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Development of the environmental remediation materials for decomposition of refractory organic matter in marine sediments using the oxidation catalyst doped granulated coal ash

Research Project

Project/Area Number 16H05892
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Modeling and technologies for environmental conservation and remediation
Research InstitutionKobe University

Principal Investigator

ASAOKA Satoshi  神戸大学, 内海域環境教育研究センター, 助教 (60548981)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥23,530,000 (Direct Cost: ¥18,100,000、Indirect Cost: ¥5,430,000)
Fiscal Year 2019: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2018: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Keywords残留性有機汚染物質 / 有機フッ素化合物 / 難分解性有機物 / 瀬戸内海 / 堆積物 / 石炭灰造粒物 / ヒューミン / 全有機炭素濃度 / 石炭灰 / 酸化触媒 / 閉鎖性水域 / リサイクル / ゼロ価鉄 / フェリハイドライト / フミン酸 / フルボ酸 / 海産性粒状有機物 / 酸化チタン / 環境材料 / 環境技術 / 海洋保全 / 海底堆積物 / 水圏現象 / 水質汚濁・土壌汚染防止・浄化
Outline of Final Research Achievements

The purposes of this study are to (1) quantify labile and refractory organic matter in coastal marine sediments from the Seto Inland Sea, Japan, and to (2) develop an environmental remediation material for decomposition of refractory organic matter in marine sediments. Refractory organic matter content in sediments ranged from 4.7 to 21.4 mg/g, a percent composition equivalent to 72 to 94% of TOC. The concentrations of perfluorocarboxylic acid in surface sediments from the Sea ranged from 0.05 to 0.67 ng/g. The concentrations of HCHs, DDTs, and CHLs in sediments from the Sea were <0.002 to 1.20 ng/g, 0.01 to 2.51 n/g, and 0.01 to 0.48 ng/g, respectively. The organic matter decomposition experiments were carried out to optimize the environmental remediation materials. When the granulated coal ash which was prepared by mixing coal fly ash and blast furnace cement was applied to the sediments, the organic matter decomposition was enhanced compared to control.

Academic Significance and Societal Importance of the Research Achievements

近年,河川や湖沼の有機物の組成が生物に分解されにくい難分解性成分が増えている報告を受け,本研究では知見が不足している沿岸域の堆積物に含まれる難分解性有機物を定量的に把握した点で学術的意義がある.また,ストックホルム条約の発効によって,随時,廃絶・使用が制限されたはずの残留性農薬が,近年堆積したと考えられる瀬戸内海表層堆積物において検出されていることがわかった.引き続き,残留性有機汚染物質の環境動態の解明が必要であることを示した点で学術的・社会的意義がある.

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (7 results)

All 2020 2019 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (6 results) (of which Int'l Joint Research: 1 results,  Invited: 3 results)

  • [Journal Article] Persistent organic pollutants are still present in surface marine sediments from the Seto Inland Sea, Japan2019

    • Author(s)
      Asaoka Satoshi、Umehara Akira、Haga Yuki、Matsumura Chisato、Yoshiki Ryosuke、Takeda Kazuhiko
    • Journal Title

      Marine Pollution Bulletin

      Volume: 149 Pages: 110543-110543

    • DOI

      10.1016/j.marpolbul.2019.110543

    • NAID

      120006719418

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] 富栄養な海、貧栄養な海、それぞれの環境修復技術2020

    • Author(s)
      浅岡 聡
    • Organizer
      神戸大学内海域環境教育研究センター ,アジア太平洋地球変動研究ネットワーク(APN),公益財団法人 国際エメックスセンター共催セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] Remediation of eutrophic sediments using granulated coal ash derived from coal fired generation2019

    • Author(s)
      Satoshi ASAOKA、Takahito OIKAWA、 Hideaki NOHARA
    • Organizer
      4th Green & sustainable Chemistry Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 閉鎖性水域の堆積物中の硫黄の化学形態と石炭灰造粒物を利用した閉鎖性水域の底質改善法2019

    • Author(s)
      浅岡 聡
    • Organizer
      2019年度立命館大学SRセンター成果報告会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 火力発電所からの石炭灰をリサイクルした環境修復材料の開発2019

    • Author(s)
      浅岡 聡
    • Organizer
      はりま産学交流会創造例会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 瀬戸内海の表層堆積物の分解特性と腐植物質組成2019

    • Author(s)
      浅岡 聡,Jadoon Waqar,竹田一彦,梅原 亮,藤嶽暢英
    • Organizer
      第53回日本水環境学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 石炭灰造粒物を用いた閉鎖性水域の環境改善2017

    • Author(s)
      浅岡 聡,山本民次,早川慎二郎,井上智子
    • Organizer
      日本セラミクス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited

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Published: 2016-04-21   Modified: 2021-02-19  

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