Design and development of photocatalysts of high activity and highly efficient photocatalytic reaction systems based on the understanding of photocatalytic reaction mechanisms
| Project/Area Number |
17029001
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Hokkaido University |
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Principal Investigator |
OHTANI Bunsho Hokkaido University, Catalysis Research Center, Professor (80176924)
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| Project Period (FY) |
2001 – 2006
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| Project Status |
Completed (Fiscal Year 2006)
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| Budget Amount *help |
¥9,800,000 (Direct Cost: ¥9,800,000)
Fiscal Year 2006: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 2005: ¥4,900,000 (Direct Cost: ¥4,900,000)
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| Keywords | photocatalytic reaction / action spectrum / photoabsorption / decahedral particles / anatase-rutile mixture / decoloration of dyes / 金属微粒子 / 酸化分解 / 光音響スペクトル |
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| Research Abstract |
1. Action spectrum analyses: It was revealed that this is one of the best methods for the evaluation of photocatalysts and photocatalytic reaction by showing that methylene blue, a frequently employed photocatalytic reaction substrate, is decomposed through photosensitizing mechanism as well as photocatalytic reaction. Moreover, pseudo action spectra taken by using optical cut-off filters show different shape compared from true action spectra.
2. Preparation of highly active titania photocatalyst through novel gas phase reaction: High temperature as-phase synthesis of metal oxide particles is favorable since crystallization of particles is promoted without aggregation to give larger particles. In this study, new type of titania preparation method enabling rapid heating-rapid cooling of titanium(IV) chloride was developed. The resulting anatase small crystallites were of decahedral shape exposing two kinds of lattice facet, 101 and 001 and showed high photocatalytic activity in several reaction systems. The preparation conditions were optimized.
3. Isolation of anatase and rutile crystallites from Degussa P25: From Degussa P25, a representative commercial titania powder with anatase and rutile mixed crystallites, anatase and rutile crystallites were isolated through newly developed method. The isolated samples were used for making calibration curves of each crystal phase to obtain, for the first time, exact composition of P25 and for reconstruction of P25 from two kinds of isolated pure crystallites and commercial amorphous titania. Comparison of physical properties and photocatalytic activities between original and reconstructed samples revealed that there seems to be no synergetic effects by mixing anatase and rutile on the photocatalytic activity.
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Report
(3 results)
Research Products
(52 results)
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[Journal Article] Evaluation of electron-hole recombination properties of titanium(IV) oxide particles with high photocatalytic activity2007
Author(s)
Murakami, S. -y. J Kominami, H. *, Kera, Y., Ikeda, S., Noguchi, H., Uosaki, K., Ohtani, B.
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Journal Title
Res. Cheat. Interm. 33
Pages: 285-296
Description
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[Journal Article] Evaluation of electron-hole recombination properties of titanium (IV) oxide particles with high photocatalytic activity2007
Author(s)
Murakami, S.-i., kominami, H., Kera, Y., Ikeda, S., Noguchi, H., Uosaki, K., Ohtani, B.
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Journal Title
Res. Chem. Interm. 33
Pages: 285-296
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[Journal Article] Electric-Field-Induced Changes in Absorption and Emision Spectra of CdS Nanoparticles Doped in a Polymer Film2006
Author(s)
Oliara, Y., Nakabayashi, T., Iwasaki, K., Torimoto, T., Ohtani, B., Hiratani, T., Konishi, K., Ohta, N. *
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Journal Title
J. Phys. Chem. B 110
Pages: 20927-20936
Description
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[Journal Article] Photo-switching behavior of CdS nanoparticles doped in a polymer film2006
Author(s)
Ohara, Y., Nakabayashi, T., Iwasaki, K., Torimoto, T., Ohtani, B., Ohta, N. *
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Journal Title
Compt. Rend. Chim. 9
Pages: 742-749
Description
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[Journal Article] Photochemical Fine-Tuning of Luminescent Color of Cadmium Selenide Nanoparticles : Fabricating a Single-Source Multi-Color Luminophore2006
Author(s)
Torimoto, T., Murakami, S.-y., Sakuraoka, M., Iwasaki, K., Okazaki, K-i., Shibayama, T., Ohtani, B.
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Journal Title
J. Phys. Chem. B 110
Pages: 13314-13318
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[Journal Article] Photocatalytic Preparation of Encapsulated Gold Nanoparticles by Jingle-Bell-Shaped Cadmium Sulfide-Silica Nanoparticles2005
Author(s)
Pal, B., Torimoto, T., Ikeda, S., Shibayama, T., Sugawara, K., Takahashi, H., Ohtani, B. *
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Journal Title
Top. Catal. 35
Pages: 321-325
Description
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[Journal Article] Selective Photocatalytic Reduction of Nitrate to Nitrogen Molecules in an Aqueous Suspension of Metal-loaded Titanium(IV) Oxide Particl es2005
Author(s)
Kominami, H. *, Nakaseko, T., Shimada, Y., Furusho, A., Inoue, H., Murakami, S. -y., Kera, Y., Ohtani, B.
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Journal Title
Chem. Comaun.
Pages: 2933-2935
Description
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[Journal Article] Synthesis of Metal-Cadmium Sulfide Nanocomposites Using Jingle-Bell-Shaped Core-Shell Photocatalyst Particles2005
Author(s)
Pal, B., Torimoto, T., Iwasaki, K., Shibayama, T., Takahashi, H., Ohtani, B. *
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Journal Title
J. Appl. Electrochem. 35
Pages: 751-756
Description
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[Journal Article] Solvothermal Syntheses of Semiconductor Photocatalysts of Ultra-high Activities2003
Author(s)
Koininaini, H.*, Kato, J. -i., Murakami, S. -y., Ishii, Y., Kohno, M., Yabutani, K. -i., Yamamoto, T., Kera, Y., Inoue, M., Inui, T., Ohtani, B.
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Journal Title
Catal. Today 84
Pages: 181-189
Description
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