| Budget Amount *help |
¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Fiscal Year 2019: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2018: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
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| Outline of Final Research Achievements |
Two-component self-assembly of photopolymerizable zwitterionic molecule and acids such as benzenesulfonic acid and protic ionic liquids provided the hexagonal columnar liquid-crystalline phases. In-situ photopolymerization allowed for the construction of self-standing high-proton conductive polymer films. We revealed that the LC nanostructured films exhibited higher proton conduction with lower activation energy than those of amorphous films.
In addition, we demonstrated that the Bronsted base/acid complexes consisting of imidazole derivative with long alkyl chains and various acids such as benzenesulfonic acid formed the columnar, bicontinuous cubic, and smectic LC phases by simply changing the mixing ratio.
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