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Functional nanocarbon and hydrogen co-production systems for zero emission industry

Research Project

Project/Area Number 16H01795
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionTohoku University

Principal Investigator

HONMA Itaru  東北大学, 多元物質科学研究所, 教授 (90181560)

Co-Investigator(Kenkyū-buntansha) 小林 弘明  東北大学, 多元物質科学研究所, 助教 (90804427)
笘居 高明  東北大学, 多元物質科学研究所, 准教授 (80583351)
Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥41,730,000 (Direct Cost: ¥32,100,000、Indirect Cost: ¥9,630,000)
Fiscal Year 2019: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2018: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2017: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2016: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Keywordsグラフェン / 水素製造 / コプロダクション / 水熱電解 / 超臨界流体 / 亜臨界水 / ナノカーボン / 脱炭素 / 水熱電気化学 / 電解合成 / 地球温暖化対策 / ダイヤモンド / システム工学 / 水素 / ナノチューブ・フラーレン / エネルギー全般 / 環境技術
Outline of Final Research Achievements

In this research project, we have developed a novel co-production processes of mono-layer graphene and hydrogen via hydrothermal cathodic reduction under a subcritical water. In the developed process, the hydrothermal subcritical water solution was used to enhance the electrochemical reaction kinetics due to an increased electrolytic dissociation rate of the water and prevent the formation of undesirable amorphous carbon. The hydrothermal electrochemical reaction enabled low-temperature graphene growth on a Pt cathode surface with simultaneous hydrogen production. The conversion of hydrocarbons/basic chemicals to the high-value-added nanocarbons, including graphene, carbon nanotubes, and fullerenes, with valuable hydrogen has high potential economic/environmental benefits.

Academic Significance and Societal Importance of the Research Achievements

本研究では、高付加価値の炭素素材を水素と同時生産することにより結果的に水素製造のコストダウンを実現するところにシステム工学的に革新性がある。地球温暖化対策のキーテクノロジーである水素は低コスト化と量産化が課題であるが、これをコプロダクションというシステム的なアプローチで解決できれば、工学上の難問に対する素晴らしい解答であり、環境技術としてのイノベーションになることが期待できる。コプロダクションが実現すれば、ゼロエミッション燃料である水素燃料の格段の低コスト化、市場普及するに違いない。持続可能社会に貢献する強力なゼロエミッション技術の創成は、産業経済への広範な波及効果が予想できる。

Report

(5 results)
  • 2020 Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (56 results)

All 2021 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (8 results) Journal Article (17 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 17 results,  Open Access: 2 results) Presentation (20 results) (of which Int'l Joint Research: 7 results,  Invited: 4 results) Book (6 results) Remarks (4 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] メルボルン大学/ニューカッスル大学/南オーストラリア大学(オーストラリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Ton Duc Thang大学/ハノイ科学技術大学/ベトナム科学技術院(ベトナム)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Visvesvaraya Technical University(インド)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] 中国科学技術院(中国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ベトナム科学技術院/ハノイ科学技術大学(ベトナム)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Hanyang 大学(韓国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ベトナム科学技術機構(ベトナム)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Hanyang 大学(韓国)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Defect-Rich Exfoliated MoSe2 Nanosheets by Supercritical Fluid Process as an Attractive Catalyst for Hydrogen Evolution in Water2020

    • Author(s)
      Quang Duc Truong, Yuta Nakayasu, Quyen T. Nguyen, Duc N. Nguyen, Chuc T. Nguyen, Murukanahally Kempaiah Devaraju, Dinesh Rangappa, Keiichiro Nayuki, Yoshikazu Sasaki, Phong D. Tran, Takaaki Tomai, Itaru Honma
    • Journal Title

      Applied Surface Science

      Volume: 505 Pages: 144537-144537

    • DOI

      10.1016/j.apsusc.2019.144537

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bottom-up synthesis of graphene via hydrothermal cathodic reduction2020

    • Author(s)
      Takaaki Tomai, Yuta Nakayasu, Yusuke Okamura, Shunichi Ishiguro, Naoki Tamura, Shusuke Katahira and Itaru Honma
    • Journal Title

      Carbon

      Volume: 158 Pages: 131-136

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] MoS2 Nanosheets Having Controlled Numbers of Layers and Phase Structure by Supercritical Hydrothermal Processing2020

    • Author(s)
      Yuki Takahashi, Yuta Nakayasu, Kazuyuki Iwase, Hiroaki Kobayashi and Itaru Honma
    • Journal Title

      Dalton Transactions

      Volume: 49 Issue: 27 Pages: 9377-9384

    • DOI

      10.1039/d0dt01453b

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rapid synthesis of defective and composition-controlled metal chalcogenide nanosheets by supercritical hydrothermal processing2019

