porous electrically conductive coordination polymer nanosheets for highly selective / sensitive sensing

• Project/Area Number: 16K13610
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Nanostructural chemistry
• Research Institution: Osaka Prefecture University
• Principal Investigator: Makiura Rie 大阪府立大学, 工学(系)研究科(研究院), 准教授 (30457436)
• Project Period (FY): 2016-04-01 – 2021-03-31
• Project Status: Completed (Fiscal Year 2020)
• Budget Amount: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000); Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
• Keywords: ナノシート / 気液界面 / 配位高分子 / 電気伝導度 / X線構造解析 / センサー / センサ / X線回折 / 多孔性材料 / 放射光 / ナノ材料 / 二次元材料 / 表面 / 界面 / 金属錯体 / Ｘ線回折 / ナノ細孔 / 分子認識 / 電子状態 / 界面合成

Outline of Final Research Achievements

Metal-organic frameworks (MOFs) composed of metal ions and organic ligands possess regulated nanopores and their electronic properties can be controlled by varying the combination of the components. Electrically conductive MOFs are expected to show new functionalities generated from interaction of guest molecules into framework electronic properties and application of MOFs in nanosheet states will open further up their use in varied applications including thin film electronic devices. The aim of this work is to create highly-oriented conductive MOF nanosheets and reveal their electronic properties.
Air/liquid interfacial synthesis was applied for creating highly-oriented MOF nanosheets composed of triphenylene derivatives with high π electron activity and transition metal ions. The planar electric conductivity of the nanosheets recorded as highest in related MOF nanosheets.

Academic Significance and Societal Importance of the Research Achievements

本研究は、センサ材料として有望視されてきた配位高分子に関して、その電気的不活性な性質とナノシート化が困難であるという課題のために、応用展開に歯止めがかかってきた状況を打破するものである。本研究で対象とするナノシートは、高選択性・高感度な極薄センサ材料として理想的であるとともに、規則ナノ細孔を有するナノシートが必要とされる分離膜、生体膜研究の進展にも波及効果をもたらす。

Research Products

• [Int'l Joint Research] 欧州シンクロトロン放射光研究所(フランス)
• [Int'l Joint Research] Durham大学(英国)
• [Journal Article] Heteroatom-Doped Carbon Electrocatalysts Derived from Nanoporous Two-Dimensional Covalent Organic Frameworks for Oxygen Reduction and Hydrogen Evolution (2020)
  • Author(s): Yang Chao、Tao Shanshan、Huang Ning、Zhang Xiaobin、Duan Jingui、Makiura Rie、Maenosono Shinya
  • Journal Title: ACS Applied Nano Materials Volume: 3 Issue: 6 Pages: 5481-5488
  • DOI: 10.1021/acsanm.0c00786
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Observation of surfactant-based film-forming curing agent using Brewster angle microscope (2019)
  • Author(s): 伊藤 遥子、酒井 雄也、牧浦 理恵
  • Journal Title: SEISAN KENKYU Volume: 71 Issue: 1 Pages: 51-54
  • DOI: 10.11188/seisankenkyu.71.51
  • NAID: 130007584211
  • ISSN: 0037-105X, 1881-2058
  • Year and Date: 2019-01-01
  • Peer Reviewed / Open Access
• [Journal Article] Structural Analysis of Molecular Nanosheets for Separation Membrane Assembled with a Bottom-Up Approach at Liquid Interfaces (2018)
  • Author(s): Ohata Takashi、Hirosawa Ichiro、Watanabe Takeshi、Makiura Rie
  • Journal Title: SPring-8/SACLA Research Report Volume: 6 Issue: 1 Pages: 137-140
  • DOI: 10.18957/rr.6.1.137
  • NAID: 130007969507
  • ISSN: 2187-6886
