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Investigation of ancient methane seepage in Sakhalin using silica clathrate minerals

Research Project

Project/Area Number 16H05742
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section海外学術
Research Field Petrology/Mineralogy/Economic geology
Research InstitutionNational Museum of Nature and Science, Tokyo

Principal Investigator

Momma Koichi  独立行政法人国立科学博物館, 地学研究部, 研究主幹 (30552781)

Co-Investigator(Kenkyū-buntansha) 長瀬 敏郎  東北大学, 学術資源研究公開センター, 准教授 (10237521)
ジェンキンズ ロバート  金沢大学, 地球社会基盤学系, 准教授 (10451824)
谷 健一郎  独立行政法人国立科学博物館, 地学研究部, 研究主幹 (70359206)
井尻 暁  国立研究開発法人海洋研究開発機構, 超先鋭研究開発部門(高知コア研究所), 主任研究員 (70374212)
宮脇 律郎  独立行政法人国立科学博物館, 地学研究部, 部長 (80290865)
Project Period (FY) 2016-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2020: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2019: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2018: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2017: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2016: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Keywordsシリカクラスレート鉱物 / メタン湧水 / メラノフロジャイト / 千葉石 / 房総石 / リシカクラスレート / シリカクラスレート / 天然ガス
Outline of Final Research Achievements

Minerals containing natural gas molecules in their crystal structures (silica clathrate minerals) and their decomposed materials (quartz pseudomorphs after silica clathrate minerals) were identified from several areas in southwestern Sakhalin, providing direct evidence of natural gas that has disappeared from the formation. Two types of mineralization were identified: (1) in calcareous concretions in sedimentary rocks in association with fossils of chemosynthetic communities, and (2) in silica and calcareous veins associated with small igneous bodies intruded into sedimentary rocks. Isotope values suggest that the latter natural gas also originated from pyrolysis of organic matter in sedimentary rocks, indicating that carbon cycling occurs with igneous rocks as the heat source.

Academic Significance and Societal Importance of the Research Achievements

有機物として堆積物中に取り込まれた炭素が、地熱により分解し、天然ガスとして地層外に湧出する過程を調べる手掛かりとして、シリカクラスレート鉱物が新たな物証となることを提示した。シリカクラスレート鉱物は地層からは消失した天然ガスを保持しているだけでなく、シリカクラスレート鉱物が分解したときにできるシリカ鉱物組織を判別することで、天然ガスの湧出があったことを示す直接的な証拠が、より広範にわたって得られることがわかった。

Report

(6 results)
  • 2022 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (37 results)

All 2021 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (6 results) Journal Article (17 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 16 results,  Open Access: 5 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results)

  • [Int'l Joint Research] Russian Academy of Science(ロシア連邦)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Universitat Wien, Althanstrasse(オーストリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Far East Geological Institute(ロシア連邦)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Universitat Wien(オーストリア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Far East Geological Institute(ロシア連邦)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Far East Geological Institute/SB RAS(ロシア連邦)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Bosoite, a new silica clathrate mineral from Chiba Prefecture, Japan2020

    • Author(s)
      Momma Koichi、Ikeda Takuji、Nagase Toshiro、Kuribayashi Takahiro、Honma Chibune、Nishikubo Katsumi、Takahashi Naoki、Takada Masayuki、Matsushita Yoshitaka、Miyawaki Ritsuro、Matsubara Satoshi
    • Journal Title

      Mineralogical Magazine

      Volume: 84 Issue: 6 Pages: 941-948

    • DOI

      10.1180/mgm.2020.91

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Transformation pathways and isothermal compressibility of a MTN-type clathrasil using penetrating and non-penetrating fluids2019

    • Author(s)
      Scheidl K.S.、Effenberger H.S.、Yagi T.、Momma K.、Miletich R.
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 273 Pages: 73-89

    • DOI

      10.1016/j.micromeso.2018.06.033

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Isotherms of individual pores by gas adsorption crystallography2019

    • Author(s)
      Cho Hae Sung、Yang Jingjing、Gong Xuan、Zhang Yue-Biao、Momma Koichi、Weckhuysen Bert M.、Deng Hexiang、Kang Jeung Ku、Yaghi Omar M.、Terasaki Osamu
    • Journal Title

      Nature Chemistry

      Volume: 11 Issue: 6 Pages: 562-570

    • DOI

      10.1038/s41557-019-0257-2

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The hydrocarbon-bearing clathrasil chibaite and its host?guest structure at low temperature2018

    • Author(s)
      Scheidl K. S.、Effenberger H. S.、Yagi T.、Momma K.、Miletich Ronald
    • Journal Title

