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Arsenic and its transformation of chemical form in the cycle of crust and hydrosphere

Research Project

Project/Area Number 17H01863
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionOsaka City University

Principal Investigator

Nakaya Harue  大阪市立大学, 大学院理学研究科, 教授 (70183944)

Co-Investigator(Kenkyū-buntansha) 三田村 宗樹  大阪市立大学, 大学院理学研究科, 教授 (00183632)
中村 英人  大阪市立大学, 大学院理学研究科, 特任講師 (00785123)
奥平 敬元  大阪市立大学, 大学院理学研究科, 教授 (20295679)
篠田 圭司  大阪市立大学, 大学院理学研究科, 准教授 (40221296)
西川 禎一  大阪市立大学, 大学院生活科学研究科, 教授 (60183539)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2019: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2018: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywordsヒ素の生物濃縮 / ヒ素化学形態 / プレートテクトニクス / マグマ性流体 / 付加体堆積物 / ヒ素の地球化学的循環 / ヒ素循環 / 水蒸気噴火 / 海底熱水系 / 付加体 / マグマ流体 / ヒ素汚染 / ヒ素化学形態分析 / 化学的風化作用 / ヒ素含有有機物 / 続成作用 / 環境分析 / 水圏現象 / 地球化学 / 有害化学物質 / 物質循環 / ケロジェン / 続成・変成作用 / 生物化学作用 / メタンハイドレート
Outline of Final Research Achievements

In order to document the arsenic behavior in the convergent margin of Philippine Sea Plate, transportation process and associating transformation of chemical species of arsenic was studied via geochemical analyses of the deep-sea sediment from Nankai Trough, accretionary complexes of Shimanto and Sambagawa belt in Shikoku, and magmatic fluids of Kirishima volcanoes. Obtained results are as follows. 1) Mobile arsenic is fixed in detritus and biogeochemcal reaction plays an important role to change the chemical forms of arsenic. 2) High arsenic concentration is derived from sea-floor hydrothermal activity, and arsenic in kerogen preserves until the host rock suffers with metamorphism at >300°C. 3) Magmatic fluid would contain arsenic derived from subducting slab.

Academic Significance and Societal Importance of the Research Achievements

ヒ素の地球化学的循環過程において、沈み込み帯とその周辺で海洋地殻と大陸地殻をつなぐ付加体やウェッジマントルでのヒ素の移動過程を、観察から明らかにした初めての報告である。ヒ素の化学形態分析により、深海底の少なくとも500mまでの深度の海底堆積物や火山の山体などで、可動性の高いヒ素の化学形態について、生物化学作用が重要な働きをしていることを明示した点は、学術的意義が高い。また、生物化学作用を用いたヒ素の無毒化や鉱物への固定などの基礎的情報となり、新たなヒ素汚染抑制対策を開発する際の基本原理を与える点で社会的意義がある。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (40 results)

All 2019 2018 2017 Other

All Int'l Joint Research (1 results) Journal Article (12 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 4 results) Presentation (25 results) (of which Int'l Joint Research: 8 results,  Invited: 3 results) Book (2 results)

  • [Int'l Joint Research] トリブバン大学(ネパール)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Leaching characteristics of naturally derived toxic elements in the alluvial marine clay layer beneath Osaka Plain, Japan: implications for the reuse of excavated soils2019

    • Author(s)
      Ito H., Masuda H., Oshima A.
    • Journal Title

      Environmental Earth Sciences

      Volume: 78 Issue: 20 Pages: 589

    • DOI

      10.1007/s12665-019-8595-3

    • NAID

      120006900906

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019824

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Vertical profiles of arsenic and arsenic species transformations in deep-sea sediment, Nankai Trough, offshore Japan2019

    • Author(s)
      Harue Masuda、Haruka Yoshinishi、Shigeshi Fuchida、Tomohiro Toki、Emilie Even
    • Journal Title

      Progress in Earth and Planetary Science

      Volume: 6 Issue: 1 Pages: 28-28

    • DOI

      10.1186/s40645-019-0269-y

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Forms of trace arsenic, cesium, cadmium, and lead transported into river water for the irrigation of Japanese paddy rice fields2018

    • Author(s)
      Nakaya S., Murota S., Hai C., Masuda H.
    • Journal Title

      Journal of Hydrology

      Volume: 51 Issue: 23 Pages: 335-347

    • DOI

      10.1002/hyp.13277

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Arsenic cycling in the Earth’s crust and hydrosphere: interaction between naturally occurring arsenic and human activities2018

    • Author(s)
      Masuda H.
    • Journal Title

      Progress in Earth and Planetary Science

      Volume: 5 Issue: 1 Pages: 68-68

    • DOI

      10.1186/s40645-018-0224-3

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Forms of trace arsenic, cesium, cadmium, and lead transported into river water for the irrigation of Japanese paddy rice fields.2018

    • Author(s)
      Nakaya S., Murota S., Hai C., Masuda H.
    • Journal Title

      Journal of Hydrology

      Volume: 51 Pages: 335-347

    • DOI

      10.1016/j.jhydrol.2018.04.018

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 大阪平野の地下水の帯水層構造と水質-特に低深度の地下水の抱える課題-2018

