• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

耐放射線性を有す高効率太陽電池および低損失電力変換素子用材料の開発

Research Project

Project/Area Number 16J04128
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Aerospace engineering
Research InstitutionKyushu University

Principal Investigator

草場 彰  九州大学, 工学府, 特別研究員(DC1)

Project Period (FY) 2016-04-22 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2018: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2017: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2016: ¥700,000 (Direct Cost: ¥700,000)
KeywordsIII族窒化物半導体 / 有機金属気相成長 / 表面再構成 / 第一原理計算 / 非平衡量子熱力学 / 結晶成長 / 溶液成長 / 固液界面 / その場観察
Outline of Annual Research Achievements

III族窒化物半導体の窒化ガリウム(GaN)は,高耐圧・低損失な次世代の電力変換素子(パワーデバイス)用材料として期待されている.また,III族窒化物半導体は耐放射線性に優れているため宇宙利用に適している.縦型GaNパワーデバイスの実現に向けては,低炭素濃度のGaNエピタキシャル層(ドリフト層)を,高速に成長させる必要がある.成長速度(成長駆動力)の解析には,平成28年度に開発した表面構造(面方位・再構成)依存の熱力学解析手法が活用できた.平成29年度は,非平衡量子熱力学に基づく化学吸着モデルを開発した.本年度は,この化学吸着モデルを活用し,GaN有機金属気相成長における炭素不純物混入の面方位依存性を解析した.従来,原料分子の吸着に関しては,吸着エネルギーと分子の化学ポテンシャル比較による解析が行われ,吸着が優位に生じるか否かが理解されてきた.本研究では,前述のモデルによって,不純物分子(メタン)吸着を定量的に解析し,Ga極性面・N極性面における吸着確率の比を求めた.この結果は表面構造(面方位・再構成)に依存するものである.報告されている炭素不純物濃度の面方位依存性についての実験結果は,メタン吸着確率の面方位依存性だけでは,説明付けることができなかった.そこで,結晶表面第1層における不純物原子の安定性まで考慮した不純物混入モデルを提案し,実験結果を説明することができた.以上,本研究課題で提案した「表面構造を考慮する成長速度解析手法・炭素不純物濃度解析手法」は,GaN有機金属気相成長の成長条件最適化に貢献できるものと考える.さらに,他の半導体結晶・成長面方位・気相成長法・不純物原子への適用も期待される.

Research Progress Status

平成30年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

平成30年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (29 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (6 results) Journal Article (5 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 5 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (18 results) (of which Int'l Joint Research: 9 results,  Invited: 2 results)

  • [Int'l Joint Research] Institute of High Pressure Physics(ポーランド)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Virginia Tech(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Institute of High Pressure Physics(Poland)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Virginia Tech(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Institute of High Pressure Physics(Poland)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Virginia Tech(米国)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] CH4 Adsorption Probability on GaN(0001) and (000-1) during Metalorganic Vapor Phase Epitaxy and Its Relationship to Carbon Contamination in the Films2019

    • Author(s)
      Kusaba Akira、Li Guanchen、Kempisty Pawel、von Spakovsky Michael、Kangawa Yoshihiro
    • Journal Title

      Materials

      Volume: 12 Issue: 6 Pages: 972-972

    • DOI

      10.3390/ma12060972

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Thermodynamic analysis of (0001) and $(000\bar{1})$ GaN metalorganic vapor phase epitaxy2017

    • Author(s)
      Kusaba Akira、Kangawa Yoshihiro、Kempisty Pawel、Valencia Hubert、Shiraishi Kenji、Kumagai Yoshinao、Kakimoto Koichi、Koukitu Akinori
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 7 Pages: 070304-070304

    • DOI

      10.7567/jjap.56.070304

    • NAID

      210000147978

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Modeling the Non-Equilibrium Process of the Chemical Adsorption of Ammonia on GaN(0001) Reconstructed Surfaces Based on Steepest-Entropy-Ascent Quantum Thermodynamics2017

    • Author(s)
      Kusaba Akira、Li Guanchen、von Spakovsky Michael、Kangawa Yoshihiro、Kakimoto Koichi
    • Journal Title

      Materials

      Volume: 10 Issue: 8 Pages: 948-948

    • DOI

      10.3390/ma10080948

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] DFT modeling of carbon incorporation in GaN(0001) and GaN(000-1) metalorganic vapor phase epitaxy2017

    • Author(s)
      Kempisty Pawel、Kangawa Yoshihiro、Kusaba Akira、Shiraishi Kenji、Krukowski Stanislaw、Bockowski Michal、Kakimoto Koichi、Amano Hiroshi
    • Journal Title

      Applied Physics Letters

      Volume: 111 Issue: 14 Pages: 141602-141602

    • DOI

      10.1063/1.4991608

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Advances in modeling semiconductor epitaxy: Contributions of growth orientation and surface reconstruction to InN metalorganic vapor phase epitaxy2016

    • Author(s)
      A. Kusaba, Y. Kangawa, P. Kempisty, K. Shiraishi, K. Kakimoto, A. Koukitu
    • Journal Title

      Applied Physics Express

      Volume: 9 Issue: 12 Pages: 125601-125601

    • DOI

      10.7567/apex.9.125601

    • NAID

      210000138129

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Formation Mechanism of Singular Structure in AlInN Layer Grown on M-GaN substrate by MOVPE2018

    • Author(s)
      Yuya Inatomi, Akira Kusaba, Yoshihiro Kangawa, Kazunobu Kojima, Shigefusa Chichibu
    • Organizer
      6th International Conference on Light-Emitting Devices and Their Industrial Applications (LEDIA '18)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] GaN-MOVPE成長におけるCH4吸着確率とC不純物濃度の面方位依存性2018

