• [Presentation] Au-GTR系ナノ粒子の電気泳動(PAGE)、質量分析、電子顕微鏡によるサイズの比較 (2007)
  • Author(s): 杉本 将之・八尾 浩史・佐藤 井一・根岸 雄一・佃 達也・木村 啓作
  • Organizer: 第60回コロイド討論会
  • Place of Presentation: 信州大学
• [Presentation] Self-Assembling of Au and Ag Nanoparticles using Hydrogen Bonding (2006)
  • Author(s): K. Kimura, Y. Yang, H. Yao, S. Sato
  • Organizer: The 3rd Annual Meeting of Missouri Nanotechnology Alliance
  • Place of Presentation: Missouri, USA, Invited
• [Book] シリコンナノ粒子の性質と応用 (2008)
  • Author(s): 佐藤 井一
  • Total Pages: 400
  • Publisher: ナノ粒子の創製と応用展開 ; フロンティア出版
• [Book] 表面 (2007)
  • Author(s): 佐藤井一、木村啓作、Mark Swihart
  • Publisher: 有機分子終端シリコンナノ粒子の合成と可視領域発光
• [Book] No.3 of the Microscopy book series, Ed. A. Mendez-Vilas, J. Diaz ; Formatx, Badajoz (2007)
  • Author(s): H. Yao, K. Kimura
  • Publisher: Field Emission Scanning Electron Microscopy for Structural Characterization of 3D Gold Nanoparticle Superlattices, In Modern Research and Educational Topics in Microscopy
• [Book] Field Emission Scanning Electron Microscopy for Structural Characterization of 3D God Nanoarticle Superlattices (2007)
  • Author(s): H. Yao and K. Kimura
  • Total Pages: 700
  • Publisher: Microscopy Series #3, Eds. A. Mendez-Vilas, J. Diaz; Formatex
• [Book] In Nanoparticle Assemblies and Superstructures, Ed. N. A. Kotov, CRC Press (2005)
  • Author(s): H. Yao, S. Sato, K. Kimura
  • Publisher: Self-Assembling of Gold Nanoparticles at an Air/Water Interface
• [Book] ナノマテリアルハンドブック、NTS (2005)
  • Author(s): 八尾浩史、木村啓作
  • Publisher: 金属・ナノハイブリッド-粒子結晶制御(第9章2節4項)
• [Book] ナノマテリアルハンドブック (2005)
  • Author(s): 八尾浩史, 木村啓作
  • Total Pages: 1000
  • Publisher: NTS出版
• [Remarks] 「シリコンで人工格子」日刊工業新聞、平成16年6月28日
• [Remarks] 「光るシリコン粒子」日経産業新聞、第一面、平成18年7月28日
• [Remarks]
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• [Remarks]
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• [Patent(Industrial Property Rights)] (財)新産業創造研究機構「シリコンクラスタ超格子、シリコンクラスタ超格子の製造方法、シリコンクラスタの製造方法、シリコンクラスタ超格子構造物、シリコンクラスタ超格子構造物の製造方法、半導体デバイスおよび量子デバイス」
  • Inventor(s): 木村啓作、佐藤井一、山本直樹
• [Patent(Industrial Property Rights)] 株式会社イオックス : 「二層式金属微粒子製造方法」
  • Inventor(s): 木村啓作