    • Author(s)
      益田晴恵
    • Journal Title

      地下水技術

      Volume: 69

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 陸域断層の内部構造.2018

    • Author(s)
      重松紀生・大谷具幸・小林健太・奥平敬元・豊島剛志
    • Journal Title

      地質学雑誌

      Volume: 124

    • NAID

      130007530983

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 大阪平野の地下水帯水層と水質構造2017

    • Author(s)
      益田晴恵・新谷毅
    • Journal Title

      環境技術

      Volume: 46 Pages: 241-247

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 地球表層部のヒ素の分布と環境汚染の要因2017

    • Author(s)
      益田晴恵
    • Journal Title

      地球環境

      Volume: 22 Pages: 3-12

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Grain size reduction due to fracturing and subsequent grain-size-sensitive creep in a lower crustal shear zone in the presence of CO2-rich fluid.2017

    • Author(s)
      Okudaira T., Shigematsu N., Harigane Y., Yoshida K.
    • Journal Title

      Journal of Structural Geology

      Volume: 95

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Reaction-induced grain boundary cracking and anisotropic fluid flow during prograde devolatilization reactions within subduction zones2017

    • Author(s)
      Okamoto A, Shimizu H, Fukuda JI, Muto J, Okudaira T
    • Journal Title

      Contributions to Mineralogy and Petrology

      Volume: 172 Issue: 9 Pages: 1-23

    • DOI

      10.1007/s00410-017-1393-6

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison by multilocus variable-number tandem repeat analysis and antimicrobial resistance among atypical enteropathogenic Escherichia coli strains isolated from food samples and human and animal faecal specimens2017

    • Author(s)
      Wang, L., Nakamura, H., Kage-Nakadai, E., Hara-Kudo, Y., and Nishikawa, Y.
    • Journal Title

      J. Appl. Microbiol.

      Volume: 122 Issue: 1 Pages: 268-278

    • DOI

      10.1111/jam.13322

    • NAID

      120006319607

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019940

    • Related Report
      2017 Annual Research Report
  • [Presentation] 霧島連山と薩摩硫黄島における熱水活動に伴うヒ素と水銀の挙動2019

    • Author(s)
      羽渕元哉・益田晴恵・新谷毅・古谷宗三・森啓悟・石橋純一郎・松島健・武内章記・大嶋将吾・井川怜欧
    • Organizer
      日本地球惑星科学連合大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 霧島火山群・硫黄山水蒸気噴火に関連した熱水循環プロセス2019

    • Author(s)
      森啓悟・益田晴恵・新谷毅・羽渕元哉・古谷宗三・石橋純一郎・松島健・大嶋将吾・井川怜欧
    • Organizer
      日本地球惑星科学連合大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 四国の付加体堆積岩中のヒ素の挙動2019

    • Author(s)
      古谷宗三・益田晴恵・中村英人
    • Organizer
      日本地球化学会年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] プレート収束域で上昇する水銀の起源2019

    • Author(s)
      益田晴恵・武内章記・石橋純一郎・松島健
    • Organizer
      日本地球化学会年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Geological cycles of arsenic and mercury- element behavior related to plate tectonics2019

    • Author(s)
      Masuda H.
    • Organizer
      4th China-Japan Forum in Annual Meeting of Chinese Association of Petrology, Mineralogy and Geochemistry
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Geological cycles of arsenic and mercury; element behavior related to plate tectonics2019

    • Author(s)
      Masuda H.
    • Organizer
      4th China-Japan Forum in Annual Meeting of Chinese Association of Petrology, Mineralogy and Geochemistry, Hangzhou. (2019.4.21)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Arsenic behavior in accretionary complex of Shikoku, Japan2018

    • Author(s)
      古谷宗三・中村英人・益田晴恵
    • Organizer
      2018年日本地球惑星科学連合大会,SGL29-06, 千葉.(2018.05.24)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 河川系に置ける地質由来ヒ素の水田涵養用水を経由する土壌水から水稲への輸送と蓄積2018

    • Author(s)
      中屋眞司・遅海・室田健吾・益田晴恵
    • Organizer
      2018年日本地球惑星科学連合大会,AHW20-17, 千葉.(2018.05.21)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 西大阪地域における沖積粘土中の自然由来重金属等の存在形態2018

    • Author(s)
      伊藤浩子・益田晴恵・大島昭彦
    • Organizer
      第53回地盤工学研究発表会講演集,2239-2240. 高松(2018.7)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Effect of recharging water from Megna River to the arsenic contaminated groundwater2018

    • Author(s)
      Masuda H., Hirai N., Reza S.
    • Organizer
      The 7th International Congress & Exhibition on arsenic in environment, Environmental arsenic and changing world. Beijing. (2018.07.03)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Concentrations of the naturally-derived toxic elements and its geochemical characteristics of the alluvial marine clay layer of Osaka Plain, Japan2018