    • Author(s)
      草場彰,李冠辰,パヴェウ・ケンピスティ,マイケル・フォン・スパコフスキー,寒川義裕
    • Organizer
      第10回ナノ構造・エピタキシャル成長講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Relationship between the CH4 Adsorption Probability and the C Impurity Concentration in the Polar-GaN MOVPE System2018

    • Author(s)
      Akira Kusaba, Guanchen Li, Michael R. von Spakovsky, Pawel Kempisty, Yoshihiro Kangawa
    • Organizer
      7th International Symposium on Growth of III-Nitrides (ISGN-7)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 窒化ガリウム極性面におけるメタン吸着確率と炭素不純物取り込み2018

    • Author(s)
      草場彰,李冠辰,パヴェウ・ケンピスティ,マイケル・フォン・スパコフスキー,寒川義裕
    • Organizer
      日本学術振興会第162委員会第110回研究会・特別公開シンポジウム『紫外発光デバイスの最前線と将来展望』
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Non-equilibrium analysis of CH4 adsorption on GaN(0001) and (000-1): the growth orientation dependence of the C impurity concentration2018

    • Author(s)
      Akira Kusaba, Guanchen Li, Pawel Kempisty, Michael R. von Spakovsky, Yoshihiro Kangawa
    • Organizer
      International Workshop on Nitride Semiconductors 2018 (IWN 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Driving force for m-plane GaN MOVPE: a new thermodynamic modeling2018

    • Author(s)
      Akira Kusaba, Yoshihiro Kangawa, Kenji Shiraishi
    • Organizer
      10th International Symposium on Advanced Plasma Science and its Applications for Nitrides and Nanomaterials (ISPlasma 2018)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MOVPE成長m面AlInN/GaNヘテロ構造における特異構造(2)2018

    • Author(s)
      稲富悠也,草場彰,柿本浩一,寒川義裕,小島一信,秩父重英
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] NH3化学吸着の非平衡状態発展:最急エントロピー勾配量子熱力学モデリング2017

    • Author(s)
      草場彰,Guanchen Li,Michael R. von Spakovsky,寒川義裕,柿本浩一
    • Organizer
      第9回ナノ構造・エピタキシャル成長講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Steepest-entropy-ascent quantum thermodynamic behavior of ammonia chemical adsorption on GaN(0001) surfaces under MOVPE2017

    • Author(s)
      Akira Kusaba,Guanchen Li,Michael R. von Spakovsky,Yoshihiro Kangawa,Koichi Kakimoto
    • Organizer
      E-MRS 2017 Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermodynamic Modeling of GaN MOVPE: Contribution of Surface State2017

    • Author(s)
      Akira Kusaba,Yoshihiro Kangawa,Pawel Kempisty,Kenji Shiraishi,Koichi Kakimoto,Akinori Koukitu
    • Organizer
      International Conference on Materials and Systems for Sustainability 2017 (ICMaSS 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Adsorption of ammonia in III-nitrides vapor phase epitaxy: theoretical approach based on steepest-entropy-ascent quantum thermodynamics2017

    • Author(s)
      Akira Kusaba,Guanchen Li,Michael R. von Spakovsky,Yoshihiro Kangawa
    • Organizer
      International Workshop on UV Materials and Devices 2017 (IWUMD 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] GaN(0001)におけるNH3吸着過程の非平衡量子熱力学モデリング:付着係数の理論解析2017

    • Author(s)
      草場彰,李冠辰,マイケル・ヴォン・スパコフスキー,寒川義裕,柿本浩一
    • Organizer
      第46回結晶成長国内会議 (JCCG-46)
    • Related Report
      2017 Annual Research Report
  • [Presentation] GaN MOVPE法における基板面方位依存性を考慮した流れの影響I2017

    • Author(s)
      川上賢人,高村昴,山本芳裕,草場彰,芳松克則,岡本直也,寒川義裕,柿本浩一,白石賢二
    • Organizer
      第46回結晶成長国内会議 (JCCG-46)
    • Related Report
      2017 Annual Research Report
  • [Presentation] GaN MOVPE法における基板面方位依存性を考慮した流れの影響II2017

    • Author(s)
      高村昴,川上賢人,山本芳裕,草場彰,芳松克則,岡本直也,寒川義裕,柿本浩一,白石賢二
    • Organizer
      第46回結晶成長国内会議 (JCCG-46)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Influence of Growth Orientation on Driving Force for InN Deposition by MOVPE2016

    • Author(s)
      A. Kusaba, Y. Kangawa, M. R. von Spakovsky, K. Shiraishi, K. Kakimoto, A. Koukitu
    • Organizer
      International Workshop on Ntride Semiconductors 2016
    • Place of Presentation
      Orlando (USA)
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermodynamic analysis of InN metalorganic vapor phase epitaxy: influence of growth orientation and surface reconstruction2016

    • Author(s)
      A. Kusaba, Y. Kangawa, K. Kakimoto, K. Shiraishi, H. Amano, A. Koukitu
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Nagoya (Japan)
    • Year and Date
      2016-08-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] InおよびN極性InN有機金属気相成長の熱力学解析2016

    • Author(s)
      草場彰,寒川義裕,柿本浩一,白石賢二,纐纈明伯
    • Organizer
      第35回電子材料シンポジウム
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県・守山市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] InN(0001)面および(000-1)面MOVPE成長の熱力学解析2016

    • Author(s)
      草場彰,寒川義裕,白石賢二,柿本浩一,纐纈明伯
    • Organizer
      第8回窒化物半導体結晶成長講演会
    • Place of Presentation
      京都大学桂キャンパス(京都府・京都市)
    • Year and Date
      2016-05-09
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2016-05-17   Modified: 2024-03-26  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi