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Development of gold clusters catalysts deposited on metal oxides and application for highly selective functionalization using molecular oxygen

Research Project

Project/Area Number 16K17943
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Green/Environmental chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

Taketoshi Ayako  首都大学東京, 都市環境科学研究科, 助教 (50533056)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords金クラスター / 金ナノ粒子 / 金属酸化物 / 酸素酸化 / 触媒
Outline of Final Research Achievements

Gold clusters, which are smaller than 2 nm in diameter and less than 200 atoms, can be deposited on several metal oxides by Deposition-precipitation method followed by microwave drying instead of conventional oven drying at 120 °C and freeze drying. This method can be applied to metal oxides having different microwave absorption efficiencies. The obtained catalysts were tested in sulfide oxidation, CO oxidation, and oxidative esterification of aliphatic aldehyde. They exhibited high activities in both liquid and gas phase oxidation.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (10 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (8 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Int'l Joint Research] 煙台大学(中国)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Preparation of gold clusters on metal oxides by deposition-precipitation with microwave drying and their catalytic performance for CO and sulfide oxidation2017

    • Author(s)
      Ayako Taketoshi, Tamao Ishida, Hironori Ohashi, Tetsuo Honma, Masatake Haruta
    • Journal Title

      Chinese Journal of Catalysis

      Volume: 38 Issue: 11 Pages: 1888-1898

    • DOI

      10.1016/s1872-2067(17)62909-7

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Oxidative Esterification of Octanal Catalyzed by Gold Nanoparticles in Batch and Continuous Flow Reactors2018

    • Author(s)
      Ayako Taketoshi
    • Organizer
      TMU and PetroMat Joint Mini Symposium on Catalysis and Advanced Materials 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 担持金ナノ粒子触媒によるアルデヒドの酸化的エステル化2017

    • Author(s)
      竹歳絢子, 石田玉青, 春田正毅
    • Organizer
      第119回触媒討論会
    • Place of Presentation
      首都大学東京 (東京都八王子市)
    • Year and Date
      2017-03-22
    • Related Report
      2016 Research-status Report
  • [Presentation] 1.Oxidative Esterification of Octanal by Gold Nanoparticulate Catalysts2017

    • Author(s)
      Ayako Taketoshi, Tamao Ishida, Masatake Haruta
    • Organizer
      YTU-TMU Joint Workshop
    • Place of Presentation
      Yantai (中国)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 流通式反応装置を用いた担持金ナノ粒子触媒によるオクタナールの酸化的エステル化2017

    • Author(s)
      竹歳絢子, 石田玉青, 春田正毅
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金ナノ粒子を担持した酸化ニオブ触媒によるフルフラールの酸化反応2017

    • Author(s)
      村山徹, 竹歳絢子, 石田玉青, 春田正毅
    • Organizer
      第47回石油・石油化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属酸化物担持金クラスター触媒調製におけるマイクロ波乾燥効果2017

    • Author(s)
      竹歳絢子, 石田玉青, 大橋弘範, 本田徹生, 春田正毅
    • Organizer
      第14回Spring-8産業利用報告会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Preparation of Gold Clusters on Metal Oxides by Deposition-Precipitaion with Microwave Drying2017

    • Author(s)
      Ayako Taketoshi, Tamao Ishida, Masatake Haruta
    • Organizer
      Dalian Institute of Chemical Physics-Tokyo Metropolitan University (DICP-TMU) Joint Symposium on Gold Catalysis Research
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金属酸化物担持金クラスター触媒の調製時におけるマイクロ波乾燥の効果2016

    • Author(s)
      竹歳絢子, 石田玉青, 本田徹生, 春田正毅
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学 (岩手県盛岡市)
    • Year and Date
      2016-09-23
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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