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Qquantitative evaluation of atmospheric aerosol oxidation (aging) rate by HOx radicals

Research Project

Project/Area Number 16K16183
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental dynamic analysis
Research InstitutionKyoto University

Principal Investigator

Sakamoto Yosuke  京都大学, 地球環境学堂, 助教 (50747342)

Research Collaborator KAJII Yoshizumi  京都大学, 大学院地球環境学堂, 教授 (40211156)
HIROKAWA Jun  北海道大学, 大学院環境科学院, 准教授 (20262115)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsエアロゾル / エイジング / 対流圏 / 不均一反応 / 反応速度論 / HOxラジカル / 健康影響 / 気候影響 / ヒドロキシラジカル / ヒドロペルオキシラジカル / レーザー / レーザー分光法 / 大気環境化学 / 大気化学 / 大気汚染
Outline of Final Research Achievements

A novel system for measurement of HOx radical uptake rate onto aerosols (LP-LIF) was developed. We tested and confirmed the validity of the system with standard particles by comparing results with previous reported values. In some cases of OH uptake measurements, we found that previous methods might underestimate the uptake rates. We applied the system to chamber experiments with the secondary organic aerosols that have complex compositions and succeeded to obtain their uptake rates for the first time. To measure the uptake rate for ambient particles requires an additional system such as a particle concentrator because of detection limit of the system.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (6 results)

All 2018 2017 2016

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results) Presentation (5 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results)

  • [Journal Article] Air quality study in Hanoi, Vietnam in 2015?2016 based on a one-year observation of NO x , O 3 , CO and a one-week observation of VOCs2018

    • Author(s)
      Sakamoto Yosuke、Shoji Koki、Bui Manh Trung、Ph?m Thi Huong、Vu The Anh、Ly Bich Thuy、Kajii Yoshizumi
    • Journal Title

      Atmospheric Pollution Research

      Volume: 9 Issue: 3 Pages: 544-551

    • DOI

      10.1016/j.apr.2017.12.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Measurement of OH Radical Uptake onto Aerosols with a Combination of Laser-Flash Photolysis and Laser-Induced Fluorescence Detection2017

    • Author(s)
      Yosuke Sakamoto, Kohno Nanase, Jun Hirokawa, Yoshizumi Kajii
    • Organizer
      International Conference on Aerosol Cycle, ICAC 2017
    • Place of Presentation
      リール大学、リール、フランス
    • Year and Date
      2017-03-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Direct measurement of HOx (OH and HO2) radical uptake onto aerosols by a laser photolysis generation and probe techniques2017

    • Author(s)
      Yosuke Sakamoto, Maho Nakagawa, Nanase Kohno, Jun Hirokawa, Yoshizumi Kajii
    • Organizer
      34th International Symposium on Free Radicals
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Novel Measurement Technique of HOx Radical Uptake onto Aerosols using Laser Flash Photolysis Generation and Laser Induced Fluorescence Detection2017

    • Author(s)
      Yosuke Sakamoto, Kohno Nanase, Jun Hirokawa, Yoshizumi Kajii
    • Organizer
      33rd Symposium on Chemical Kinetics and Dynamics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics study of OH radical uptake onto aerosols by laser techniques2017

    • Author(s)
      Yosuke Sakamoto
    • Organizer
      3rd International workshop on heterogeneous kinetics related to atmospheric aerosol &NSFC-project workshop on chemical processes in formation of air pollution complex in China
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] レーザーポンプ・プローブ法を用いたエアロゾルによるOHラジカル取り込み速度の新規測定法の開発2016

    • Author(s)
      坂本陽介、河野七瀬、廣川淳、梶井克純
    • Organizer
      第22回大気化学討論会
    • Place of Presentation
      北海道大学、札幌
    • Year and Date
      2016-10-12
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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