      IUCrJ

      Volume: 5 Issue: 5 Pages: 595-607

    • DOI

      10.1107/s2052252518009107

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Iyoite, MnCuCl(OH)3 and misakiite, Cu3Mn(OH)6Cl2: new members of the atacamite family from Sadamisaki Peninsula, Ehime Prefecture, Japan2017

    • Author(s)
      Nishio-hamane D.、Momma K.、Ohnishi M.、Shimobayashi N.、Miyawaki R.、Tomita N.、Okuma R.、Kampf A. R.、Minakawa T.
    • Journal Title

      Mineralogical Magazine

      Volume: 81 Issue: 3 Pages: 485-498

    • DOI

      10.1180/minmag.2016.080.104

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] CRYSTAL STRUCTURES OF POTASSIUM TETRA-SILICIC FLUORO-MICAS2017

    • Author(s)
      Ritsuro Miyawaki,Koichi Momma,Maki Okube,Akira Yoshiasa,Shun-Ichi Ohta
    • Journal Title

      Clay Science

      Volume: 21 Issue: 3 Pages: 41-54

    • DOI

      10.11362/jcssjclayscience.21.3_41

    • NAID

      130006120062

    • ISSN
      0009-8574, 2186-3555
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kurchatovite from the Fuka mine, Okayama Prefecture, Japan2017

    • Author(s)
      Hayashi A., K. Momma, R. Miyawaki, M. Tanabe, S. Kishi, S. Kobayashi and I. Kusachi
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 112 Issue: 4 Pages: 159-165

    • DOI

      10.2465/jmps.170330

    • NAID

      130006044231

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chibaite, a new mineral discovered from Minamiboso, Chiba Prefecture, Japan2017

    • Author(s)
      門馬綱一
    • Journal Title

      Japanese Magazine of Mineralogical and Petrological Sciences

      Volume: 46 Issue: 1 Pages: 47-49

    • DOI

      10.2465/gkk.161222

    • NAID

      130005475602

    • ISSN
      1345-630X, 1349-7979
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between crystal morphology and twin boundary structures of quartz twinned in accordance with Japan law2017

    • Author(s)
      門馬綱一
    • Journal Title

      Japanese Magazine of Mineralogical and Petrological Sciences

      Volume: 46 Issue: 1 Pages: 35-41

    • DOI

      10.2465/gkk.161220

    • NAID

      130005475599

    • ISSN
      1345-630X, 1349-7979
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mineral species of alkaline-carbonatite complexes in Brazil2017

    • Author(s)
      Horiuchi, H., T. Ozawa, N. Haga, O. Tachikawa, N. Aikawa, R. Miyawaki, K. Momma, T. Sano, M. Shigeoka and S. Matsubara
    • Journal Title

      Bulletin of the National Museum of Nature and Science, Series C

      Volume: 43 Pages: 27-48

    • NAID

      40021490862

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Raman spectroscopy of chibaite, natural MTN silica clathrate, at high pressure up to 8 GPa2016

    • Author(s)
      Likhacheva Anna Yu.、Goryainov Sergey V.、Seryotkin Yuriy V.、Litasov Konstantin D.、Momma Koichi
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 224 Pages: 100-106

    • DOI

      10.1016/j.micromeso.2015.11.033

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chevkinite-bearing tuffs from the Boso and Noto peninsulas in central Japan and from Primorye, Far East Russia2016

    • Author(s)
      K. Momma, Y. Tsutsumi, T. Sano, R. Miyawaki, M. Shigeoka and K. Yokoyama
    • Journal Title

      Memoirs of the National Museum of Nature and Science

      Volume: 51 Pages: 89-98

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Kimuraite-(Y), a layered hydrous carbonate of calcium and rare earths, from Voznesenskii, Russia2016

    • Author(s)
      R. Miyawaki, K. Momma, T. Sano, M. Shigeoka, Y. Tsutsumi, S.A. Kasatkin
    • Journal Title

      Memoirs of the National Museum of Nature and Science

      Volume: 51 Pages: 99-108

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Bunnoite, a new hydrous manganese aluminosilicate from Kamo Mountain, Kochi Prefecture, Japan.2016

    • Author(s)
      Nishio-Hamane D., Momma K., Miyawaki R., Minakawa T.
    • Journal Title

      Mineralogy and Petrology

      Volume: 110 Issue: 6 Pages: 917-926

    • DOI

      10.1007/s00710-016-0454-2

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A CO3-bearing member of the hydroxylapatite?hydroxylellestadite series from Tadano, Fukushima Prefecture, Japan: CO3-SO4 substitution in the apatite?ellestadite series2016

    • Author(s)
      Banno Y.、Miyawaki R.、Momma K.、Bunno M.
    • Journal Title

      Mineralogical Magazine

      Volume: 80 Issue: 2 Pages: 363-370

    • DOI

      10.1180/minmag.2016.080.005

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Eclarite and other Bi-minerals from the Jishakuyama ore deposit of the Akagane mine, Iwate Prefecture, Japan2016

