Synthesis of nanodiamond using photoinduced liquid phase plasma reaction field
Project/Area Number |
16K13929
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Physical chemistry
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Research Institution | Kyoto University |
Principal Investigator |
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Project Period (FY) |
2016-04-01 – 2018-03-31
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Project Status |
Completed (Fiscal Year 2017)
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Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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Keywords | 液相アブレーション / レーザー / プラズマ / ナノダイヤモンド / グラフェン / 酸化グラフェン / 発光 / ナノ材料 / 量子光工学 / 光物性 / 触媒・化学プロセス / プラズマ加工 |
Outline of Final Research Achievements |
By using liquid phase laser ablation technique, we have investigated direct-synthesis of nanodiamond with a diameter of several nanometers, which is difficult to synthesize by detonation method. We have developed high efficient synthesis method of nanoparticle by using femtosecond double-pulse trains. The synthesized nanodiamonds have a conventional cubic diamond structure and high dens phase of hexagonal diamond structure (Lonsdaleite). In the case of graphene oxide dispersed in cyclohexane, the surface of synthesized nanodiamond was covered with a functional group such as OH, C=O, and COOH groups. The photoluminescence of the nanodiamond synthesized in cyclohexane was broadened and red-shifted compared to that in pure water. Furthermore, in the case of the nanodiamond synthesized in aqueous ammonia, amide and ammonia groups were adsorbed on the nanodiamond surface, leading to much higher PL intensity (at least 40 times).
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Report
(3 results)
Research Products
(52 results)
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[Journal Article] Molecular dynamics simulation of the Soret effect in a CaSiO3 glass melt2017
Author(s)
M. Shimizu, H. Kato, M. Nishi, D. Hanakawa, K. Nagashima, H. Visbal, H. Itasaka, M. Sakakura, Y. Shimotsuma, K. Miura, K. Hirao
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Journal Title
J. Ceram. Soc. Jpn.
Volume: 125
Pages: 180-184
DOI
Related Report
Peer Reviewed
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[Journal Article] Diamond photonics platform enabled by femtosecond laser writing2016
Author(s)
B. Sotillo, V. Bharadwaj, J. P. Hadden, M. Sakakura, A. Chiappini, T. T. Fernandez, S. Longhi, O. Jedrkiewicz, Y. Shimotsuma, L. Criante, R. Osellame, G. Galzerano, M. Ferrari, K. Miura, R. Ramponi, P. E. Barclay, S. M. Eaton
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Journal Title
Sci. Rep.
Volume: 6
Pages: 35566
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
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[Presentation] Observation of stress dynamics after fs laser irradiation inside diamond2016
Author(s)
M. Sakakura, T. Okada,V. Bharadwaj, B. Sotillo, S. Eaton, R. Ramponi, T. Fernandez, A. Serpenguzel, U. Gokay, Y. Shimotsuma, K. Miura
Organizer
JSAP-OSA Joint Symposia
Place of Presentation
朱鷺メッセ(新潟県・新潟市)
Year and Date
2016-09-13 – 2016-09-16
Related Report
Int'l Joint Research
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[Presentation] Diamond quantum photonics platform enabled by femtosecond laser processing2016
Author(s)
T. T. Fernandez, V. Bharadwaj, B. Sotillo, J. P. Hadden, M. Sakakura, A. Chiappini, S. Longhi, R. Osellame, G. Galzerano, Y. Shimotsuma ,M. Ferrari, K. Miura, R. Ramponi, P. E Barclay, S. M Eaton
Organizer
JSAP-OSA Joint Symposia
Place of Presentation
朱鷺メッセ(新潟県・新潟市)
Year and Date
2016-09-13 – 2016-09-16
Related Report
Int'l Joint Research / Invited
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[Presentation] Femtosecond laser written photonic circuits in diamond for quantum information2016
Author(s)
S. M. Eaton, B. Sotillo, V. Bharadwaj, M. Sakakura, Y. Shimotsuma, A. Chiappini, M. Ferrari, J. P. E. Hadden, P. E. Barclay, K. Miura, R. Ramponi
Organizer
ICTON 2016
Place of Presentation
トレント(イタリア)
Year and Date
2016-07-10 – 2016-07-14
Related Report
Int'l Joint Research / Invited
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