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Extensive Research of Multiple-Angle Incidence Resolution Spectrometry : Study of Molecular Self-Organization of via Analysis of Molecular Anisotropic Structure

Research Project

Project/Area Number 16350048
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionTokyo Institute of Technology (2006)
Nihon University (2004-2005)

Principal Investigator

HASEGAWA Takeshi  Tokyo Insitiute of Technology, Graduate School of Science and Engineering, Associate Professor, 大学院理工学研究科, 助教授 (30258123)

Co-Investigator(Kenkyū-buntansha) OZAKI Yukihiro  Kwnasei Gakuin Univ., Faculty of Science and Engineering, Professor, 理工学部, 教授 (00147290)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥12,000,000 (Direct Cost: ¥12,000,000)
Fiscal Year 2006: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2005: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2004: ¥9,300,000 (Direct Cost: ¥9,300,000)
KeywordsIR MAIRS / infrared spectroscopy / organic ultrathin films / molecular orientation / polymer / semiconductor surface / prion protein / spectroscopic analysis / 分子配向解析 / 計測化学 / 回帰式
Research Abstract

A new spectroscopic analysis method was designed aiming at proposing a new measurement principle, and putting it to practical use as a measurement method and it made it public on J.Phys.Chem. B in 2002. This was based on a peculiar idea that built 'virtual light' with a parallel electric field vibration to the traveling direction of light into the regression, and the measurement theory had the side not somewhat understood easily. On the other hand, it only has to measure the single beam spectrum of the hilt that changes the angle of incidence to the thin film, and it is extremely easily enforceable in an actual measurement. This method was named multiplicity incidence resolution spectroscopy (multiple-angle incidence resolution spectrometry ; MAIRS), and the base of this research was completed. Afterwards, the basic research into the MAIRS method was begun, and the arrangement of the relation with the theory and the search for coverage began on the basic principle so far.
Because infrar … More ed rays MAIRS method was based on a special conception like virtual light and the regression, etc., the following one was at least obtained as a result by the one with special achieved result.
(1)The pure out-of-plane vibration spectrum can be measured on the surface of the nonmetal.
(2)The spectrum of the vibration outside the vibration spectrum in the side and respect can be measured from one sample at the same time.
(3)The result of the reflection spectrum corresponding is obtained from the optics system of penetration.
(4)The polarized light spectrum corresponding is obtained without the polarizer.
(5)It is possible to analyze it quantitatively for a molecular distribution without an optical constant.
Then, such a possibility developed with the applied research, and it developed with the research on the surface coating analysis on the research on the creation of a molecular cohesion analysis of an abnormal prion and a noncovalent bond Polymer material and the microchip etc.
This base research research development roughly go well change research result begin to appear initial stage science and technology promotion mechanism future disregard structural function measurement analysis adopt research further accelerate. Moreover, it connected with getting Dr. Masao Horiba Award for the principle and the applied result of MAIRS. Less

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (23 results)

All 2007 2006 2005 2004

All Journal Article (19 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Ordered Arrays of Organometallic Iridium Complexes with Long Alkyl Chains on Graphite2007

    • Author(s)
      J.Otsuki, T.Tokimoto, Y.Noda, T.Yano, T.Hasegawa, X.Chen, Y.Okamoto
    • Journal Title

      Chemistry : a European Journal 13(8)

      Pages: 2311-2319

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Analysis of Gibbs Monolayer Adsorbed at the Toluene/Water Interface by UV-Visible Partial Internal Reflection Spectrometry2006

    • Author(s)
      Y.Moriya, T., T.Okada, N.Ogawa, E.Kawai, K.Abe, M.Ogasawara, S.Kato, S.Nakata
    • Journal Title

      Analytical Chemistry 78(22)

      Pages: 7850-7856

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Analysis of Structurally Heterogeneous Langmuir-Blodgett Films of Folded/Unfolded Long-Chain Molecules by Infrared Multiple-Angle Incidence Resolution Spectroscopy2006

    • Author(s)
      Takeshi Hasegawa, Yu Iiduka, Hiroyuki Kakuda, Tetsuo Okada
    • Journal Title

      Analytical Chemistry 78(17)

      Pages: 6121-6125

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Measurements of a Monolayer Langmuir-Blodgett Film on a Thin Glass Plate by Infrared Multiple-Angle Incidence Resolution Spectroscopy2006

    • Author(s)
      Takeshi Hasegawa, Yusuke Nakano
    • Journal Title

      Vibrational Spectroscopy 42(1)

      Pages: 41-44

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] ロイシンファスナーでB-シートを組織化した超分子単分子膜2006

    • Author(s)
      山田哲弘, 高橋京子, 上野香央里, 山谷裕香, 長谷川健
    • Journal Title

      高分子論文集 63(7)

      Pages: 476-483

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Molecular Orientation Analysis of a Single-Monolayer Langmuir-Blodgett Film on a Thin Glass Plate by Infrared Multiple-Angle Incidence Resolution Spectrometry2006

    • Author(s)
      Takeshi Hasegawa, Yusuke Nakano, Yasuyoshi Ishii
    • Journal Title

      Analytical Chemistry 78(6)

