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Ambient pressure-induction of high pressure organic synthesis with in-pore super high pressure effect

Research Project

Project/Area Number 17H03039
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional solid state chemistry
Research InstitutionShinshu University

Principal Investigator

Kaneko Katsumi  信州大学, 先鋭領域融合研究群先鋭材料研究所, 特別特任教授 (20009608)

Co-Investigator(Kenkyū-buntansha) 服部 義之  信州大学, 学術研究院繊維学系, 教授 (20456495)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2019: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2018: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2017: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Keywordsナノ空間 / 単層カーボンナノチューブ / 高圧有機合成化学 / 分子間相互作用 / 細孔内反応機構 / フタロシアニン / 電子顕微鏡 / ナノ細孔空間 / 超制約効果 / ナノチューブ / イメージチャージ効果 / 分子シミュレーション / 高圧有機合成反応 / カーボン細孔体 / ナノ細孔体 / 高圧反応 / 吸着 / 表面 / 有機合成 / 細孔場超高圧効果 / ナノ細孔 / 赤外分法法 / 物理触媒作用 / ナノ細孔分子場 / 結晶成長 / 結晶核 / 細孔性グラフェン / カーボン / ナノ細孔場 / カーボンナノチューブ
Outline of Final Research Achievements

High pressure chemistry is essentially important in enhancement of the chemical reaction rate and induction of specific reactions. High pressure chemistry must use autoclaves, being energy-intensive and less safe. We should invent a new science enabling the effective induction of high pressure reactions under ambient conditions. Carbon nanopores such as internal spaces of single wall carbon nanotube(SWCNT) can highly compress molecules whose density corresponds to that under about 1 GPa. We succeeded to induce representative high pressure organic synthetic reactions under ambient conditions using SWCNTs. The transfer of nuclei formed inside nanopores to the bulk reaction media gives the abundant products. The obtained products are trans-cyclohexanediol and Cu phthalocyanine which are identified by synchrotron X-ray diffraction, infra-red spectroscopy, high resolution transmission microscopy and other methods.

Academic Significance and Societal Importance of the Research Achievements

化学工業は基本的に全産業のエネルギーの半分近くを消費する。高圧化学はよりスペースを必要とし、安全性に課題が残る。従って、数万から数十万気圧におよぶ高圧化学・工学を常圧下で行えると、省エネルギー・省スペース・安全という大きなメリットが得られ、学術的ならびに人類への貢献が顕著である。本研究では、内部求引圧力が10万気圧相当の単層カーボンナノチューブ(SWCNT)のナノ空間を用いて、高圧下で生成する目的有機化合物のタネ結晶を大気圧下で合成して、バルク反応相に移行して大量の目的有機化合物を合成する方法を開発した。本方法は医療品として必要な有機化合物合成にも応用可能であり、その意義は大きい。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (45 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (11 results) Journal Article (10 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 10 results,  Open Access: 10 results) Presentation (21 results) (of which Int'l Joint Research: 11 results,  Invited: 10 results) Book (1 results) Remarks (2 results)

  • [Int'l Joint Research] カリフォルニア大学LA校/ドレクセル大学/ピッツバーグ大学(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ツールズ大学(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ドレスデン大学(ドイツ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] コペルニクス大学(ポーランド)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] North Caolina State University(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Indonesia University of Education(インドネシア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Sorbonne University/Paul Sabatier University(France)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Loughborough University(英国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Drexel University(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Nicolaus Copernicus University in Torun(Poland)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Murdoch University(Australia)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 523.Mesoscopic cage-like structured single-wall carbon nanotube cryogels2020

    • Author(s)
      Y. Kamijyou, D. Stevic, R. Kukobat, K. Urita , N. Chotimah, Y. Hattori, R. Futamura, F. Vallejos-Burgos, I. Moriguchi, S. Utsumi, T. Sakai, K. Kaneko
    • Journal Title

      Microporous Mesoporous Materials

      Volume: 293 Pages: 109814-109822

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 518.Thermally stable near UV-light transparent and conducting SWCNT/glass flexible films2019

    • Author(s)
      R. Kukobat, Y. Kamijyou, D. Stev, T. Hayashi, T. Sakai, K. Kaneko
    • Journal Title

