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Permittivity control due to dielectric tunable materials using ferroelectric critical endpoint

Research Project

Project/Area Number 16K13820
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Condensed matter physics I
Research InstitutionNagoya Institute of Technology

Principal Investigator

Iwata Makoto  名古屋工業大学, 工学(系)研究科(研究院), 教授 (40262886)

Co-Investigator(Kenkyū-buntansha) 籠宮 功  名古屋工業大学, 工学(系)研究科(研究院), 准教授 (40318811)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords強誘電体 / 誘電率 / 誘電チューナビィティー / 電場誘起相転移 / 臨界点 / ペロブスカイト / 酸化物 / 構造相転移 / 物理学 / 物性実験 / 高誘電率 / 電子材料
Outline of Final Research Achievements

The dielectric tunable material is defined as a material changing the permittivity largely due to the DC electric field. To use such materials in the filter circuit of smartphones, the tunability higher than 90% is required.
The applicants had already clarified both in experiment and theory that the large dielectric tunability appears if the material located near the ferroelectric critical endpoint is adopted. At that point, however, no material showing tunability higher than 90% at room temperature was found. In this research, materials were searched, and among them, Pb(Sc1/2Ta1/2)O3 (PST) single crystals were grown. It was found experimentally that the tunability in PST exceeds 90% at room temperature. Thus, the goal of this study was achieved.

Academic Significance and Societal Importance of the Research Achievements

これまでのチューナブル材料の探索では、ヒステリシスループの角型性が小さいソフト強誘電体材料やリラクサーや複合材料 (含人工超格子) のような非線形性の大きな不均一系材料が調べられてきたが、探索に指導原理が無く、経験則による研究が進められていた。申請者の知る限り、申請段階でt = 90% を越える材料は、まだ見つかっていなかった。
本研究の学術的価値は、大きなチューナブル材料を探索するときには室温付近に強誘電的臨界点のある物質を探せばよいという探索指針を明らかにしたことであり、社会的価値は、PST を用いると、室温付近でチューナビリティーが90%を超えることを実験的に見出したことである。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (45 results)

All 2018 2017 2016

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (33 results) (of which Int'l Joint Research: 8 results,  Invited: 3 results)

  • [Journal Article] Nonlinear dielectric constant in relaxor ferroelectrics Pb(Mg1/3Nb2/3)O3-PbTiO32018

    • Author(s)
      Yasutaka Kaiden, Makoto Iwata, Yoshikazu Umeda, Yoshinori Takikawa, and Yoshihito Tachi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 57 Issue: 11S Pages: 11UC01-11UC01

    • DOI

      10.7567/jjap.57.11uc01

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric dispersion in a dual-frequency nematic liquid crystal 2-chloro-4-(4-pentylbenzoyloxy)benzoate2018

    • Author(s)
      Yoshinori Takikawa, Syunsuke Odani, In-hwan Lee, Kosuke Kaneko, and Makoto Iwata
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 57 Issue: 11S Pages: 11UB02-11UB02

    • DOI

      10.7567/jjap.57.11ub02

    • NAID

      210000149784

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phenomenological Approach to the Critical Slowing Down in Pyridinium Tetrafluoroborate Single Crystals2018

    • Author(s)
      Makoto Iwata, Kenta Ninoseki, Shunsuke Odani, and Yoshinori Takikawa
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 89 Issue: 12 Pages: 124708-124708

    • DOI

      10.7566/jpsj.87.124708

    • NAID

      210000135050

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature dependence of the dielectric tunability near the critical endpoint in Pb(Zn1/3Nb2/3)-PbTiO32018

    • Author(s)
      Makoto Iwata, Norikazu Tamaoki, and Yoshihiro Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 532 Issue: 1 Pages: 190-198

    • DOI

      10.1080/00150193.2018.1430425

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Double hysteresis loops in 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 near the ferroelectric critical endpoint2018

    • Author(s)
      Makoto Iwata, Yasutaka Kaiden, and Yoshihiro Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 533 Issue: 1 Pages: 139-144