    • Author(s)
      S. Harada, Y. Suzuki, R. Miyawaki, K. Momma, M. Shigeoka and S. Matsubara
    • Journal Title

      Bulletin of the National Museum of Nature and Science, Series C

      Volume: 42 Pages: 19-27

    • NAID

      40021148704

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 講座:ご当地の化学 千葉県/関東支部 千葉で発見された新鉱物「千葉石」2016

    • Author(s)
      門馬綱一
    • Journal Title

      化学と教育

      Volume: 64 Pages: 612-615

    • Related Report
      2016 Annual Research Report
  • [Presentation] 北部フォッサマグナ地域から産出した千葉石の続報2021

    • Author(s)
      門馬綱一・宮島 宏・下林典正・石橋 隆・高山信之・長瀬敏郎・宮脇律郎・松原 聰・井尻 暁・古川 善博
    • Organizer
      日本鉱物科学会2021年年会, 2021.9.17, 広島大学, 東広島(Online大会)
    • Related Report
      2020 Annual Research Report
  • [Presentation] メラノフロジャイトと千葉石のゲスト分子の分子ダイナミクス2021

    • Author(s)
      平沼こうた・門馬綱一・景山真帆・白石柚衣・岡村英一・野口直樹
    • Organizer
      日本鉱物科学会2021年年会, 2021.9.17, 広島大学, 東広島(Online大会)
    • Related Report
      2020 Annual Research Report
  • [Presentation] Evaluation of the best weighting schemefor the maximum entropy Patterson method2019

    • Author(s)
      K. Momma
    • Organizer
      XIX International Meeting on Crystal Chemistry, X-ray Diffraction and Spectroscopy of Minerals
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] sII型シリカクラスレート『千葉石』の骨格構造とゲスト分子の挙動2019

    • Author(s)
      門馬綱一
    • Organizer
      シンポジウム「H2Oを科学する」
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Occurrences and crystal structures of melanophlogite from Sakhalin, Far East Russia2018

    • Author(s)
      K. Momma, T. Nagase, R. Jenkins, Y. Miyajima, K. Tani, A. Ijiri, S. Kasatkin, I. Chekryzhov, R. Miyawaki,
    • Organizer
      XXII Meeting of the International Mineralogical Association
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ロシア極東サハリンから産出したメラノフロジャイトの単結晶X線回折実験2018

    • Author(s)
      門馬綱一・長瀬敏郎・ジェンキンズ ロバート・宮嶋佑典・谷健一郎・井尻暁・Sergei Kasatkin・Igor Chekryzhov・宮脇律郎
    • Organizer
      日本地球惑星科学連合2018年大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] シリカ鉱物の仮像組織2018

    • Author(s)
      長瀬敏郎・門馬綱一・石橋隆・浜根大輔・栗林貴弘
    • Organizer
      日本鉱物科学会2018年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] The crystal chemistry of sakuraiite2017

    • Author(s)
      Momma, K., R. Miyawaki, S. Matsubara, T. Nagase, S. Kamada, S. Ozawa, E. Ohtani, M. Shimizu, A. Kato
    • Organizer
      24th Congress and General Assembly of the International Union of Crystallography
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] サハリン南部におけるシリカクラスレート鉱物の産状2017

    • Author(s)
      門馬綱一・谷健一郎・宮脇律郎・長瀬敏郎
    • Organizer
      日本鉱物科学会2017年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] サハリンにおけるシリカクラスレート鉱物の新産地2016

    • Author(s)
      門馬綱一 宮脇律郎 谷 健一郎
    • Organizer
      地球惑星科学連合2016年大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] ブラジルミナスジェライス州産のパイロクロア2016

    • Author(s)
      門馬綱一 松原 聰 宮脇律郎 佐野貴司 重岡昌子 堀内弘之
    • Organizer
      日本鉱物科学会2016年年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] X型日本式双晶に見る接合面ごとの成長速度異方性2016

    • Author(s)
      門馬綱一 長瀬敏郎
    • Organizer
      日本鉱物科学会2016年年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 櫻井鉱の単結晶X線構造解析2016

    • Author(s)
      門馬綱一 宮脇律郎 松原聰 重岡昌子 加藤昭 清水正明 長瀬敏郎
    • Organizer
      日本結晶学会平成28年度年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] シリカクラスレート鉱物の地球科学2016

    • Author(s)
      門馬綱一
    • Organizer
      第 20 回規則性多孔体セミナー
    • Related Report
      2016 Annual Research Report
    • Invited

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Published: 2016-04-21   Modified: 2024-01-30  

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