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Experimental study of heat-resistant and photoluminescent polymers exhibiting extremely large Stokes shift for spectral conversion

Research Project

Project/Area Number 17H03112
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Ando Shinji  東京工業大学, 物質理工学院, 教授 (00272667)

Co-Investigator(Kenkyū-buntansha) 石毛 亮平  東京工業大学, 物質理工学院, 助教 (20625264)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2019: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2018: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Keywords高分子機能材料 / 光波長変換材料 / 高発光性ポリイミド / 室温燐光 / 励起状態プロトン移動 / ドナー・アクセプター
Outline of Final Research Achievements

Based on the knowledge of molecular design and optical properties of highly luminescent polyimides (HLPI), we designed and selected polyimide copolymers with excellent properties for solar wavelength conversion membranes and established the synthesis, film formation, and characterization techniques for large-area HLPI membranes that can be used as practical wavelength conversion membranes. Specifically, a new polyimide copolymer was synthesized by mixing a highly efficient blue-fluorescent acid dianhydride and a small amount of a red-orange luminescent acid dianhydride undergoing excited-state proton transfer. An HLPI film thus obtained is almost completely transparent and has an extremely large Stokes shift (>11,000 cm-1) through an efficient excitation energy transfer between the two polymers with a ultraviolet conversion efficiency of up to 23%. The HLPI film was uniformly deposited on a 6-inch-diameter optical glass substrate.

Academic Significance and Societal Importance of the Research Achievements

本研究で開発された高発光性ポリイミド(HLPI)膜は、合成と製膜が容易な点に加え、350℃以上の耐熱性、高い耐光性と耐環境性、柔軟性と軽量性、十分な機械強度を有し、無色透明かつ高効率の赤橙色発光を示す初めての高分子膜であり、その学術的意義は極めて高い.このHLPI膜を太陽光波長変換膜として利用することで、Si系やペロブスカイト型太陽電池の変換効率向上が可能であり、再生可能エネルギーの加速に資することができる.

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (48 results)

All 2019 2018 2017 Other

All Int'l Joint Research (10 results) Journal Article (11 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 11 results,  Open Access: 4 results) Presentation (25 results) (of which Int'l Joint Research: 6 results,  Invited: 6 results) Book (1 results) Remarks (1 results)

  • [Int'l Joint Research] ビルニュス物理科学研究セン ター(リトアニア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ウィーン工科大学(オーストリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] 中国科学院過程工程研究所(中国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] プサン国立大学校(韓国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] 国立台湾科技大・国立台湾大(その他の国・地域)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ビルニュス物理科学研究センター(リトアニア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ウィーン工科大学(オーストリア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] 国立台湾科技大・国立台湾大(台湾)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ヴィルニュス物理科学研究センター(リトアニア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ウィーン工科大学(オーストリア)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Photoluminescence Properties of Novel Fluorescent Polyimide Based on Excited State Intramolecular Proton Transfer at The End Groups2019

    • Author(s)
      Naiqiang LIANG, Eisuke FUJIWARA, Mayuko NARA, Ryohei ISHIGE, Shinji ANDO
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 32 Issue: 3 Pages: 449-455

    • DOI

      10.2494/photopolymer.32.449

    • NAID

      130007744405

    • ISSN
      0914-9244, 1349-6336
    • Year and Date
      2019-06-24
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Colorless Troeger’s Base-based Partially Alicyclic Polyimides Exhibiting Good Solubility and Dual Fluorescence/Phosphorescence Emission2019

    • Author(s)
      Yongbing ZHUANG, Ryoji ORITA, Eisuke FUJIWARA, Yu ZHANG, Shinji ANDO
    • Journal Title

      Macromolecules

      Volume: 52 Issue: 10 Pages: 3813-3824

    • DOI

      10.1021/acs.macromol.9b00273

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of fluorescent polycarbonates with highly twisted N,N-bis(dialkylamino)anthracene AIE luminogens in the main chain2019