  • Year and Date: 2018-01-25
  • Peer Reviewed
• [Journal Article] Influence of solution pH and reaction atmosphere on the morphology of SrTiO3 nanocubes synthesized by thermohydrolysis (2018)
  • Author(s): Makiura Rie
  • Journal Title: Research on Chemical Intermediates Volume: in press Issue: 8 Pages: 1-8
  • DOI: 10.1007/s11164-018-3283-6
  • Peer Reviewed
• [Journal Article] Air/Liquid Interfacial Nanoassembly of Molecular Building Blocks into Preferentially Oriented Porous Organic Nanosheet Crystals via Hydrogen Bonding (2017)
  • Author(s): Makiura Rie、Tsuchiyama Kohei、Pohl Ehmke、Prassides Kosmas、Sakata Osami、Tajiri Hiroo、Konovalov Oleg
  • Journal Title: ACS Nano Volume: 11 Issue: 11 Pages: 10875-10882
  • DOI: 10.1021/acsnano.7b04447
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Solution-based sequential modification of LiCoO2 particle surfaces with iron(II) oxalate nanolayers (2017)
  • Author(s): Yuki Kishimoto, So Yubuchi, Akitoshi Hayashi, Masahiro Tatsumisago and Rie Makiura
  • Journal Title: ＣｒｙｓｔＥｎｇＣｏｍｍ Volume: 印刷中
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 規則ナノ細孔を有する分子ナノシートの液相界面ボトムアップ合成 (2016)
  • Author(s): 牧浦 理恵
  • Journal Title: C&I Commun Volume: 41 Pages: 19-21
  • NAID: 40021247020
• [Presentation] 気水界面における分子ナノシート結晶の創製：モルフォロジ制御に向けたその場広 角X線回折測定による形成過程の解明 (2021)
  • Author(s): 牧浦理恵・大畑考司
  • Organizer: SPRUCソフト界面科学研究会
  • Invited
• [Presentation] 気水界面における分子ナノシート結晶の創製：モルフォロジー制御と機能創出 (2021)
  • Author(s): 牧浦理恵
  • Organizer: 日本化学会第101春季年会
  • Invited
• [Presentation] Highly-oriented electrically conductive MOF nanosheets utilizing liquid interfacial synthesis (2021)
  • Author(s): Takashi Ohata, Rie Makiura
  • Organizer: The 1st Asian Conference on Molecular Magnetism
• [Presentation] 気水界面における多孔性分子ナノシート結晶の創製 (2020)
  • Author(s): 牧浦理恵
  • Organizer: 第69回高分子討論会
  • Invited
• [Presentation] 多孔性分子ナノシート結晶における構造・結合と光学特性の相関解明 (2020)
  • Author(s): 大畑考司・牧浦理恵
  • Organizer: 第66回高分子研究発表会
• [Presentation] 電気・吸着特性制御に向けたmetal-organic frameworkへの欠陥導入 (2020)
  • Author(s): 小池隆斗・牧浦理恵
  • Organizer: 第66回高分子研究発表会
• [Presentation] 異種水素結合を用いた多孔性分子ナノシートの構造多様性 (2020)
  • Author(s): 西野秦平・牧浦理恵
  • Organizer: 第66回高分子研究発表会
• [Presentation] 気液界面合成で得られる高配向metal-organic framework(MOF)ナノシートの電気特性 (2020)
  • Author(s): 大畑考司・牧浦理恵
  • Organizer: 薄膜材料デバイス研究会
• [Presentation] Creation of highly-oriented porous molecular nanosheets utilizing air/liquid interfaces and investigation of their optical properties (2020)
  • Author(s): Takashi Ohata*, Rie Makiura
  • Organizer: 日本化学会第100春季年会
• [Presentation] 多孔性金属錯体ナノシートの気液界面合成：モルフォロジー制御と機能創出 Air/liquid interfacial synthesis of porous metal complex nanosheets : Morphology tuning and creation of new functions (2020)
  • Author(s): Rie Makiura
  • Organizer: 日本化学会第100春季年会
  • Invited
• [Presentation] Creation of electrically conductive metalorganic framework nanosheets utilizing liquid phase interfacial coordination (2019)
  • Author(s): Takashi Ohata*, Rie Makiura
  • Organizer: Okinawa colloids2019
  • Int'l Joint Research
• [Presentation] Creation of electrically conductive metal-organic framework nanosheets utilizing liquid phase interfacial coordination (2019)
