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Amorphization/Nanocrystallization of Shape Memory Alloys and Mechanism of Phase Transformation

Research Project

Project/Area Number 17360312
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionToyohashi University of Technology

Principal Investigator

TSUCHIYA Koichi  Toyohashi University of Technology, Faculty of Engineering, Associate Professor, 工学部, 助教授 (50236907)

Co-Investigator(Kenkyū-buntansha) TABUCHI Masayuki  Hakodate Polytechnic College, Dept. of General Science and Mathematics, Associate Professor, 一般科目理数系, 助教授 (90321364)
WATANABE Seiichi  Hokkaido University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (60241353)
TODAKA Yoshikazu  Toyohashi University of Technology, Faculty of Engineering, Research Associate, 工学部, 助手 (50345956)
UMEMOTO Minoru  Toyohashi University of Technology, Faculty of Engineering, Professor, 工学部, 教授 (90111921)
Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥13,400,000 (Direct Cost: ¥13,400,000)
Fiscal Year 2006: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2005: ¥10,200,000 (Direct Cost: ¥10,200,000)
Keywordsshape memory alloys / superelasticity / severe plastic deformation / amorphous / nanocrystalline / dislocations / twins / martensitic transformation
Research Abstract

TiNi shape memory alloy has been used in diverse areas of applications. Recently the application is expanding in the field of medical devices such as guide wires and stents due to the development of minimally invasive surgery. It is also know that the TiNi undergoes crystalline-to-amorphous transformation by severe plastic deformations. In the present investigation, the process of amorphization/nanocrystallization by various methods of severe plastic deformation, including cold rolling, high pressure torsion and shot peening, was investigated by TEM observations.
It was revealed that the B19' martensite reverts to B2 phase by plastic deformation and it transformed to amorphous by further deformation. Peculiar lamellar structures composed of alternative layers of amorphous and B2 crystalline phase. It was also found that the B2 layers on both sides of amorphous layers possess the almost identical crystallographic orientation. This indicates that the defect accumulation at the variant boundaries is responsible for the amorphization.
For comparison, Zr-Cu alloys with various compositions were deformed by HPT. Only Zr_<50>Cu_<50> exhibited amorphization. The alloy was in B19' phase and has the fine martensitic twin structure before deformation. Thus it can be inferred that the fine twin structure promotes the accumulation of dislocations and invoke amorphization.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (14 results)

All 2007 2006 2005

All Journal Article (14 results)

  • [Journal Article] Nanostructured Shape Memory Alloys for Biomedical Applications2007

    • Author(s)
      K.Tsuchiya, et al.
    • Journal Title

      Mater. Sci. Forum 539-547

      Pages: 505-510

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Nanostructured Shape Memory Alloys for Biomedical Applications2007

    • Author(s)
      K.Tsuchiya, et al.
    • Journal Title

      Mater.Sci.Forum 539-547

      Pages: 505-510

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Nanostructured Shape Memory Alloys for Biomedical Applications2007

    • Author(s)
      K.Tsuchiya, et al.
    • Journal Title

      Mater. Sci. Forum, 539-547(2007)505-510. 539-547

      Pages: 505-510

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Martensitic Transformation and Mechanical Behavior of TiNi Shape Memory Alloys after Severe Plastic Deformation2006

    • Author(s)
      K.Tsuchiya, et al.
    • Journal Title

      Mater. Sci. Forum 503-504

      Pages: 419-424

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] TiNi系形状記憶合金の表層非晶質化/ナノ結晶化に与えるショットピーニング条件の影響2006

    • Author(s)
      曹 奇峰ら
    • Journal Title

      J. Japan Inst. Metals(日本金属学会誌) 70

      Pages: 473-477

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Martensitic Transformation in Nanostructured TiNi formed viα Severe Plastic Deformation2006

    • Author(s)
      K.Tsuchiya, et al.
    • Journal Title

      Mater. Sci. Eng. A438-440

      Pages: 643-648

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] TEM Observations of Nanostructured TiNi Shape Memory Alloy Produced by Severe Plastic Deformation2006

    • Author(s)
      K.Tsuchiya et al.
    • Journal Title

      Proceedings of 16^<th> International Microscopy Congress

      Pages: 1295-1295

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Effect of Shot Peening on Surface Amorphization of TiNi Shape Memory Alloys2006

    • Author(s)
      Q.Cao et al.
    • Journal Title

      J.Japan Inst.Metals 70

      Pages: 473-477

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] TEM Observations of Nanostructured TiNi Shape Memory Alloy Produced by Severe Plastic Deformation2006

    • Author(s)
      K.Tsuchiya et al.
    • Journal Title

      Proceedings of 16th International Microscopy Congress

      Pages: 1295-1295

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Martensitic Transformation in Nanostructured TiNi formed via Severe Plastic Deformation2006

    • Author(s)
      K.Tsuchiya, et al.
    • Journal Title

      Mater. Sci. Eng., A438-440 (2006) 643-648. A438-440

      Pages: 643-648

    • Related Report
      2006 Annual Research Report
  • [Journal Article] TiNi系形状記憶合金の表層非晶質化/ナノ結晶化に与えるショットピーニング条件の影響2006

    • Author(s)
      曹 奇峰, 土谷浩一, 原田泰典, Dacian Tomus, 森井浩一, 戸高義一, 梅本実
    • Journal Title

      日本金属学会誌 (掲載予定)

    • NAID

      10018161187

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Martensitic Transformation and Mechanical Behavior of TiNi Shape Memory Alloys after Severe Plastic Deformation2006

    • Author(s)
      K.Tsuchiya, M.Inuzuka, A.Hosokawa, D.Tomus, H.Nakayama, K.Morii, Y.Todaka, M.Umemoto
    • Journal Title

      Mater.Sci.Forum. 503-504

      Pages: 419-424

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Martensitic Transformation and Mechanical Behavior of TiNi Shape Memory Alloys after Severe Plastic Deformation2005

    • Author(s)
      K.Tsuchiya, et al.
    • Journal Title

      Mater.Sci.Forum 503-504

      Pages: 419-424

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Surface Amorphization of TiNi Shape Memory Alloy by Shot Peening2005

    • Author(s)
      K.Tsuchiya, H.Nakayama, Y.Todaka, M.Umemoto, K.Morii
    • Journal Title

      J.Metastable and Nanocrystalline Solids 24-25

      Pages: 615-618

    • Related Report
      2005 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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