新しい炭素前駆体：２Ｄナノ材料を用いた２Ｄ／３Ｄ ＭＯＦｓの合成
| Project/Area Number |
17F17080
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 外国 |
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| Research Field |
Inorganic materials/Physical properties
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| Research Institution | National Institute for Materials Science |
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| Host Researcher |
井出 裕介 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究員 (40449327)
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| Foreign Research Fellow |
TANG JING 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
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| Project Period (FY) |
2017-04-26 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2018: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2017: ¥1,200,000 (Direct Cost: ¥1,200,000)
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| Keywords | 金属有機構造体 / 炭素材料 / 多孔体 |
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| Outline of Annual Research Achievements |
In this project, we have devoted to fabricating high-performance carbon-based electrode materials for electrochemical capacitance, electrochemical catalysis, and rechargeable batteries. We rationally designed MOF-derived carbon-based materials with controlled 2D/3D morphologies, doped heteroatoms, and encapsulated functional nanosheets, which were quite important and of great interest from the viewpoint of synthetic chemistry and practical electrochemical applications. ZIF-incorporated hybrid polymeric fibres were fabricated by using a dual‐phase electrospinning method. These were then transformed into Co3O4‐nanoparticle‐decorated porous N‐doped carbon fibres (ZIF‐Co3O4/NCF) through multi‐step annealing treatment. The resultant ZIF‐Co3O4/NCF was interweaved into a self‐supported film and could be used as a bi‐functional catalyst for catalysing oxygen reduction in both aqueous and non‐aqueous electrolytes. Electrochemical tests demonstrate that ZIF‐Co3O4/NCF displayed a high catalytic activity for oxygen reduction with a half‐wave potential (E1/2) of 0.813 V (vs. RHE) and an almost favourable four‐electron reduction pathway in alkaline medium.
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| Research Progress Status |
平成30年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
平成30年度が最終年度であるため、記入しない。
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Report
(2 results)
Research Products
(2 results)