  • Author(s): Takashi Ohata*, Rie Makiura
  • Organizer: JSPS-EPSRC Core-to Core International Workshop On Two-Dimensional Coordination Nanosheets
  • Int'l Joint Research
• [Presentation] 電子機能性metal-organic frameworkナノシート結晶の電気特性とモルフォロジーの相関調査 (2019)
  • Author(s): 大畑 考司*, 牧田 龍幸, 竹谷 純一, 牧浦 理恵
  • Organizer: 第65回高分子研究発表会
• [Presentation] Porousmolecularnanosheetsassembledatair/liquidinterfaces:Applicationofmultiplemolecularcomponentstowardsfinetuneofporesize and shape (2019)
  • Author(s): Rie Makiura*
  • Organizer: 錯体化学会第69回討論会
• [Presentation] 界面活性剤系養生剤による水分逸散抑制効果に関する研究 (2019)
  • Author(s): 伊藤 遥子, 酒井 雄也, 牧浦 理恵, 豊田 太郎
  • Organizer: 第19回 コンクリート構造物の補修，補強，アップグレードシンポジウム
• [Presentation] Interfacial nanocrafting of molecular building blocks into crystalline porous nanosheets (2019)
  • Author(s): Rie Makiura
  • Organizer: The 7th Asian Conference on Coordination Chemistry (ACCC7)
  • Int'l Joint Research / Invited
• [Presentation] Liquid-phase interfacial nanoassembly of molecular building units into porous nanosheet crystals (2019)
  • Author(s): Rie Makiura
  • Organizer: Okinawa colloids 2019
  • Int'l Joint Research / Invited
• [Presentation] Liquid-phase Interfacial nanocrafting of molecular building blocks into crystalline porous nanosheets (2019)
  • Author(s): Rie Makiura
  • Organizer: JSPS-EPSRC Core-to Core International Workshop On Two-Dimensional Coordination Nanosheets
  • Int'l Joint Research / Invited
• [Presentation] 電子機能性MOFナノシート結晶のシート形態・配向性と電気的特性の相関関係調査 (2018)
  • Author(s): 大畑 考司・牧田 龍幸・竹谷 純一・牧浦 理恵
  • Organizer: 第64回高分子研究発表会
• [Presentation] 気液界面における細孔径可変MOF薄膜の作製 (2018)
  • Author(s): 渕上 晃輝・牧浦 理恵
  • Organizer: 第64回高分子研究発表会
• [Presentation] Pore-size-adjustable MOF nanosheets assembled (2018)
  • Author(s): 渕上 晃輝・牧浦 理恵
  • Organizer: 錯体化学第68回討論会
• [Presentation] MOFナノシート結晶の電子機能の開拓:配向性・シート形態と電気的特性の調査 (2018)
  • Author(s): 大畑 考司・牧田 龍幸・竹谷 純一・牧浦 理恵
  • Organizer: 錯体化学第68回討論会
• [Presentation] 電子機能性metal-organic frameworkナノシート結晶の電気特性とモルフォロジーの相関調査 (2018)
  • Author(s): 大畑 考司・牧田 龍幸・竹谷 純一・牧浦 理恵
  • Organizer: 第69回コロイドおよび界面化学討論会
• [Presentation] 気液界面における多孔性分子ナノシートの創製：細孔サイズと形状の制御に向けた多成分の適用 (2018)
  • Author(s): 牧浦 理恵
  • Organizer: 第69回コロイドおよび界面化学討論会
• [Presentation] Electronic functional MOF nanosheet crystals varied by orientation and morphology (2018)
  • Author(s): Takashi Ohata, Rie Makiura
  • Organizer: The 43rd International Conference on Coordination Chemistry
  • Int'l Joint Research
• [Presentation] Pore-size adjustable MOF nanosheets assembled at air/liquid interfaces (2018)
  • Author(s): Koki Fuchigami, Rie Makiura
  • Organizer: The 43rd International Conference on Coordination Chemistry
  • Int'l Joint Research
• [Presentation] Liquid-phase interfacial nanoassembly of molecular building units into (2018)
  • Author(s): Rie Makiura
  • Organizer: The 43rd International Conference on Coordination Chemistry
  • Int'l Joint Research / Invited
• [Presentation] 分子の積み木細工による2次元機能材料の創成 (2018)
  • Author(s): 牧浦 理恵
  • Organizer: 第五回ヘキサカンファレンス
  • Invited
• [Presentation] 高配向性 metal-organic frameworkナノシート結晶の形態と電気的特性の相関調査 (2018)
  • Author(s): 大畑 孝司*、牧田 龍幸、竹谷 純一、牧浦 理恵
  • Organizer: 日本化学会第98春季年会