      Carbon

      Volume: 152 Pages: 7-15

    • DOI

      10.1016/j.carbon.2019.04.053

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 517.Unusual hygroscopic nature of nanodiamonds in comparison with well-known porous materials2019

    • Author(s)
      E.-Z. Piña-Salazar, T. Sakai, E. Osawa, R. Futamura, K. Kaneko
    • Journal Title

      J. Colloid Interface Science

      Volume: 549 Pages: 133-139

    • DOI

      10.1016/j.jcis.2019.04.053

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 519.Measuring adsorption isotherms with a flowmeter and a pressure gauge :Observations on the quasi-equilibrium method2019

    • Author(s)
      F. Vallejos-Burgos, K. Kaneko
    • Journal Title

      Adsorption

      Volume: 25 Issue: 4 Pages: 809-817

    • DOI

      10.1007/s10450-019-00068-8

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 520.An asymmetric supercapacitor-diode (CAPode) for unidirectional energy storage2019

    • Author(s)
      E. Zhang, G.P. Hao, H.Y.- Zhang, K. Kaneko, L. Borchardt. S. Kaskel
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 58 Issue: 37 Pages: 2-8

    • DOI

      10.1002/anie.201904888

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 512.Water-selective adsorption sites on detonation nanodiamonds2018

    • Author(s)
      E.Z.Pina-Salazar, R. Kukobat, R. Futamura, T. Hayashi, S. Toshio, E. Osawa, K. Kaneko
    • Journal Title

      Carbon

      Volume: 139 Pages: 53-860

    • DOI

      10.1016/j.carbon.2018.07.036

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 513.Mild oxidation-production of subnanometer-sized nanowindows of single wall carbon nanohorn2018

    • Author(s)
      N. Tanigaki, K. Murata, T. Hayashi, K. Kaneko
    • Journal Title

      J. Colloid Interface Sccience

      Volume: 529 Pages: 32-336

    • DOI

      10.1016/j.jcis.2018.06.023

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 514.X-ray absorption anomaly of well-characterized multiwall carbon nanotubes2018

    • Author(s)
      F. Lhoerunnisa, R. Futamura, S.Mukai, T. Konishi, T. Fujikawa, K. Kaneko
    • Journal Title

      Carbon

      Volume: 145 Pages: 209-217

    • DOI

      10.1016/j.carbon.2019.01.021

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores2017

    • Author(s)
      Ryusuke Futamura, Taku Iiyama, Yuma Takasaki, Yury Gogotsi, Mark Biggs, Mathieu Salanne, Julie Segalini, Patrice Simon, Katsumi Kaneko
    • Journal Title

      Nature Materials

      Volume: 16 Issue: 12 Pages: 1225-1232

    • DOI

      10.1038/nmat4974

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Water adsorption property of hierarchically nanoporous detonation nanodiamonds2017

    • Author(s)
      E.-Z. Pina-Salazar, K.Urita, T. Hayashi, R. Futamura, F. Vallejos-Burgos, J. Wloch, P. Kowalczyk, M. Winiewski, T. Sakai, I. Moriguchi, A. Terzyk, E. Osawa, K. Kaneko
    • Journal Title

      Langmuir

      Volume: 33 Pages: 11180-11188

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] INTERFACIAL SCIENCE OF GRAPHENE-BASED NANOSTRUCTURES2020

    • Author(s)
      K. Kaneko
    • Organizer
      2nd Global Conference on Carbon Nanotubes and Graphene Technologies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] INTRINSIC FUNCTIONS OF NANOSCALE INTERFACIAL CARBON STRUTURES2019

    • Author(s)
      K.Kaneko
    • Organizer
      47th IUPAC Congress: Symposium for Electrochemical Energy Storage and Conversion Systems
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Engineering Perspectives of Water and Ionic Solution Constrained at Interfacial Nanostructures2019

    • Author(s)
      K. Kaneko
    • Organizer
      Symposium on Advanced Water Science and Technology
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子系と協奏的に相互作用する表面性固体の賢さ2019

    • Author(s)
      金子克美
    • Organizer
      第50回中部化学関係協会支部連合秋季大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Ambient pressure synthesis of cyclohexanediol high pressure organic reaction through in-pore superhigh pressure effect of SWCNTs2019