    • Author(s)
      Sairi Amir Sharidan、Kuwahara Kohei、Sasaki Shunsuke、Suzuki Satoshi、Igawa Kazunobu、Tokita Masatoshi、Ando Shinji、Morokuma Keiji、Suenobu Tomoyoshi、Konishi Gen-ichi
    • Journal Title

      RSC Advances

      Volume: 9 Issue: 38 Pages: 21733-21740

    • DOI

      10.1039/c9ra03701b

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis and Characterization of Photo-Conductive Polyimides Derived from a Novel Imidazole Containing Diamine2019

    • Author(s)
      Keuk-Min JEONG, Pradip Kumar TAPASWI, Takehiko KAMBARA, Ryohei ISHIGE, Shinji ANDO, Chang-Sik HA
    • Journal Title

      High Perform. Polym.

      Volume: 2019 Issue: 6 Pages: 1-11

    • DOI

      10.1177/0954008319892307

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Colorless Semi-aromatic Polyimide Derived from a Sterically Hindered Bromine-Substituted Dianhydride Exhibiting Dual Fluorescent and Phosphorescent Emission2019

    • Author(s)
      Kenta Kanosue, Shuzo Hirata, Martin Vacha, Ramunas Augulis, Vidmantas Gulbinas, Ryohei Ishige, Shinji Ando
    • Journal Title

      Materials Chemistry Frontier

      Volume: 3 Issue: 1 Pages: 39-49

    • DOI

      10.1039/c8qm00409a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhanced Fluorescence of Phthalimide Compounds Induced by the Incorporation of Electron-Donating Alicyclic Amino Groups2018

    • Author(s)
      Ryoji ORITA, Marius FRANCKEVIUS, Aurimas VYNIAUSKAS, Vidmantas GULBINAS, Haruki SUGIYAMA, Hidehiro UEKUSA, Kenta KANOSUE, Ryohei ISHIGE, Shinji ANDO
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 20 Issue: 23 Pages: 16033-16044

    • DOI

      10.1039/c8cp01999a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Pressure-Induced Variations of Aggregation Structures in Colorless and Transparent Polyimide Films Analyzed by Optical Microscopy, UV.Vis Absorption, and Fluorescence Spectroscopy2018

    • Author(s)
      Eisuke FUJIWARA, Hiroshi FUKUDOME, Kazuhiro TAKIZAWA, Ryohei ISHIGE, Shinji ANDO
    • Journal Title

      J. Phys. Chem. B.

      Volume: 122 Issue: 38 Pages: 8985-8997

    • DOI

      10.1021/acs.jpcb.8b06423

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancing Photoconductivity of Aromatic Polyimide Films by Incorporating Fluorinated Dianhydrides and Main Chain Triphenylamine Structure2018

    • Author(s)
      Kazuhiro TAKIZAWA, Sho FUKUCHI, Chiaki TAKEMASA, Ryohei ISHIGE, Shigeo ASAI, Shinji ANDO
    • Journal Title

      Polymer (Elsevier)

      Volume: 157 Pages: 122-130

    • DOI

      10.1016/j.polymer.2018.10.025

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photophysical relaxation mechanism of excited phtalimide compounds2018

    • Author(s)
      Ignas CIPLYS, Ryoji ORITA, Shinji ANDO, Vidamantas GULBINAS
    • Journal Title

      Lithuanian J. Phys.

      Volume: 58 Issue: 4 Pages: 337-345

    • DOI

      10.3952/physics.v58i4.3878

    • NAID

      120006715880

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Design and Synthesis of Multi-Colour Luminescent Polyimides with Very Large Stokes Shifts and Their Performance for Solar Spectral Conversion2017

    • Author(s)
      Kenta KANOSUE, Takamichi SHIMOSAKA, Junji WAKITA, Ryohei ISHIGE, Shinji ANDO
    • Journal Title

      Proceedings of STEPI-10

      Volume: 10 Pages: 143-150

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Analysis of Luminescence Properties of Phosphorescent Polyimides under Low Temperature and Vacuum Conditions2017

    • Author(s)
      Kenta KANOSUE, Shinji ANDO
    • Journal Title

      Scientific Instrument News

      Volume: 8 Pages: 19-27

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Multi-color Fluorescent/Phospholescent Polyimides Exhibiting Very Large Stokes Shifts and Their Application For Solar Spectral Conversion2019