    • Author(s)
      Yuta Nakayasu, Siobhan Bradley, Hiroaki Kobayashi, Keiichiro Nayuki, Yoshikazu Sasaki, Takaaki Tomai, Thomas Nann and Itaru Honma
    • Journal Title

      Nanoscale Advances

      Volume: 1 Issue: 9 Pages: 3383-3387

    • DOI

      10.1039/c9na00435a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Inversion Domain Boundary in MoSe2 Layers2018

    • Author(s)
      Quang Duc Truong, Nguyen T. Hung, Yuta Nakayasu, Keiichiro Nayuki, Yo-shikazu Sasaki, Murukanahally Kempaiah Devaraju, Li-Chang Yin, Takaaki Tomai, Riichiro Saito, Itaru Honma
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 58 Pages: 33391-33397

    • DOI

      10.1039/c8ra07205a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Electrodeposited amorphous tungsten-doped cobalt oxide as an efficient catalyst for the oxygen evolution reaction2018

    • Author(s)
      Linh N. Nguyen, Ung Thi Dieu Thuy, Quang Duc Truong, Itaru Honma, Quang Liem Nguyen and Phong Dinh Tran
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 13 Issue: 12 Pages: 1530-1534

    • DOI

      10.1002/asia.201800401

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] One-pot rapid synthesis of Mo(S,Se)2 nanosheets on graphene for highly efficient hydrogen evolution2018

    • Author(s)
      Yuta Nakayasu, Yoji Yasui, Ryosuke Taniki, Kotaro Oizumi, Hiroaki Kobayashi, Naoka Nagamura, Takaaki Tomai and Itaru Honma
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 6 Issue: 9 Pages: 11502-11510

    • DOI

      10.1021/acssuschemeng.8b01614

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quasi-solid-state lithium batteries using bulk-size transparent Li7La3Zr2O12 electrolytes2018

    • Author(s)
      Shoichi Sugata, Noriko Saito, Akio Watanabe, Ken Watanabe, Je-Deok Kim, Kan Kitagawa, Yosuke Suzuki and Itaru Honma
    • Journal Title

      Solid State Ionics

      Volume: 319 Pages: 285-290

    • DOI

      10.1016/j.ssi.2018.02.029

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biocompatible batteries -Materials and chemistry, fabrication, applications, and future prospects2018

    • Author(s)
      Sven Stauss and Itaru Honma
    • Journal Title

      Bull. Chen. Soc. Jpn. (Accounts & Reviews)

      Volume: 91 Issue: 3 Pages: 492-505

    • DOI

      10.1246/bcsj.20170325

    • NAID

      130006507083

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic states of quinones for organic energy devices: The effect of molecular structure on electrochemical characteristics2018

    • Author(s)
      Naoka Nagamura, Ryosuke Taniki,Yuta Kitada, Asuna Masuda, Hiroaki Kobayashi, Nobuto Oka and Itaru Honma
    • Journal Title

      ACS Applied Energy Materials

      Volume: 1 Issue: 7 Pages: 3084-3092

    • DOI

      10.1021/acsaem.7b00156

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Capacity improvement of the carbon-based electrochemical capacitor by zigzag-edge introduced graphene2018

    • Author(s)
      Naoki Tamura, Takaaki Tomai, Nobuto Oka and Itaru Honma
    • Journal Title

      Applied Surface Science

      Volume: 428 Pages: 986-989

    • DOI

      10.1016/j.apsusc.2017.09.187

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel amorphous molybdenum selenide as an efficient catalyst for the hydrogen evolution reaction2018

    • Author(s)
      Quyen T. Nguyen, Phuc Dinh Nguyen, Duc N. Nguyen, Quang Duc Truong, Tran Thi Kim Chi, Thuy Ung, Itaru Honma, Nguyen Quang Liem, and Phong D. Tran
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 10 Pages: 8659-8665

    • DOI

      10.1021/acsami.7b18675

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Correlation between the carbon structures and their tolerance to carbon corrosion as catalyst supports for polymer electrolyte fuel cells2018

    • Author(s)
      Takanori Tamaki, Hailin Wang, Nobuto Oka, Itaru Honma, Seong-Ho Yoon and Takeo Yamaguchi
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 43 Issue: 12 Pages: 6406-6412

    • DOI

      10.1016/j.ijhydene.2018.01.205

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of three-dimensional CuInS2 solar-cell structure via supercritical fluid processing2017

    • Author(s)
      Takaaki Tomai, Yoji Yasui, Shinji Watanabe, Yuta Nakayasu, Liwen Sang, Masatomo Sumiya, Takeshi Momose, Itaru Honma
    • Journal Title

      The Journal of Supercritical Fluids

      Volume: 120 Pages: 448-452

    • DOI

      10.1016/j.supflu.2016.05.026

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure-Based Selective Adsorption of Graphene on a Gel Surface: Toward Improving the Quality of Graphene Nanosheets2017

    • Author(s)
      Takaaki Tomai, Shunichi Ishiguro, Naoki Tamura, Yuta Nakayasu, Itaru Honma
    • Journal Title

      Langmuir

      Volume: 33 Issue: 22 Pages: 5406-5411

    • DOI

      10.1021/acs.langmuir.7b00254

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exfoliated MoS2 and MoSe2 nanosheets by supercritical fluid process for hybrid Mg-Li-ion battery2017

    • Author(s)
      Quang Duc Truong, Murukanahally Kempaiah Devaraju, Yuta Nakayasu, Naoki Tamura, Yoshikazu Sasaki, Takaaki Tomai, Itaru Honma
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 5 Pages: 2360-2367

    • DOI

      10.1021/acsomega.7b00379

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Cu2ZnSnS4 thin films using a Cu-Zn-Sn-O amorphous precursor and supercritical fluid sulfurization2017

    • Author(s)
      Yuta Nakayasu, Takaaki Tomai, Nobuto Oka, Kanako Shojiki, Shigeyuki Kuboya, Ryuji Katayama, Liwen Sang, Masatomo Sumiya and Itaru Honma
    • Journal Title

      Thin Solid Films

      Volume: 638 Pages: 244-250

    • DOI

      10.1016/j.tsf.2017.07.063

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 超臨界水熱合成法を用いたMoS2の構造制御合成とその水素発生活性2021

    • Author(s)
      高橋 裕紀、岩瀬 和至、中安 祐太、小林 弘明、本間 格
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 超臨界水熱反応場における二硫化モリブデンの構造制御合成2020

    • Author(s)
      高橋裕紀、岩瀬和至、中安祐太、小林弘明、本間格
    • Organizer
      日本セラミック協会2020年年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機還元剤を用いた超臨界還元場によるMoS2ナノシートの形態制御合成2019

    • Author(s)
      高橋 裕紀, 中安 祐太, 岩瀬 和至, 小林 弘明, 本間 格
    • Organizer
      東北大学環境科学研究科 環境科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Synthesis of MoS2 nanosheets by supercritical hydrothermal process and their electrocatalytic properties for hydrogen evolution2019

    • Author(s)
      Yuki Takahashi, Yuta Nakayasu, Hiroaki Kobayashi and Itaru Honma
    • Organizer
      The 18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Rapid fabrication of metallic MoS2 thin film under hydrothermal electrodeposition for electrocatalytic hydrogen evolution reaction2019

    • Author(s)
      Yuta Nakayasu, Hiroaki Kobayashi, Shusuke Katahira, Itaru Honma
    • Organizer
      The 18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機還元剤を用いた超臨界還元場によるMoS2ナノシートの選択的合成2019

    • Author(s)
      高橋裕紀・岩瀬和至・中安祐太・小林弘明・本間格
    • Organizer
      第9回化学フェスタ2019 (9th CSJ Chemistry Festa)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Facile Synthesis of MoS2 Cathode for Water Splitting Catalyst Using Electrochemical Reduction Under Hydrothermal Condition2019

    • Author(s)
      Hiroaki Kobayashi, Shunsuke Katahira, Yuta Nakayasu and Itaru Honma
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM 13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水素発生電極に資するエッジリッチ構造を有したMo(S,Se)2と(Mo,W)S2ナノシートの超臨界水熱合成2019

    • Author(s)
      中安 祐太、小林弘明、 本間 格
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水熱電気化学プロセスによる水分解用MoS2 ナノシート電極の作製2019

    • Author(s)
      片平 周介、中安 裕太、小林 弘明、本間 格
    • Organizer
      化学工学会 第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水熱電解プロセスを用いたMoS2薄膜電極の作製と水素発生反応触媒活性2019

    • Author(s)
      片平周介、中安祐太、小林弘明、本間格
    • Organizer
      第86回電気化学会大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of Mo(S,Se)2 and (Mo, W)S2 nanosheets from metal- oxide and pure- chalcogen precursors in supercritical fluids2018

    • Author(s)
      Yuta Nakayasu, Hiroaki Kobayashi and Itaru Honma
    • Organizer
      2018 MRS Fall Meeting and Exhibit
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水素発生用MoS2薄膜の水熱電解合成2018