    • Author(s)
      A. Furuse, R. Futamura, K. Kaneko
    • Organizer
      Okinawa colloid 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ambient pressure-induction of cyclohexanediol high pressure organic reaction with in-pore superhigh pressure effect2019

    • Author(s)
      A. Furuse, R. Futamura, K. Kaneko
    • Organizer
      Adsorption 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pore Structure Analysis of SWCNT Cryogels2019

    • Author(s)
      Y. Kamijyou, R. Kukobat, R. Futamura, F. Vallejos-Burgos, T. Sakai, K. Kaneko
    • Organizer
      13th Fundamentals of Adsorption
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structure and Porosity Regulations of Carbon Materials by Thermal-treatment and Air Oxidation2019

    • Author(s)
      S. Wang, K. Kaneko
    • Organizer
      Carbon2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノダイヤモンドの異常吸湿性の相対評価2019

    • Author(s)
      3.P. S. Elda-Zoraida, 二村竜祐、酒井俊郎、大澤映二、金子克美
    • Organizer
      第46回炭素材料学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Ambient pressure induction mechanism of cyclohexanediol high pressure synthesis inside single wall carbon nanotube pores2019

    • Author(s)
      A. Furuse, R. Futamura, K. Kaneko
    • Organizer
      日本化学会第99春季年会(2019)
    • Related Report
      2019 Annual Research Report
  • [Presentation] SWCNT凍結乾燥ゲルの細孔構造2019

    • Author(s)
      1.上條由人, R. Kukobat, 瓜田幸幾, 服部義之, 二村竜祐, 森口勇, 酒井俊郎, 金子克美
    • Organizer
      第33回日本吸着学会発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 単層カーボンナノチューブネットの細孔構造2019

    • Author(s)
      山田麻夢, R. Kukobat, 服部義之, 金子克美
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] グラフェン様構造を生かしたナノ界面エンジニアリング2019

    • Author(s)
      金子克美
    • Organizer
      2次元材料に関する第二回KOINEミーティング
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] カーボンナノ細孔内での超高圧効果を利用した1,2-シクロヘキサンジオールの常圧合成2018

    • Author(s)
      古瀬あゆみ, 二村竜祐, 金子克美
    • Organizer
      第32回日本吸着学会研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ambient pressure induction mechanism of cyclohexanediol high pressure synthesis inside single wall carbon nanotube pores2018

    • Author(s)
      FURUSE Ayumi, FUTAMURA Ryusuke, KANEKO Katsumi
    • Organizer
      日本化学会第99春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] INTERFACE SCIENCE OF CARBON MATERIALS2018

    • Author(s)
      K. Kaneko
    • Organizer
      Energy Materials Nanotechnology Meeting on Mesoporous Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] NANOCONFINEMENT MEDIATED MATERIALS/ADSORPTION ENGINEERING2018

    • Author(s)
      K.Kaneko
    • Organizer
      International Workshop “Characterizationn of Porous Materials from Angstromes to Milimeters
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 企画の趣旨及び最新の吸着科学と可能性2018

    • Author(s)
      金子克美
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Porous SWCNT/Graphene Films2017

    • Author(s)
      N. Chotimah, T. Sakai, K.Kaneko
    • Organizer
      吸着学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Interfacial Science and Engineering of Highly Surfaceous Carbons2017

    • Author(s)
      K.Kaneko
    • Organizer
      7th International Symposium on Energy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale Environment-Interactive Carbon Engineering2017

    • Author(s)
      K. Kaneko
    • Organizer
      Carbon2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] Nanoporous Materials for Gas Storage2019

    • Author(s)
      K. Kaneko, F. Rodoriguez-Reinoso
    • Total Pages
      403
    • Publisher
      Springer
    • Related Report
      2019 Annual Research Report
  • [Remarks] Katsumi Kanreko Research Group

    • URL

      http://www.shinshu-u.ac.jp/faculty/engineering/kaneko-group/

    • Related Report
      2018 Annual Research Report
  • [Remarks] Superinterface-Nanospace Science and Technology

    • URL

      http://goo.gl/tcpTuy

    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2022-06-10  

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