Creation of polymeric metal complexes having multi-decker sandwich metallocene units for hydrogen storage materials
| Project/Area Number |
16K14055
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Energy-related chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 高分子合成 / 金属錯体 / 水素貯蔵 / ヘテロール / 遷移金属 / 合成化学 / 水素 / 多積層型高分子錯体 |
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| Outline of Final Research Achievements |
So as to explore the possibility to develop the next generation hydrogen storage systems that enable the reversible storage and release of hydrogen with small energies, polymeric metal complexes having multi-decker sandwich metallocene units have been synthesized by the reaction of stannolyl dianion derivatives derived from stannoles with various multi-valent transition metal salts. Polymers containing phosphametallocene repeating units have also been prepared from polymers having phospholyl anions and half-metallocene complexes.
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Report
(3 results)
Research Products
(53 results)
