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Development of transparent glaze without sintering and elucidation of its formation mechanism on the basis of fresco technique

Research Project

Project/Area Number 16K05932
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionNagoya Institute of Technology

Principal Investigator

Hashimoto Shinobu  名古屋工業大学, 工学(系)研究科(研究院), 准教授 (10242900)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsフレスコ画 / 顔料 / 炭酸カルシウム / 焼かない陶磁器 / 超臨界二酸化炭素 / セラミック / 水酸化カルシウム / セラミックス
Outline of Final Research Achievements

Pure calcium carbonate powder was simultaneously pressed uniaxially at 250 MPa and heated to 250 ℃ to prepare a solid calcium carbide body, and then the surface of the hardened body was colored with a mineral pigment. Beforehand, the pigment mixed with calcium carbonate powder. After heat and pressure treatment was performed again to fix the pigment particles on the calcium carbonate hardened body, the sample subjected to supercritical carbon dioxide treatment containing water. This series of processes has succeeded in reproducing the frescoes which usually formed for over several decades to a hundred years in a short time. Resultant products are expected to be used as pottery fabricated without burning.

Academic Significance and Societal Importance of the Research Achievements

水酸化カルシウム粉末を出発原料として用い、我々の開発した300℃までの熱と300MPaまでの圧力を同時に印加するウォームプレス法で炭酸カルシム固化生地を作製し、その表面に鉱物顔料で彩色を施した。再度のウォームプレス処理、引き続く含水超臨界二酸化炭素処理で炭酸カルシウムが顔料を被覆したフレスコ画の短時間再生に成功した。この方法を応用すれば彩色を施した焼かない陶磁器の作製も期待される。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (5 results)

All 2019 2018 Other

All Presentation (3 results) Remarks (2 results)

  • [Presentation] 超臨界二酸化炭素を用いたフレスコ画の短時間再現2019

    • Author(s)
      永田陽平、橋本 忍、大幸裕介、本多沢雄、岩本雄二
    • Organizer
      日本セラミックス協会2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] フレスコ画の短時間再現2018

    • Author(s)
      永田陽平、橋本 忍、大幸裕介、本多沢雄、岩本雄二
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2018 Annual Research Report 2017 Research-status Report
  • [Presentation] フレスコ画の短時間再現2018

    • Author(s)
      永田陽平、橋本 忍、大幸裕介、本多沢雄、岩本雄二
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Remarks] 名古屋工業大学 生命・応用化学科・専攻 極限環境材料研究室

    • URL

      http://hashimotolab.web.nitech.ac.jp/research.htm

    • Related Report
      2018 Annual Research Report
  • [Remarks] 極限環境材料研究室 橋本研HP

    • URL

      http://hashimotolab.web.nitech.ac.jp/index.html

    • Related Report
      2017 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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