    • Author(s)
      Shinji ANDO
    • Organizer
      Symp. ICL-TokyoTech Plastic Electronics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Polyimides and Imide Compounds Exhibiting High Optical Transparency and Enhanced Phosphorescence Emission under Atmospheric and Very High Pressure2019

    • Author(s)
      Shinji ANDO, Mayuko NARA, Yutaro ANDO, Kenta KANOSUE, Ryohei ISHIGE
    • Organizer
      STEPI-11 (Montpellier, France)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photoluminescence Properties of Novel Fluorescent Polyimide based on Excited State Intramolecular Proton Transfer at the End Groups2019

    • Author(s)
      Naiqiang LIANG, Eisuke FUJIWARA, Mayuko NARA, Ryohei ISHIGE, Shinji ANDO
    • Organizer
      Photopolym. Sci. Technol. Conf. (Chiba, Japan)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超高圧下での発光寿命測定に基づく燐光性ポリイミド薄膜および低分子イミド化合物の発光挙動と凝集状態の相関解析2019

    • Author(s)
      安東 優太郎・藤原 瑛右・折田 良司・石毛 亮平・M. Franckeviius・A. Vysniauskas・V. Gulbinas・安藤 慎治
    • Organizer
      高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 分子鎖末端に臭素を導入したポリイミド薄膜の室温燐光特性と光物理過程の解析2019

    • Author(s)
      奈良 麻優子・折田 良司・石毛 亮平・安藤 慎治
    • Organizer
      高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Photoluminescence Properties of Novel Fluorescent Polyimide based on Excited State Intramolecular Proton Transfer at the End Groups2019

    • Author(s)
      Naiqiang Liang, Eisuke Fujiwara, Mayuko Nara, Ryohei Ishige, Shinji Ando
    • Organizer
      高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 温度可変発光スペクトル測定に基づく高発光性ポリイミドの蛍光・燐光特性解析2019

    • Author(s)
      奈良 麻優子・藤原 瑛右・石毛 亮平・安藤 慎治
    • Organizer
      光化学討論会年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Highly Transparent and Orange Fluorescent Polyimide Copolymers based on Excited Intramolecular Proton Transfer in the Main Chain2019

    • Author(s)
      Naiqiang Liang, Mayuko Nara, Eisuke Fujiwara, Ryohei Ishige, Shinji Ando
    • Organizer
      高分子学会討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 赤/白色励起状態プロトン移動蛍光を示す末端修飾ポリイミドに向けた蛍光性化合物の合成と光学物性2019

    • Author(s)
      田淵 敦子・奈良 麻優子・石毛 亮平・安藤 慎治
    • Organizer
      日本ポリイミド・芳香族系高分子会議
    • Related Report
      2019 Annual Research Report
  • [Presentation] ナフタレン骨格を有する燐光発光性イミド化合物の発光特性解析2019

    • Author(s)
      土井 真里奈・武藤 江一朗・奈良 麻優子・梁 乃強・藤原 瑛右・石毛 亮平・安藤 慎治・佐野 浩介・森 浩章
    • Organizer
      日本ポリイミド・芳香族系高分子会議
    • Related Report
      2019 Annual Research Report
  • [Presentation] 温度可変発光スペクトル測定に基づく高蛍光性ポリイミドの発光特性解析2019

    • Author(s)
      奈良 麻優子・藤原 瑛右・石毛 亮平・安藤 慎治
    • Organizer
      日本ポリイミド・芳香族系高分子会議
    • Related Report
      2019 Annual Research Report
  • [Presentation] Multi-Color Fluorescent / Phospholescent Polyimides Exhibiting Very Large Stokes Shifts and Their Performance for Solar Spectral Conversion (Keynote lecture)2018

    • Author(s)
      Shinji ANDO, Junji WAKITA, Ryohei ISHIGE, K. KANOSUE
    • Organizer
      2018 Int. Conf. Adv. Polym. Sci. Technol.
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 芳香族ポリマーの光・電子・熱機能化のための新しい高分子特性解析法2018

