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Study of the mesoscopic nano-structures by using the scanning near-field Raman spectroscopy

Research Project

Project/Area Number 16340084
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics I
Research InstitutionMuroran Institute of Technology

Principal Investigator

SAKAI Akira  Muroran Institute of Technology, Faculty of engineering, Professor, 工学部, 教授 (70136422)

Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥14,600,000 (Direct Cost: ¥14,600,000)
Fiscal Year 2006: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2005: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 2004: ¥11,000,000 (Direct Cost: ¥11,000,000)
Keywordsnear-field optics / Raman scattering / mesoscopic / nano structure
Research Abstract

Most of the condensed matters have the hierarchical structures especially in the structural phase transition. The microscopic atomic arrangements form the mesoscopic structures in the intermediate range. In addition, the higher structures appear from the mesoscopic structures. Therefore, it is necessary to study the mesoscopic structures appeared in the nano-scale region in order to understand the physical property of the condensed mater. To observe the nano-Raman scattering spectra in the mesoscopic structure, a new type of scanning near-field Raman spectroscopic system has been developed by combing scanning atomic force microscopy with micro-Raman scattering spectroscopy.
For the observation from the nano-scale region which is smaller than the wavelength of the light, a silicon cantilever with the minute aperture was used both as the illumination nano-scale and the nano-detector of scattered light. We applied for a patent about this technique. To get better performance, the spectroscopic system bas been reconstituted by using the selected optical components such as the lens, miller, filter and so on.
Because the mesoscopic structure emerges at its characteristic temperature, the temperature of the sample should be controlled in the wide range. Thus, we have developed the temperature controlled sample-stage which can set in the scanning near-field Raman spectrometer. The sample-stage was required high performance: high temperature stability, low optical loss at the window, including the piezo-scanning system of the cantilever, removing the vibration produced by the vacuum pump and so on.
The near-field Raman scattering spectra were successfully observed by using the system developed in the present study. In the next phase, we will attack the phenomena in the mesoscopic structure.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (20 results)

All 2007 2006 2005 2004 Other

All Journal Article (19 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Temperature Dependence of Raman Scattering Spectra in Lead Nitrate Crystal2007

    • Author(s)
      H.Isoda, A.Sakai, R.Kawashima
    • Journal Title

      Physica status solidi (b) (印刷中)

    • NAID

      110006342616

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Infrared Spectra of Internal Modes in Gd_2(MoO_4)_3 near the Ferroelectric Phase Transition Temperature2007

    • Author(s)
      A.Sakai, K.Honma
    • Journal Title

      J. Korean Phys. Soc. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Temperature Dependence of Raman Scattering Spectra in Lead Nitrate Crystal2007

    • Author(s)
      H.Isoda, A.Sakai, R.Kawashima
    • Journal Title

      Physica status solidi (b) (in press)

    • NAID

      110006342616

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Infrared Spectra of Internal Modes in Gd_2(MoO_4)_3 near the Ferroelectric Phase Transition Temperature2007

    • Author(s)
      A.Sakai, K.Honma
    • Journal Title

      J.Korean Phys.Soc. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Temperature Dependence of Raman Scattering Spectra in Lead Nitrate Crystal2007

    • Author(s)
      H.Isoda, A.Sakai, R.Kawashima
    • Journal Title

      Phycica (b) (印刷中)

    • NAID

      110006342616

    • Related Report
      2006 Annual Research Report
  • [Journal Article] ナノスケールでの分光計測を目指して-走査型近接場ラマン分光装置の開発-2006

    • Author(s)
      酒井 彰
    • Journal Title

      室蘭工業大学機器分析センター年報 8

      Pages: 13-17

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Raman Scattering Spectra of Quasi-Two-Dimensional Crystallization Water in Cu(HCOO)_2・4H_2O near the Antiferroelectric Phase Transition2006

    • Author(s)
      A.Sakai, T.Mizushima, C.Moriyoshi
    • Journal Title

      Ferrioelectrics 346

      Pages: 168-172

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Observation of Raman spectra in nano-meter region -Development of scanning near-field Raman spectrometer-2006

    • Author(s)
      A.Sakai
    • Journal Title

      Annual Report of Center for Instrumental Analysis Muroran Institute of Technology vol.8

      Pages: 13-17

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Raman Scattering Study of Antiferroelectric Phase Transition in Cu(HCOO)_2・4H_2O2005

    • Author(s)
      T.Mizushima, A.Sakai, C.Moriyoshi, T.Omura, I.Itoh
    • Journal Title

      Journal of the Korean Physical Society 46・1

      Pages: 202-204

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Raman Scattering Study of Antiferroelectric Phase Transition in Cu(HCOO)_2・4H_2O2005

    • Author(s)
      T.Mizushima, A.Sakai, C.Moriyoshi, T.Omura, I.Itoh
    • Journal Title

      Journal of the Korean Physical Society vol.46

      Pages: 202-204

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 微小開ロカンチレバープローブを用いた走査型近接場ラマン分光装置の開発-ナノ領域におけるスペクトル観察-2004

    • Author(s)
      佐々木直人, 二宮隆徳, 酒井 彰
    • Journal Title

      分光研究 53・2

      Pages: 87-92

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Near-Field Raman Spectra of Ferroelectric Single Crystal2004

    • Author(s)
      A.Sakai, T.Ninomiya, N.Sasaki
    • Journal Title

      Ferroelectrics 303

      Pages: 227-232

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 走査型近接場ラマン顕微鏡2004

    • Author(s)
      酒井 彰
    • Journal Title

      光学 33・12

      Pages: 721-723

    • NAID

      10014211377

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Development of scanning near-field Raman spectrometer using a cantilever with miniature aperture2004

    • Author(s)
      N.Sasaki, T.Ninomiya, A.Sakai
    • Journal Title

      Journal of the Spectroscopical Society of Japan vol.53

      Pages: 87-92

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Near-Field Raman Spectra of Ferroelectric Single Crystal2004

    • Author(s)
      A.Sakai, T.Ninomiya, N.Sasaki
    • Journal Title

      Ferroelectrics vol.303

      Pages: 227-232

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Scanning near-field Raman microscope2004

    • Author(s)
      A.Sakai
    • Journal Title

      Japanese journal of optics vol.33

      Pages: 721-723

    • NAID

      10014211377

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 微小開口カンチレバープローブを用いた走査型近接場ラマン分光装置の開発-ナノ領域におけるスペクトル観察-2004

    • Author(s)
      佐々木直人
    • Journal Title

      分光研究 53・2

      Pages: 87-92

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Near-Field Raman Spectra of Ferroelectric Single Crystal2004

    • Author(s)
      Akira Sakai
    • Journal Title

      Ferroelectrics 303

      Pages: 227-232

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Raman Scattering Spectra of Quasi-Two-Dimensional Crystallization Water in Cu(HCOO)_2・4H_2O near the Antiferroelectric Phase Transition

    • Author(s)
      A.Sakai, T.Mizushima, C.Moriyoshi
    • Journal Title

      Ferroelectrics vol.346

      Pages: 168-172

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 微小開ロカンチレバーおよびそれを用いた近接場分光装置2005

    • Inventor(s)
      酒井 彰
    • Industrial Property Rights Holder
      室蘭工業大学
    • Industrial Property Number
      2005-150803
    • Filing Date
      2005-05-24
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary

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Published: 2004-04-01   Modified: 2020-05-15  

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