      Pages: 1739-1742

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Ultarthin films of β-sheet organized by leucine fastener2006

    • Author(s)
      N.Yamada, K.Takahashi, K.Ueno, Y.Yamaya, T.Hassegawa
    • Journal Title

      Kobunshi Ronbunshu 63(7)

      Pages: 476-483

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Taylor & Francis2006

    • Author(s)
      Takeshi Hasegawa, Veeranjaneyulu Konka, Roger M.Leblanc
    • Journal Title

      Vibrational Spectroscopy of Biological and Polymeric Materials

      Pages: 99-162

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] ロイシンファスナーでβ-シートを組織化した超分子単分子膜2006

    • Author(s)
      山田哲弘, 高橋京子, 上野香央里, 山谷裕香, 長谷川健
    • Journal Title

      高分子論文集 63(7)

      Pages: 476-483

    • NAID

      10018184964

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A Spectral Simulation Study on an Influence of the Principal-Component Analysis Step on Principal-Component Regression2006

    • Author(s)
      Takeshi Hasegawa
    • Journal Title

      Applied Spectroscopy 60(1)

      Pages: 95-98

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Molecular Orientation Analysis of a Single-Monolayer Langmuir-Blodgett Film on a Thin Glass Plate by Infrared Multiple-Angle Incidence Resolution Spectrometry (Accelerated Article)2006

    • Author(s)
      Takeshi Hasegawa, Yusuke Nakano, Yasuyoshi Ishii
    • Journal Title

      Analytical Chemistry 78(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Characterization of Thin Cast Films of a Trileucine-lnduced Lipid by Infrared Multiple-Angle Incidence Resolution Spectrometry2005

    • Author(s)
      Takeshi Hasegawa, Junzo Umemura, Norihiro Yamada
    • Journal Title

      Journal of Molecular Structure 735/736

      Pages: 63-67

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Leucine-Fastener Formation Mechanism between Peptide β-Sheets in a Mono layer Studied by Infrared Multiple-Angle Incidence Resolution Spectroscopy2005

    • Author(s)
      Takeshi Hasegawa, Hiroyuki Kakuda, Norihiro Yamada
    • Journal Title

      The Journal of Physical Chemistry B 109(10)

      Pages: 4783-4787

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Fibril-like Aggregate Formation of Peptide Carboxylate Langmuir Films Analyzed by Surface Pressure, Surface Dipole Moment and Infrared Spectroscopy2005

    • Author(s)
      T.Hasegawa, Daisuke Moriya, Hiroyuki Kakuda ; Changqing Li, Jhony Orbulescu, Roger M.Leblanc
    • Journal Title

      The Journal of Physical Chemistry B 109(26)

      Pages: 12856-12860

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Analysis of Hydrogen-Terminated Si(111)Surface by Infrared Multiple-Angle Incidence Resolution Spectroscopy2005

    • Author(s)
      H.Kakuda, T.Hasegawa ; T.Tanaka, K.Tanaka, M.Shionoya
    • Journal Title

      Chemical Physics Letters 415

      Pages: 172-175

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Characterization of Thin Cast Films of a Trileucine-Induced Lipid by Infrared Multiple-Angle Incidence Resolution Spectrometry2005

    • Author(s)
      Takeshi Hasegawa, Junzo Umemura, Norihiro Yamada
    • Journal Title

      Journal of Molecular Structure 735/736

      Pages: 63-67

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Hydrogen Bonding Networks of Dialkyl Disulfides Containing the Urea Moiety in Self-Assembled Monolayers2004

    • Author(s)
      J.H.Kim, H.S.Shin, S.B.Kim, T.Hasegawa
    • Journal Title

      Langmuir 20

      Pages: 1674-1679

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structural Analysis Biological Aliphatic Compounds Using Surface-Enhanced Fourier Transform Raman Spectroscopy2004

    • Author(s)
      Takeshi Hasegawa
    • Journal Title

      Biopolymers 73(4)

      Pages: 457-462

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A Novel Approach of Cartesian-Structure Analysis in Cast Films by Advanced Infrared Multiple-Angle Incidence Resolution Spectroscopy2004

    • Journal Title

      Analytical Chemistry 76(11)

      Pages: 3084-3090

    • Related Report
      2004 Annual Research Report
  • [Book] Vibrational Spectroscopy of Biological and Polymeric Materials2006

    • Author(s)
      Takeshi Hasegawa, Veeranjaneyulu Konka, Roger M. Leblanc
    • Total Pages
      64
    • Publisher
      Taylor & Francis
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Book] スペクトル定量分析(単著)2005

    • Author(s)
      長谷川 健
    • Total Pages
      170
    • Publisher
      講談社サイエンティフィク
    • Related Report
      2005 Annual Research Report
  • [Book] 基本分析化学(日本分析化学会・編)第3章3.3節2004

    • Author(s)
      長谷川 健
    • Total Pages
      4
    • Publisher
      朝倉書店
    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 分光解析装置2007

    • Inventor(s)
      長谷川健
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2007-037051
    • Filing Date
      2007-02-16
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary

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Published: 2004-04-01   Modified: 2016-04-21  

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