    • DOI

      10.1080/00150193.2018.1470827

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric tunability in Pb(Sc1/2Ta1/2)O3 single crystals2017

    • Author(s)
      Makoto Iwata, Norikazu Tamaoki, Yohei Arimoto, and Yoshihiro Ishibashi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 56 Issue: 10S Pages: 10PB01-10PB01

    • DOI

      10.7567/jjap.56.10pb01

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Soft-mode behavior in lanthanide-modifiedbismuth titanates2017

    • Author(s)
      Shunsuke Suzuki, Toru Mogami, Shota Nakamura, Yuhji Tsujimi, and Makoto Iwata
    • Journal Title

      Ferroelectrics

      Volume: 512 Issue: 1 Pages: 52-57

    • DOI

      10.1080/00150193.2017.1355163

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Novel low-temperature sintering ceramic substrate based on indialite/cordierite glass ceramics2017

    • Author(s)
      Jobin Varghese, Timo Vahera, Hitoshi Ohsato, Makoto Iwata, and Heli Jantunen
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 56 Issue: 10S Pages: 10PE01-10PE01

    • DOI

      10.7567/jjap.56.10pe01

    • NAID

      210000148376

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nonlinear dielectric susceptibility in relaxor ferroelectrics Pb(Zn1/3Nb2/3)O3-PbTiO32016

    • Author(s)
      Makoto Iwata, Tomoya Ido, Ryo Nagahashi, and Yoshihiro Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 498 Issue: 1 Pages: 52-61

    • DOI

      10.1080/00150193.2016.1170420

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct observation of the ferroelectric polarization in the layered perovskite Bi4Ti3O122016

    • Author(s)
      Daisuke Urushihara, Mai Komabuchi, Nobuo Ishizawa, Makoto Iwata, Koichiro Fukuda, and Toru Asaka
    • Journal Title

      J. Appl. Phys.

      Volume: 120 Issue: 14

    • DOI

      10.1063/1.4961719

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Notes on the domain structures in YMnO32016

    • Author(s)
      Yoshihiro Ishibashi, Makoto Iwata, and Shigeo Mori
    • Journal Title

      Ferroelectrics

      Volume: 500 Issue: 1 Pages: 20-25

    • DOI

      10.1080/00150193.2016.1214528

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Phenomenological Theory in Dielectric Tunable Materials with the Tristable States2016

    • Author(s)
      Makoto Iwata and Yoshihiro Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 503 Issue: 1 Pages: 7-14

    • DOI

      10.1080/00150193.2016.1216700

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] Nonlinear dielectric constant in relaxor ferroelectrics Pb(Mg1/3Nb2/3)O3-PbTiO32018

    • Author(s)
      Yasutaka Kaiden, Makoto Iwata, Yoshikazu Umeda, Yoshinori Takikawa, and Yoshihito Tachi
    • Organizer
      The 2018 ISAF-FMA-AMF-AMEC-PFM (IFAAP) Joint Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dielectric dispersion in a dual-frequency nematic liquid crystal 2-chloro-4-(4-pentylbenzoyloxy)benzoate2018

    • Author(s)
      Yoshinori Takikawa, Syunsuke Odani, In-hwan Lee, Kosuke Kaneko, and Makoto Iwata
    • Organizer
      The 2018 ISAF-FMA-AMF-AMEC-PFM (IFAAP) Joint Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Glass Casting and Crystallization: A Novel Approach for Next Generation Ultra-Low Dielectric Loss Micro/Millimeter Wave Substrates2018

    • Author(s)
      Hitoshi Ohsato, Jobin Varghese, Heli Jantunen, and Makoto Iwata
    • Organizer
      The 2018 ISAF-FMA-AMF-AMEC-PFM (IFAAP) Joint Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dielectric Dispersion in PCPB/MBBA mixtures showing the Dual Frequency Characteristic2018

    • Author(s)
      Yoshinori Takikawa, Syunsuke Odani, In-hwan Lee, Kosuke Kaneko, and Makoto Iwata
    • Organizer
      The 12th Japan-Korea Conference on Ferroelectricity (JKC-FE12)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pb(Mg1/3Nb2/3)O3-PbTiO3 のスローダイナミクス2018

