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グラフェンナノリボンの原子配列構造を活用した電子デバイス

Research Project

Project/Area Number 16K04897
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Han Patrick  東北大学, 原子分子材料科学高等研究機構, 助教 (80642181)

Co-Investigator(Kenkyū-buntansha) 渡邊 源規  九州大学, カーボンニュートラル・エネルギー国際研究所, 助教 (60700276)
岡田 健  東北大学, 流体科学研究所, 助教 (90616385)
Project Period (FY) 2016-04-01 – 2017-03-31
Project Status Discontinued (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
KeywordsSelf-assembly / Graphene / Nanoribbons / ナノカーボン応用
Outline of Annual Research Achievements

The aim of this proposal is to advance graphene nanoribbon (GNR) fabrication by self-assembly for the purpose of transport-devices fabrication that can elucidate the unique effects of the exact graphene atomic structures on its electromagnetic properties. We have obtained both theoretical and experimental results that are pertinent towards the goal of fabricating the first precise zigzag-edge GNR device, with properties directly accessible from the macroscopic scale. Both these results address the effects of chemical functional groups of the precursor molecules on the length of the final GNR product after self-assembly. We have developed a new mathematical equivalence sampling method to model the assembly of precursor molecules with arbitrary functional groups, to predict the final morphology of the GNR products. We have also used experiments to test the effects of select functional groups on the precursor molecules to determine the actual effects of these functional groups on the morphology of the final GNR products. From these two sets of results, we have elucidated the mechanism of GNR fabrication by self-assembly using select precursor molecules. These results directly contribute to the ultimate goal of this project.

Report

(1 results)
  • 2016 Annual Research Report
  • Research Products

    (4 results)

All 2017 2016

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Open Access: 2 results) Presentation (1 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Chemical and entropic control on the molecular self-assembly process2017

    • Author(s)
      Packwood, D. M., Han, P., Hitosugi, T.
    • Journal Title

      Nature Communication

      Volume: 8 Issue: 1 Pages: 14463-14463

    • DOI

      10.1038/ncomms1446

    • NAID

      120005971845

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Precursor Geometry Determines the Growth Mechanism in Graphene Nanoribbons2017

    • Author(s)
      Schulz, F., Jacobse, P. H., Federici Canova, F., Lit, J. v. d., Gao, D. Z., Hoogenband, A. v. d., Han, P., Klein Gebbink, R. J.M., Moret, M.-E., Joensuu, P. M., Swart, I., Liljeroth, P.
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 5 Pages: 2896-2904

    • DOI

      10.1021/acs.jpcc.6b12428

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] State-space reduction and equivalence class sampling for a molecular self-assembly model2016

    • Author(s)
      Packwood, D. M., Han, P., Hitosugi, T.
    • Journal Title

      Royal Society Open Science

      Volume: 3 Issue: 7 Pages: 1-20

    • DOI

      10.1098/rsos.150681

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Toward Graphene Integration from the Bottom-Up2016

    • Author(s)
      Patrick Han
    • Organizer
      International Symposium on the Physics of Semiconductors and Applications
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2018-01-16  

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