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Novel phenomena in the incommensurate orbital/charge ordered state

Research Project

Project/Area Number 16H04020
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionWaseda University

Principal Investigator

Katsufuji Takuro  早稲田大学, 理工学術院, 教授 (00272386)

Co-Investigator(Kenkyū-buntansha) 和達 大樹  東京大学, 物性研究所, 准教授 (00579972)
森 茂生  大阪府立大学, 工学(系)研究科(研究院), 教授 (20251613)
奥田 哲治  鹿児島大学, 理工学域工学系, 准教授 (20347082)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2018: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2016: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Keywords軌道整列 / 電荷整列 / 非整合 / 緩和現象 / 緩和 / 強相関電子系
Outline of Final Research Achievements

We have investigated the incommensurate superstructures caused by the orbital and charge ordering of d electrons in transition-metal oxides and have studied the exotic physical properties caused by such ordering. We have found characteristic incommensurate superstructures in hollandite Ti oxides with double chains of Ti ions and the V oxides with quasi-triangular lattices of V ions, and have found the anomalies associated with such ordering in transport, magnetic, and thermal properties. From these measurements, we have clarified the physics of incommensurate orbital/charge ordering and have opened up a way in the research of strongly correlated electron systems.

Academic Significance and Societal Importance of the Research Achievements

物性物理の研究分野の中でも、現在最も活発な研究が進んでいる強相関電子系の研究において、非整合な軌道/電荷秩序という新たな研究分野を作り上げることができた。さらに本研究で扱ったホランダイト型Ti酸化物においては、大きな熱起電力、高い電気伝導度、低い熱伝導度を持つことから、新たなn型熱電材料としても期待されている。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (23 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (5 results) Journal Article (11 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 11 results) Presentation (7 results) (of which Int'l Joint Research: 7 results,  Invited: 7 results)

  • [Int'l Joint Research] University of Rome(イタリア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University of Rome(Italy)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University of Virginia/MIT(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University of Rome(Italy)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University of Virginia(米国)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Magnetotransport Properties of the Orbital-Ordered State of Ba1-xSrxV13O182019

    • Author(s)
      Funahashi Kazuma、Kakesu Yu、Kajita Tomomasa、Obata Yoshihito、Katayama Yumiko、Ueno Kazunori、Suzuki Takehito、Checkelsky Joseph George、Katsufuji Takuro
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 88 Issue: 2 Pages: 024708-024708

    • DOI

      10.7566/jpsj.88.024708

    • NAID

      210000135105

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transport, magnetic, thermoelectric, and structural properties of hollandite titanates BaxTi8O16+δ2018

    • Author(s)
      Yamashita Y.、Okuda T.、Mori S.、Horibe Y.、Murata R.、Katsufuji T.
    • Journal Title

      Physical Review Materials

      Volume: 2 Issue: 7 Pages: 074409-074409

    • DOI

      10.1103/physrevmaterials.2.074409

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Doping effect on orthorhombic Sr2VO4 with s=1/2 dimers2018

    • Author(s)
      Funahashi K.、Higashide T.、Ueno T.、Tasaki K.、Tahara Y.、Adachi M.、Saiki T.、Kajita T.、Katsufuji T.
    • Journal Title

      Physical Review B

      Volume: 98 Issue: 18 Pages: 184422-184422

    • DOI

      10.1103/physrevb.98.184422

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal conductivity of SrVO3-SrTiO3 thin films: Evidence of intrinsic thermal resistance at the interface between oxide layers2018

    • Author(s)
      Katsufuji T.、Saiki T.、Okubo S.、Katayama Y.、Ueno K.
    • Journal Title

      Physical Review Materials

      Volume: 2 Issue: 5

    • DOI

      10.1103/physrevmaterials.2.051002

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trimerization and orbital ordering in Ba1-xSxV13O182017

    • Author(s)
      T. Kajita, Y. Obata, Y. Kakesu, Y. Imai, Y. Shmizu, M. Itoh, H. Kuwahara, T. Katsufuji
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 24 Pages: 245126-245126

    • DOI

      10.1103/physrevb.96.245126

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photoinduced phase transitions over three phases in Ba0.9Sr0.1V13O182017

    • Author(s)
      Saiki T.、Yamaguchi N.、Obata Y.、Kakesu Y.、Kajita T.、Katsufuji T.
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 3 Pages: 035133-035133