    • Author(s)
      海田恭孝,岩田 真,梅田喜和,瀧川佳紀,舘 義仁
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 2周波液晶PCPBのフレデリクス転移2018

    • Author(s)
      瀧川佳紀,小谷俊介,金子光佑,折原 宏,岩田 真
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pb(Mg1/3Nb2/3)O3-0.295PbTiO3 におけるDC電場下の誘電率 Ⅱ2018

    • Author(s)
      梅田喜和,海田恭孝,岩田 真,瀧川佳紀,舘 義仁
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pb(Sc1/2Ta1/2)O3 の非線形誘電率2018

    • Author(s)
      有本瑶平,海田恭孝,岩田 真,瀧川佳紀
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 2周波液晶PCPB/MBBA混合物の誘電特性2018

    • Author(s)
      小谷俊介,Lee In-Hwan,瀧川佳紀,金子光佑,岩田 真
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] チューナブル誘電体 PbSc0.5Ta0.5O3 の単結晶 X 線構造解析 II2018

    • Author(s)
      坂倉輝俊,青木一朗,木村宏之,玉置範一,岩田 真,岸本俊二
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] リラクサー強誘電体の単結晶育成と蛍光X線ホログラフィーによる格子歪み解析2018

    • Author(s)
      木村耕治、横地恒平、近藤陸弥、漆原大典、尾原幸治、八方直久、浅香透、松下智裕、岩田真、林好一
    • Organizer
      第13回日本フラックス成長研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 蛍光X線ホログラフィーによるマルチフェロイック物質Pb(Fe1/2Nb1/2)O3の局所構造解析2018

    • Author(s)
      木村耕治、横地恒平、近藤陸弥、漆原大典、尾原幸治 尾原幸治、八方直久、松下智裕、岩田 真、林 好一
    • Organizer
      32回日本放射光学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] C5H6NBF4 の臨界緩和の分裂と誘電率異方性2018

    • Author(s)
      岩田 真、二関健太、小谷俊介、瀧川佳紀
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 強誘電体臨界点近傍におけるDC電場下の焦電測定2018

    • Author(s)
      鈴木洋太、海田恭孝、瀧川佳紀、岩田 真
    • Organizer
      日本物理学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pb(Mg1/3Nb2/3)O3-29.5%PbTiO3におけるDC電場下の誘電率2018

    • Author(s)
      海田恭孝、梅田喜和、瀧川佳紀、岩田 真
    • Organizer
      日本物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] BaTiO3 のドメイン境界ダイナミクス2018

    • Author(s)
      大和田謙二, 松浦直人, 塚田真也, 岩田 真, 出野顕太朗, 水木純一郎
    • Organizer
      日本物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] Pb(Zn1/3Nb2/3)O3-PbTiO3 の分極反転に伴う構造ダイナミクスの計測2018

    • Author(s)
      青柳 忍,青柳鮎美,大沢仁志,杉本邦久,中平夕貴,森吉千佳子,黒岩芳弘,岩田 真
    • Organizer
      日本物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] チューナブル誘電体 PbSc0.5Ta0.5O3 の単結晶Ⅹ線構造解析2018

    • Author(s)
      青木一朗,坂倉輝俊,木村宏之,玉置範一,岩田 真,岸本俊二
    • Organizer
      日本物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] Pb(Sc1/2Ta1/2)O3 のヒステリシスループと誘電率の電場依存性2017

    • Author(s)
      玉置範一, 有本瑶平, 岩田真
    • Organizer
      日本物理学会
    • Place of Presentation
      金沢大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Pb(Zn1/3Nb1/3)O3-PbTiO3のキュリ-定数 Ⅲ2017

    • Author(s)
      西村 宗世、岩田 真
    • Organizer
      日本物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] Pb(Sc1/2Ta1/2)O3 のヒステリシスループと誘電率の電場依存性2017

    • Author(s)
      玉置範一、有本瑶平、岩田真
    • Organizer
      日本物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] Pb(Sc1/2Ta1/2)O3 単結晶の誘電チューナビリティー2017