• [Presentation] 高配向性 metal-organic frameworkナノシート結晶の形態と電気的特性の相関調査 (2018)
  • Author(s): 大畑 孝司*、牧浦 理恵
  • Organizer: 第9回関西無機機能性材料研究会
• [Presentation] 温度による細孔サイズの制御可能なナノシートの製膜 (2018)
  • Author(s): 渕上 晃輝*、牧浦 理恵
  • Organizer: 第9回関西無機機能性材料研究会
• [Presentation] トリフェニレン誘導体を用いた高配向性Metal-Organic Frameworksナノシート結晶の気液界面合成 (2017)
  • Author(s): 大畑 孝司、牧浦 理恵
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2017-03-18
• [Presentation] Size and crystallinity control in hydrogen-bonded porous molecular nanosheets assembled at air/liquid interfaces (2017)
  • Author(s): Azusa Taniguchi, Rie Makiura
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2017-03-18
• [Presentation] 多孔性配位高分子ナノシートの２次元液相界面合成 (2017)
  • Author(s): 牧浦 理恵
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 神奈川
  • Year and Date: 2017-03-17
  • Invited
• [Presentation] 第11回NanoSquareワークショップ (2017)
  • Author(s): Takashi Ohata*、 Rie Makiura
  • Organizer: 第11回NanoSquareワークショップ
  • Int'l Joint Research
• [Presentation] Synthesis of acetylene-conjugated porphyrin for construction of metal-organic framework (2017)
  • Author(s): Zhang Lihao*, Akihiro Nomoto, Yuta Sakai, Rie Makiura, Akiya Ogawa
  • Organizer: Joint Symposium of Asia Five Universities
  • Int'l Joint Research
• [Presentation] Liquid-phase interfacial nanoassembly of molecular building units into porous nanosheet crystals (2017)
  • Author(s): Rie Makiura
  • Organizer: Joint Symposium of Asia Five Universities
  • Int'l Joint Research / Invited
• [Presentation] Air/liquid Interfacial nanoassembly of molecular building units into porous nanosheet crystals (2017)
  • Author(s): Rie Makiura
  • Organizer: 11th Japan-China Joint Symposium on Metal Cluster Compounds (11th JCSMCC) 第11回日中クラスター会議
  • Int'l Joint Research / Invited
• [Presentation] Electronic state tuning of molecular-based porous frameworks by introducing guest molecules into pores (2017)
  • Author(s): 牧浦 理恵
  • Organizer: 錯体化学会第67回討論会
• [Presentation] 高配向性ニッケル錯体ナノシート結晶の気液界面合成 (2017)
  • Author(s): 大畑 孝司*、牧浦 理恵
  • Organizer: 錯体化学会第67回討論会
• [Presentation] 気液界面に形成された多孔性分子ナノシートの構造とモルフォロジ制御 (2017)
  • Author(s): 牧浦 理恵
  • Organizer: 第68回コロイドおよび界面化学討論会
• [Presentation] Synthesis of highly orientated metal-organic framework nanosheet crystals composed of triphenylene derivative at air/liquid interfaces (2017)
  • Author(s): Takashi Ohata*、 Rie Makiura
  • Organizer: The 6th Asian Conference on Coordination Chemistry (ACCC6)
  • Int'l Joint Research
• [Presentation] LIQUID-PHASE INTERFACIAL NANOASSEMBLY OF METAL-ORGANIC FRAMEWORKS INTO HIGHLY-CRYSTALLINE NANOSHEETS (2017)
  • Author(s): Rie Makiura
  • Organizer: The 6th Asian Conference on Coordination Chemistry (ACCC6)
  • Int'l Joint Research / Invited
• [Presentation] トリフェニレン誘導体を用いたハニカム型 metal-organic frameworkナノシート結晶作製及びシート形態制御 (2017)
  • Author(s): 大畑 孝司*、牧浦 理恵
  • Organizer: 第63回高分子研究発表会
• [Presentation] 水素結合により連結した結晶性分子ナノシートの気液界面合成 (2017)
  • Author(s): 牧浦 理恵
  • Organizer: 第63回高分子研究発表会
• [Presentation] 分子の積み木細工による2次元機能材料の創製 (2017)
  • Author(s): 牧浦理恵
  • Organizer: 第45回東北地区高分子若手研究会夏季ゼミナール
  • Invited
• [Presentation] 分子の積み木細工による２次元機能材料の創製：液面の特異性を利用して作る多孔性ナノシート (2017)
  • Author(s): 牧浦理恵
  • Organizer: セミナー化学千一夜 有機合成化学協会 関西支部