    • Author(s)
      Ito H., Masuda H., Oshima A.
    • Organizer
      Proceedings of the 8th International Congress on Environmental Geotechnics 1:504-511.Hangzhou.(2018.10)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Studies on As contaminated groundwaters _an example of international scientific activity against environmental problem2017

    • Author(s)
      Masuda H.
    • Organizer
      JpGU_AGU Joint Meeting 2017,MIS03-10
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 水系を経由して水田に運ばれるヒ素,天然セシウム,鉄の輸送と水稲内の移動メカニズム.2017

    • Author(s)
      中屋眞司・石川満範・室田健吾・益田晴恵
    • Organizer
      日本地球惑星科学連合大会,A-HW32.
    • Related Report
      2017 Annual Research Report
  • [Presentation] Groundwater flow system in eastern half of Fukushima Prefecture and its surrounding _calculation of mean residence time based on CFCs and SF6-.2017

    • Author(s)
      村崎友亮・益田晴恵・山野翔馬・井上凌・坂本裕介・新谷毅・平井望生・近岡史絵・後藤葵・中屋眞司・丸井敦尚・小野昌彦
    • Organizer
      日本地球惑星科学連合大会,AHW36-01
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大阪市内における沖積粘土層中の自然由来重金属類 の含有状況とその地球化学的特徴.2017

    • Author(s)
      伊藤浩子・益田晴恵・ 大島昭彦・北田奈緒子・藤原照幸
    • Organizer
      第52回地盤工学研究発表会, 1014.
    • Related Report
      2017 Annual Research Report
  • [Presentation] GIS を用いた大阪平野の地下水水質の 3 次元可視化.2017

    • Author(s)
      新谷 毅・益田晴恵・根本達也・三田村宗樹・丸井敦尚
    • Organizer
      日本地下水学会秋期講演会,P03
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大阪平野に置ける沖積粘土の自然由来重金属類の含有状況とその地球化学的特徴.2017

    • Author(s)
      伊藤浩子・益田晴恵・ 大島昭彦・北田奈緒子・藤原照幸
    • Organizer
      第12回環境地盤工学シンポジウム,13-5
    • Related Report
      2017 Annual Research Report
  • [Presentation] Hydrogeochemical and Isotopic Evidence of Groundwater Salinization Processes in the Coastal Paleobeach Aquifer of Cox’s Bazar _Teknaf Area, South-East Bangladesh.2017

    • Author(s)
      Seddique A, Maruoka T, Yoriko Y., Anma R., Masuda H.
    • Organizer
      Goldschmidt Conference 2017, P 2063, 11j
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Petrology and geochronology of rocks in and around Chitradurga shear zone: Some insights to the mode and timing of amalgamation of western and eastern Dharwar cratons, South India.2017

    • Author(s)
      Nasheeth A, Okudaira T, Hokada T, Horie K, Satish-Kumar M, Ueno Y,
    • Organizer
      8th Symposium on Polar Science, National Institute of Polar Research
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The role of fracturing on the formation of the lower crustal shear zones.2017

    • Author(s)
      Okudaira T,
    • Organizer
      JpGU_AGU Joint Meeting 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 紀伊半島東部の中央構造線の最近の調査結果.2017

    • Author(s)
      重松紀生・藤本光一郎・亀高正男・奥平敬元・森 宏
    • Organizer
      日本地質学会第124年学術大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大阪平野における帯水層蓄熱(ATES)に関わる帯水層評価2017

    • Author(s)
      三田村宗樹
    • Organizer
      日本地質学会第124年学術大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大阪市阿倍野区における地区防災教室の実施と防災意識の変化―地区防災教室ネットワークによる防災行動マネジメントに向けて―2017

    • Author(s)
      生田英輔・三田村宗樹・佐伯大輔
    • Organizer
      地区防災計画学会第4回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] メスバウアースペクトルによるエジリンのFe3+の電場勾配主軸方向の検討2017

    • Author(s)
      篠田圭司・小林康浩
    • Organizer
      日本鉱物科学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 健康者由来の分散接着性大腸菌はVI型分泌装置によって上皮細胞からのIL-8分泌を抑制する2017

    • Author(s)
      谷本佳彦、竹内成美、玉井沙也加、柳田 咲、中台(鹿毛)枝里子、山口良弘、西川禎一
    • Organizer
      第70回日本細菌学会関西支部学術集会
    • Related Report
      2017 Annual Research Report
  • [Book] 「人と自然の環境学 ―持続可能な地域づくりにむけて」 第7章 大都市の水環境―健全な利用を進める2018

    • Author(s)
      益田晴恵
    • Publisher
      東京大学出版会
    • Related Report
      2017 Annual Research Report
  • [Book] 「コミュニティ防災の基本と実践」第1章:第1話:災害リスクとは,第2話:災害の種類,第3話:地震災害で起こること,第6話:土砂災害のリスクを知る2017

    • Author(s)
      三田村宗樹著、公立大学連携地区防災教室ワークブック編集委員会・大阪市立大学 都市防災教育研究センター編
    • Total Pages
      231
    • Publisher
      大阪公立大学共同出版会
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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