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Molecular gas thermometry using dual-comb spectroscopy

Research Project

Project/Area Number 16K05009
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field General applied physics
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Shimizu Yukiko  国立研究開発法人産業技術総合研究所, 計量標準総合センター, 主任研究員 (30357222)

Co-Investigator(Kenkyū-buntansha) 大久保 章  国立研究開発法人産業技術総合研究所, 計量標準総合センター, 主任研究員 (30635800)
Research Collaborator INABA hajime  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2018: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords温度計測 / 光周波数コム / デュアルコム分光 / 気体温度 / 燃焼 / 温度標準 / 気体温度計測 / 光コム / 振動回転スペクトル / 分子分光 / 一次温度計 / 温度測定 / 光コムレーザー分光 / 分子反応過程
Outline of Final Research Achievements

We propose and demonstrate a novel method for temperature determination using dual-comb spectroscopy and a novel analysis technique, “Rotational-state Distribution Thermometry: RDT.” We obtained the spectral profile of a vibration-rotation band of 12C2H2 using dual-comb spectroscopy at room temperature. The line-center absorbance was determined for each transition by fitting the line profile to a Gaussian function. A model function that relates the rotational temperature of the molecule to the distribution of the line-center absorbance was introduced; the gas temperature was determined by fitting the distribution to the model function. The determined temperature agrees within 0.6K to the cell-wall temperature measured with a platinum resistance thermometer. In addition, using the spectral profile obtained in this study, we compare the present analysis with two conventional methods. The present method takes full advantage of the supreme characteristics of dual-comb spectroscopy.

Academic Significance and Societal Importance of the Research Achievements

本技術が確立すれば、燃焼現象の素過程に関する新しい知見を得ることができ、その素過程が解析されれば、エンジンや燃焼装置の設計などで重要課題となる、着火や燃焼現象の制御などへの新たなアプローチが可能になる。一方で、気体分子の熱平衡状態から ボルツマン定数を介して熱力学温度を求められる本方法は、ケルビンの新定義に直結する。この熱力学温度測定システムを世界に先駆けて実現し、新しい温度の定義に基づいた熱力学温度を決定できれば、実用的な温度標準へつながり、計量標準への貢献が期待できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (16 results)

All 2019 2018 2017 2016 Other

All Journal Article (3 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (7 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Remarks (6 results)

  • [Journal Article] デュアルコム光コムによる気体温度の非接触&高精度測定法2018

    • Author(s)
      清水祐公子、大久保章、稲場肇
    • Journal Title

      RFワールド

      Volume: 45 Pages: 24-36

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 光コムの高性能化と応用2018

    • Author(s)
      稲場肇、大久保章、和田雅人、中村圭祐、柏木謙、清水祐公子、大苗敦
    • Journal Title

      レーザー研究

      Volume: 46 Pages: 362-369

    • NAID

      130007957795

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Molecular gas thermometry on acetylene using dual-comb spectroscopy: analysis of rotational energy distribution2018

    • Author(s)
      Shimizu Yukiko、Okubo Sho、Onae Atsushi、Yamada Koichi M. T.、Inaba Hajime
    • Journal Title

      Applied Physics B

      Volume: 124 Issue: 4

    • DOI

      10.1007/s00340-018-6933-x

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 偏波保持ファイバを用いたデュアルコム分光器の開発2019

    • Author(s)
      入松川知也、清水祐公子、大久保章、柏木謙、中村圭祐、稲場肇
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光周波数コムとその分子分光応用2018

    • Author(s)
      大久保章、岩国加奈、清水祐公子、山田耕一、洪鋒雷、佐々田博之、稲場肇
    • Organizer
      第8回光科学異分野横断萌芽研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 光コム温度計2017

    • Author(s)
      清水祐公子、大久保章、大苗敦、稲場肇
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Dual-comb thermometer2017

    • Author(s)
      清水 祐公子、大久保 章、大苗 敦、稲場 肇
    • Organizer
      International Comission for Optics(ICO-24)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 光コム温度計II2017

    • Author(s)
      清水 祐公子、大久保 章、大苗 敦、稲場 肇
    • Organizer
      応用物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] 光コムで温度を測る2017

    • Author(s)
      清水祐公子
    • Organizer
      光ネットワーク産業・技術研究会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] A New Method of Temperature Measurement by Dualcomb Spectroscopy of2016

    • Author(s)
      清水祐公子、大久保章、大苗敦、稲場肇
    • Organizer
      Symposium on temperature and thermal measurements in industry and science (TEMPMEKO2016)
    • Place of Presentation
      ザコパネ・ポーランド
    • Year and Date
      2016-06-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Remarks] 「光コム」で気体の温度を測定-気体分子の吸収スペクトルと温度との相関から算出-

    • URL

      https://www.aist.go.jp/aist_j/press_release/pr2017/pr20170823/pr20170823.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 産総研、「光コム」と呼ばれる超短光パルスレーザーを2台用いて気体の温度を測定する技術を開発

    • URL

      https://www.nikkei.com/article/DGXLRSP454743_T20C17A8000000/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 産総研,光コムによる気体温度の精密測定に成功

    • URL

      http://www.optronics-media.com/news/20170824/47877/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 産総研、「光コム」で気体の温度を測定

    • URL

      http://ex-press.jp/lfwj/lfwj-news/lfwj-science-research/20100/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 産総研、「光コム」(超短光パルスレーザー)2台で気体温度を測定する技術を開発

    • URL

      https://engineer.fabcross.jp/archeive/170824_aist.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 「光コム」で気体の温度を測定 - 気体分子の吸収スペクトルと温度との相関から算出 -

    • URL

      http://www.aist.go.jp/aist_j/press_release/pr2017/pr20170823/pr20170823.html

    • Related Report
      2017 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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