    • Author(s)
      片平 周介、小林 弘明、中安 祐太、本間 格
    • Organizer
      資源・素材2018 平成30年度資源素材関係学協会合同秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 水熱電解析出法による水分解用MoS2/グラフェンカソードの作製2018

    • Author(s)
      中安祐太、片平周介、小林弘明、本間格
    • Organizer
      化学工学会第50回秋季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Advanced Nanomaterials Processing for Next Generation Secondary Batteries, Solar and Fuel Cells2018

    • Author(s)
      Itaru Honma
    • Organizer
      Joint Workshop of Tohoku University & University of Science and Technology Beijing
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of edge-rich MoS2 cathode for water splitting via hydrothermal electrodeposition2018

    • Author(s)
      Shusuke Katahira, Hiroaki Kobayashi, Yuta Nakayasu Itaru Honma
    • Organizer
      2018 MRS Fall Meeting and Exhibit
    • Related Report
      2017 Annual Research Report
  • [Presentation] 水熱電解を用いた新たなダイヤモンド合成法の開発2018

    • Author(s)
      石黒駿一、小林弘明、笘居高明、本間格
    • Organizer
      平成30年度応用物理学会春季大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] アリルデキストランゲル表面へのグラフェンの構造選択的吸着2017

    • Author(s)
      石黒駿一、笘居高明、田村直貴、中安祐太、本間格
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 先端電池材料創製に向けた超臨界流体プロセスの展開2017

    • Author(s)
      本間 格
    • Organizer
      資源・素材&EARTH2017
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 機能性ナノマテリアルの次世代電池材料への応用2017

    • Author(s)
      本間 格
    • Organizer
      素材プロセッシング第69委員会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Environmentally- friendly synthesis of Cu2ZnSn(S,Se)4 thin film and Mo(S,Se)2 nanoflower for energy conversion devices employing supercritical fluid processing2017

    • Author(s)
      Yuta Nakayasu, Takaaki Tomai and Itaru Honma
    • Organizer
      2017 MRS Fall meeting & Exhibits
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] 有機低分子を活かした高容量高出力型の水系蓄電デバイス   ープロトンロッキングチェア型有機二次電池ー2018

    • Author(s)
      小林弘明、笘居高明、本間格
    • Total Pages
      3
    • Publisher
      日本化学会
    • Related Report
      2018 Annual Research Report
  • [Book] 「有機正極材料を用いたリチウムイオン電池の開発」、電気化学・インピーダンス測定のデータ解析と事例集2018

    • Author(s)
      谷木良輔、増田有沙、北田祐太、永村直佳、本間格
    • Total Pages
      3
    • Publisher
      (株)技術情報協会
    • ISBN
      9784861047305
    • Related Report
      2018 Annual Research Report
  • [Book] 超臨界流体を利用したナノシートプロセシング (附置研究所アライアンス特集号) 53巻6号2018

    • Author(s)
      笘居 高明、宮脇 仁、尹 聖昊、本間 格
    • Total Pages
      5
    • Publisher
      日本セラミックス協会誌
    • Related Report
      2017 Annual Research Report
  • [Book] スラリー型レドックスフロー電池/キャパシタ2017

    • Author(s)
      本間格、笘居高明
    • Total Pages
      14
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Annual Research Report
  • [Book] Graphene: Electrochemical Exfoliation and Applications2016

    • Author(s)
      Quang Duc Truong and Itaru Honma
    • Publisher
      CRC Press, Taylor and Francis
    • ISBN
      9781466591240
    • Related Report
      2016 Annual Research Report
  • [Book] 有機レドックス分子を用いたスーパーキャパシタ2016

    • Author(s)
      本間格、笘居高明
    • Total Pages
      5
    • Publisher
      応用物理学会
    • Related Report
      2016 Annual Research Report
  • [Remarks] グラフェンの新しい合成法 ~亜臨界水熱電解によるグラフェンと水素の同時生成~

    • URL

      http://www.tohoku.ac.jp/japanese/2019/12/press20191210-03-Gra.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 東北大学多元物質科学研究所本間研究室

    • URL

      http://www2.tagen.tohoku.ac.jp/lab/honma/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 本間研究室(東北大学多元物質科学研究所)

    • URL

      http://www2.tagen.tohoku.ac.jp/lab/honma/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東北大学多元物質科学研究所 金属資源プロセス研究センター

    • URL

      http://www2.tagen.tohoku.ac.jp/lab/cmpm/

    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] ダイヤモンド合成方法およびダイヤモンド合成装置2018

    • Inventor(s)
      本間格、笘居高明、小林弘明、石黒駿一
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-017754
    • Filing Date
      2018
    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2022-01-27  

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