    • DOI

      10.1103/physrevb.96.035133

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anomalous relaxation behavior in the resistivity and magnetization of La5Mo4O162017

    • Author(s)
      Mizuno Y.、Hasegawa T.、Katsufuji T.
    • Journal Title

      Physical Review B

      Volume: 95 Issue: 22 Pages: 224436-224436

    • DOI

      10.1103/physrevb.95.224436

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Time-of-flight elastic and inelastic neutron scattering studies on localized 4d electron layered perovskite compound La5Mo4O162017

    • Author(s)
      K. Iida, R. Kajimoto, Y. Mizuno, K. Kamazawa, Y. Inamura, A. Hoshikawa, Y. Yoshida, T. Matsukawa, T. Ishigaki, Y. Kawamura, S. Ibuka, T. Yokoo, S. Itoh, and T. Katsufuji
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 86 Issue: 6 Pages: 064803-064803

    • DOI

      10.7566/jpsj.86.064803

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unusual valence state and metal-insulator transition in BaV10O15 probed by hard x-ray photoemission spectroscopy2017

    • Author(s)
      T. Yoshino, M. Okawa, T. Kajita, S. Dash, R. Shimoyama, K. Takahashi, Y. Takahashi, R. Takayanagi, T. Saitoh, D. Ootsuki, T. Yoshida, E. Ikenaga, N. L. Saini, T. Katsufuji, and T. Mizokawa
    • Journal Title

      Phys. Rev. B

      Volume: 95 Issue: 7

    • DOI

      10.1103/physrevb.95.075151

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photoinduced dynamics in doped Mott insulators with polaronic conduction: Ba2Ti13O22 and BaxTi8O162016

    • Author(s)
      N. Yamaguchi, A. Furuhashi, H. Nishihara, R. Murata, K. Takayama, and T. Katsufuji
    • Journal Title

      Phys. Rev. B

      Volume: 94 Issue: 4

    • DOI

      10.1103/physrevb.94.045119

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic field and in situ stress dependence of elastic behavior in EuTiO3 from resonant ultrasound spectroscopy2016

    • Author(s)
      Jason Schiemer, Leszek J. Spalek, Siddharth S. Saxena, Christos Panagopoulos, Takuro Katsufuji, Annette Bussmann-Holder, Jurgen Kohler, and Michael A. Carpenter
    • Journal Title

      Phys. Rev. B

      Volume: 93 Issue: 5

    • DOI

      10.1103/physrevb.93.054108

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Anomalous metal-insulator transitionin V, Nb, and Ta oxides2019

    • Author(s)
      Takuro Katsufuji
    • Organizer
      19th Japan-Korea-Taiwan Symposium on Strongly Correlated Electron Systems
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Charge ordering and thermoelectric properties in Hollandite Titanates2018

    • Author(s)
      T. Katsufuji
    • Organizer
      The 18th Taiwan-Japan-Korea Symposium on Strongly Correlated Electron Systems (TJK2018)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Orbital degrees of freedom and thermal properties for various titanates and vanadates2017

    • Author(s)
      T. Katsufuji
    • Organizer
      Physics and chemistry of emerging superconductors and thermoelectric materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Coupling between the lattice distortion and the orbital/charge degrees of freedom in various transition-metal oxides2017

    • Author(s)
      T. Katsufuji
    • Organizer
      2nd International Symposium on Negative Thermal Expansion and Related Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photoinduced phase transitions over three phases in AV13O182017

    • Author(s)
      T. Katsufuji, T. Saiki, N. Yamaguchi, Y. Kakesu, and T. Kajita
    • Organizer
      17th Korea-Taiwan-Japan Workshop on Strongly Correlated Electron System
    • Place of Presentation
      Yong Pyong Resort , Korea
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Competing phases in AV13O18 (A=Ba, Sr) with V quasi-fcc lattice2016

    • Author(s)
      T. Katsufuji
    • Organizer
      ICSM2016
    • Place of Presentation
      Fethiye, Turkey
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Anomalous relaxation behavior in La5Mo4O16 as a possible spin/charge-coupled system2016

    • Author(s)
      T. Katsufuji
    • Organizer
      The 8th APCTP Workshop on Multiferroics
    • Place of Presentation
      Shanghai, China
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2022-05-20  

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