    • Author(s)
      安藤 慎治
    • Organizer
      第392回高分子分析研究懇談会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] エネルギー移動に基づく共重合ポリイミドの蛍光・燐光特性制御2018

    • Author(s)
      奈良 麻優子・折田 良司・鹿末 健太・石毛 亮平・安藤 慎治
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 室温燐光性ポリイミド薄膜の超高圧下における発光挙動の解析2018

    • Author(s)
      安東 優太郎・藤原 瑛右・折田 良司・石毛 亮平・安藤 慎治
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 燐光性ポリイミド薄膜および低分子イミド化合物の超高圧下における発光挙動の解析2018

    • Author(s)
      安東 優太郎・藤原 瑛右・折田 良司・石毛 亮平・安藤慎治
    • Organizer
      第67回高分子学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] フェルスター型エネルギー移動に基づく共重合ポリイミドの発光スペクトル制御2018

    • Author(s)
      奈良 麻優子,折田 良司,石毛 亮平,安藤 慎治
    • Organizer
      第26回日本ポリイミド・芳香族系高分子会議
    • Related Report
      2018 Annual Research Report
  • [Presentation] 室温燐光性イミド化合物の超高圧下における発光挙動の解析2018

    • Author(s)
      安東 優太郎・藤原 瑛右・折田 良司・石毛 亮平・安藤 慎治
    • Organizer
      第26回日本ポリイミド・芳香族系高分子会議
    • Related Report
      2018 Annual Research Report
  • [Presentation] 蛍光性末端基を有するポリイミドの圧力下における発光挙動の解析2018

    • Author(s)
      武藤 江一朗・藤原 瑛右・安東 優太郎・石毛 亮平・安藤 慎治
    • Organizer
      第26回日本ポリイミド・芳香族系高分子会議
    • Related Report
      2018 Annual Research Report
  • [Presentation] Multi-Color Fluorescent / Phospholescent Polyimides with Very Large Stokes Shifts and Their Performance for Solar Spectral Conversion2017

    • Author(s)
      Shinji ANDO, Junji WAKITA, Ryohei ISHIGE, Kenta KANOSUE
    • Organizer
      Danube Vltava Sava Polymer Meeting (Wien, Invited)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Multi-Color Fluorescent / Phospholescent Polyimides Exhibiting Very Large Stokes Shifts and Their Performance for Solar Spectral Conversion (Keynote lecture)2017

    • Author(s)
      Shinji ANDO, Junji WAKITA, Ryohei ISHIGE, K. KANOSUE
    • Organizer
      2018 Int. Conf. Adv. Polym. Sci. Technol.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] かさ高い電子供与性置換基を導入したフタルイミド化合物の蛍光特性制御2017

    • Author(s)
      折田 良司・鹿末 健太・石毛 亮平・安藤 慎治
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 重ハロゲンの立体効果による凝集状態制御を基盤とした高透明・室温燐光性ポリイミド2017

    • Author(s)
      鹿末 健太・安藤 慎治
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高い電子供与性を有する環状アミンの導入を基盤とする高蛍光性ポリイミドの光学特性制御2017

    • Author(s)
      折田 良司・鹿末 健太・石毛 亮平・安藤 慎治
    • Organizer
      第25回ポリイミド・芳香族系高分子会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] フェルスター型エネルギー移動に基づく共重合ポリイミドの蛍光・燐光特性制御2017

    • Author(s)
      奈良 麻優子・折田 良司・鹿末 健太・石毛 亮平・安藤 慎治
    • Organizer
      第25回ポリイミド・芳香族系高分子会議
    • Related Report
      2017 Annual Research Report
  • [Book] ポリイミド最近の進歩2017(分担)2017

    • Author(s)
      原田 真梨・岡田 朋大・石毛 亮平・安藤 慎治
    • Total Pages
      120
    • Publisher
      ポリイミド研究会編, 繊維工業技術振興会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 安藤慎治研究室へようこそ

    • URL

      http://www.op.titech.ac.jp/polymer/lab/sando/index.htm

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report 2017 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2022-10-20  

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