    • Author(s)
      岩田 真、玉置範一、有本瑶平、石橋善弘
    • Organizer
      強誘電体応用会議 (FMA)
    • Related Report
      2017 Research-status Report
  • [Presentation] Double hysteresis loops in Pb(Zn1/3Nb2/3)O3-PbTiO32017

    • Author(s)
      M. Iwata, Y. Kaiden, and Y. Ishibashi
    • Organizer
      The International Meeting on Ferroelectricity (IMF-2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 臨界点近傍におけるPb(Sc1/2Ta1/2)O3 の誘電チューナビリティー2017

    • Author(s)
      玉置範一, 有本瑶平, 瀧川佳紀, 岩田 真
    • Organizer
      日本物理学会
    • Related Report
      2017 Research-status Report
  • [Presentation] 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 のP-Eダブルループと臨界点2017

    • Author(s)
      有本瑶平,玉置範一,小谷俊介,瀧川佳紀,岩田 真
    • Organizer
      海田 恭孝、瀧川 佳紀、岩田 真
    • Related Report
      2017 Research-status Report
  • [Presentation] Indialite/cordierite glass ceramics applied for LTCC2017

    • Author(s)
      Hitoshi Ohsato, Jobin Varghese, Timo Vahera, Heli Jantunen, and Makoto Iwata
    • Organizer
      Materials Science & Technology 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 層状ペロブスカイト強誘電体Bi4Ti3O12の結晶構造評価2017

    • Author(s)
      漆原大典,駒淵 舞,浅香 透,福田功一郎,岩田 真
    • Organizer
      粉体粉末冶金協会 平成29年度秋季大会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Crystal structure and the ferroelectric domains of the layered perovskite Bi4Ti3O122016

    • Author(s)
      Daisuke Urushibara, Mai Komabuchi, Toru Asaka, Nobuo Ishizawa, Makoto Iwata, and Koichiro Fukuda
    • Organizer
      The 7th International Workshop on Advanced Ceramics (IWAC07)
    • Place of Presentation
      Limoges, France
    • Year and Date
      2016-09-26
    • Related Report
      2016 Research-status Report
  • [Presentation] 臨界点近傍におけるPb(Zn1/3Nb2/3)O3-PbTiO3の誘電チューナビリティーの温度依存性2016

    • Author(s)
      玉置範一、岩田 真、石橋善弘
    • Organizer
      日本物理学会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 強誘電体 Pb(Zn1/3Nb2/3)O3-PbTiO3 の非線型誘電率2016

    • Author(s)
      岩田 真、二関健太、石橋善弘
    • Organizer
      誘電体・磁性体若手 夏の学校
    • Place of Presentation
      蔵王
    • Year and Date
      2016-08-26
    • Related Report
      2016 Research-status Report
  • [Presentation] Dielectric tunability in Pb(Zn1/3Nb2/3)O3-PbTiO32016

    • Author(s)
      Makoto Iwata, Norikazu Tamaoki, and Yoshihiro Ishibashi
    • Organizer
      The Japan-Korea Conference on Ferroelectrics
    • Place of Presentation
      ソウル
    • Year and Date
      2016-08-17
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Linear and Nonlinear Permittivities in Pb(Zn1/3Nb2/3)O3-xPbTiO32016

    • Author(s)
      Makoto Iwata, Ryo Nagahashi, and Yoshihiro Ishibashi
    • Organizer
      13th Russia/CIS/Baltic/Japan Symposium on Ferroelectricity and International Workshop on Structure-Property Relations in Relaxor Ferroelectrics
    • Place of Presentation
      くにびきメッセ (島根)
    • Year and Date
      2016-06-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] リラクサ Pb(Zn1/3Nb2/3)O3-PbTiO3 の非線型誘電率2016

    • Author(s)
      岩田 真,二関健太,長橋 諒,石橋善弘
    • Organizer
      強誘電体応用会議 (FMA)
    • Place of Presentation
      コープイン京都
    • Year and Date
      2016-05-20
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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