  • Invited
• [Presentation] Interfacial nanoassembly of molecular building units into crystalline porous nanosheets (2016)
  • Author(s): Rie Makiura
  • Organizer: The 5th Symposium on Advanced Materials and Application
  • Place of Presentation: 韓国
  • Year and Date: 2016-09-27
  • Int'l Joint Research / Invited
• [Presentation] Fine control of the pore size in a molecular nanosheet by applying multicomponents for organic solar cells (2016)
  • Author(s): Azusa Taniguchi, Rie Makiura
  • Organizer: The 5th Symposium on Advanced Materials and Application
  • Place of Presentation: 韓国
  • Year and Date: 2016-09-26
  • Int'l Joint Research
• [Presentation] 液相逐次成長法による無機粒子表面への配位高分子薄層の形成と２次電池電極材料への応用 (2016)
  • Author(s): 牧浦 理恵
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川
  • Year and Date: 2016-09-16
• [Presentation] Solution based step-by-step growth of metal-organic framework nanolayers on inorganic particle surfaces and application for secondary battery electrode materials (2016)
  • Author(s): Rie Makiura
  • Organizer: 錯体化学会第66回討論会
  • Place of Presentation: 福岡
  • Year and Date: 2016-09-11
• [Presentation] Interfacial nanoassembly of molecular building units into crystalline porous nanosheets (2016)
  • Author(s): Rie Makiura
  • Organizer: 1st Japan-Australia Joint Symposium on Coordination Chemistry
  • Place of Presentation: Fukuoka
  • Year and Date: 2016-09-10
  • Int'l Joint Research / Invited
• [Presentation] 液相界面を利用した分子ナノシート結晶のボトムアップ創製 (2016)
  • Author(s): 牧浦 理恵
  • Organizer: 日本セラミックス協会 第29回秋季シンポジウム
  • Place of Presentation: 広島
  • Year and Date: 2016-09-08
  • Invited
• [Presentation] 液相界面を利用した結晶性分子ナノシートのボトムアップ創製 (2016)
  • Author(s): 牧浦 理恵
  • Organizer: 第62回高分子研究発表会
  • Place of Presentation: 兵庫
  • Year and Date: 2016-07-15
• [Presentation] Interfacial Nanoassembly of Molecular Building Units into Crystalline Porous Nanosheets (2016)
  • Author(s): Rie Makiura
  • Organizer: The 2nd International Symposium on Synthetic Two-Dimensional Polymers
  • Place of Presentation: Ｎａｒａ
  • Year and Date: 2016-06-02
  • Int'l Joint Research / Invited
• [Book] ポストグラフェン材料の創製と用途開発最前線 「第３節 規則ナノ細孔を有する有機無機ポリマーナノシートの液相界面合成」 (2020)
  • Author(s): 牧浦理恵
  • Total Pages: 448
  • Publisher: エヌ・ティー・エス
  • ISBN: 9784860436575
• [Book] PCP/MOFおよび各種多孔質材料の作り方，使い方，評価解析 「第２章 PCP/MOFの応用利用,その可能性、第14節 液相界面を利用した高配向MOFナノシートの創製」 (2019)
  • Author(s): 牧浦理恵
  • Total Pages: 639
  • Publisher: 技術情報協会
  • ISBN: 9784861047695
• [Book] Molecular Technology: Life Innovation、2. Liquid-Phase Interfacial Synthesis of Highly Oriented Crystalline Molecular Nanosheets. (2018)
  • Author(s): Rie Makiura（Edited by Hisashi Yamamoto, Takashi Kato）
  • Total Pages: 384
  • Publisher: Wiley
  • ISBN: 9783527341627
• [Book] CSJカレントレビューシリーズNo.25"2次元物質の化学", (2017)
  • Author(s): 牧浦理恵、大坪主弥、北川宏
  • Total Pages: 8
  • Publisher: 日本化学会編, 化学同人
• [Remarks] 研究室HP
  • URL: http://mtr1.osakafu-u.ac.jp/hybrid-nanomater/
• [Remarks] 研究代表者の研究室のHP
  • URL: http://mtr1.osakafu-u.ac.jp/hybrid-nanomater/
• [Remarks] 研究代表者webページ
  • URL: http://mtr1.osakafu-u.ac.jp/hybrid-nanomater/
• [Remarks] 研究代表者の研究室のホームページ
  • URL: http://mtr1.osakafu-u.ac.jp/hybrid-nanomater/