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Chain Dynamics and Photo-carrier Properties for Semiconducting Polymers at Interfaces

Research Project

Project/Area Number 17H03118
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyushu University

Principal Investigator

Kawaguchi Daisuke  九州大学, 工学研究院, 准教授 (70362267)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2019: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2018: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2017: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywords界面 / 分子鎖熱運動性 / 電荷生成 / 電荷移動 / 正孔移動度 / 表面偏析 / 有機・高分子半導体 / 有機電界効果トランジスタ / 光電荷生成 / 高分子半導体 / 分子鎖ダイナミクス / ポーラロン / 励起子 / 有機薄膜太陽電池 / エバネッセント波励起 / 過渡吸収分光測定 / 過渡光電流測定 / 高分子構造・物性 / 表面・界面物性
Outline of Final Research Achievements

Photo-carrier formation and mobility of semiconducting polymers at interfaces were examined by interface-sensitive spectroscopy. Photo-carrier formations of poly(3-hexylthiophene) at the surface and a solid interface were facilitated and suppressed, respectively, compared to the corresponding bulk. The carrier mobility in a poly(3-hexylthiophene) film was suppressed by thinning. These results can be explained in terms of the chain dynamics and the aggregation states of poly(3-hexylthiophene) at the surface and a solid interface.

Academic Significance and Societal Importance of the Research Achievements

本研究成果の学術的意義は、高分子物性の視点から高分子半導体の界面における分子鎖熱運動性とデバイスの性能因子となる光電荷生成および移動ダイナミクスを関連付けた点にある。これにより、高分子半導体の合成―構造・物性―機能の研究サイクルが加速され、新しい高分子半導体材料の開発に繋がることが期待される。また、得られた研究成果は、高分子系エネルギーデバイスの材料設計指針に繋がるものである。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (110 results)

All 2020 2019 2018 2017

All Journal Article (15 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 15 results,  Open Access: 1 results) Presentation (94 results) (of which Int'l Joint Research: 28 results,  Invited: 8 results) Book (1 results)

  • [Journal Article] The effect of interfacial dynamics on the bulk mechanical properties of rubber composites2019

    • Author(s)
      Sugimoto Shin、Inutsuka Manabu、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Polymer Journal

      Volume: 52 Issue: 2 Pages: 217-223

    • DOI

      10.1038/s41428-019-0254-8

    • NAID

      40022176489

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elucidation of a Heterogeneous Layered Structure in the Thickness Direction of Poly(vinyl alcohol) Films with Solvent Vapor-Induced Swelling2019

    • Author(s)
      Miyazaki Tsukasa、Miyata Noboru、Asada Mitsunori、Tsumura Yoshihiro、Torikai Naoya、Aoki Hiroyuki、Yamamoto Katsuhiro、Kanaya Toshiji、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Langmuir

      Volume: 35 Issue: 34 Pages: 11099-11107

    • DOI

      10.1021/acs.langmuir.9b01665

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancing the organic solar cell efficiency by combining plasmonic and Forster Resonance Energy Transfer (FRET) effects2019

    • Author(s)
      Jang Yu Jin、Kawaguchi Daisuke、Yamaguchi Shuhei、Lee Sunghee、Lim Ju Won、Kim Heejun、Tanaka Keiji、Kim Dong Ha
    • Journal Title

      Journal of Power Sources

      Volume: 438 Pages: 227031-227031

    • DOI

      10.1016/j.jpowsour.2019.227031

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Plasmon and Upconversion Mediated Broadband Spectral Response in TiO2 Inverse Opal Photocatalysts for Enhanced Photoelectrochemical Water Splitting2019

    • Author(s)
      Boppella Ramireddy、Marques Mota Filipe、Lim Ju Won、Kochuveedu Saji Thomas、Ahn Sunghyun、Lee Jiseok、Kawaguchi Daisuke、Tanaka Keiji、Kim Dong Ha
    • Journal Title

      ACS Applied Energy Materials

      Volume: 2 Issue: 5 Pages: 3780-3790

    • DOI

      10.1021/acsaem.9b00469

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Protein Resistance Driven by Polymer Nanoarchitecture2019

    • Author(s)
      Endoh Maya K.、Morimitsu Yuma、Salatto Daniel、Huang Zhixing、Sen Mani、Li Weiyi、Meng Yizhi、Thanassi David G.、Carrillo Jan-Michael Y.、Sumpter Bobby G.、Kawaguchi Daisuke、Tanaka Keiji、Koga Tadanori
    • Journal Title

      ACS Macro Letters

      Volume: 8 Issue: 9 Pages: 1153-1159

    • DOI

      10.1021/acsmacrolett.9b00518

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Surface Effect on Frictional Properties for Thin Hydrogel Films of Poly(vinyl ether)2019

    • Author(s)
      Itagaki Nozomi、Kawaguchi Daisuke、Oda Yukari、Nemoto Fumiya、Yamada Norifumi L.、Yamaguchi Tetsuo、Tanaka Keiji
    • Journal Title

      Macromolecules

      Volume: 52 Issue: 24 Pages: 9632-9638

    • DOI

      10.1021/acs.macromol.9b01786

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Aggregation States of Poly(4-methylpentene-1) at a Solid Interface2018

    • Author(s)
      Yamamoto Kentaro、Kawaguchi Daisuke、Sasahara Kazuki、Inutsuka Manabu、Yamamoto Satoru、Uchida Kiminori、Mita Kazuki、Ogawa Hiroki、Takenaka Mikihito、Tanaka Keiji
    • Journal Title

      Polymer Journal

      Volume: 51 Issue: 2 Pages: 247-255

    • DOI

      10.1038/s41428-018-0134-7

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impact of the Solid Interface on Proton Conductivity in Nafion Thin Films2018

    • Author(s)
      Ogata Yudai、Abe Tatsuki、Yonemori Shigeki、Yamada Norifumi L.、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Langmuir

      Volume: 34 Issue: 50 Pages: 15483-15489

    • DOI

      10.1021/acs.langmuir.8b03396

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fracture Mechanism Change at a Heterogeneous Polymer-Polymer Interface Reinforced with in Situ Graft Copolymers2018

    • Author(s)
      Kim Hoyeon、Kawaguchi Daisuke、Tanaka Keiji、Seo Yongsok
    • Journal Title

      Langmuir

      Volume: 34 Issue: 37 Pages: 11027-11033

    • DOI

      10.1021/acs.langmuir.8b01860

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Direct Observation of Conformational Relaxation of Polymer Chains at Surfaces2018

    • Author(s)
      Nguyen Hung K.、Inutsuka Manabu、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      ACS Macro Letters

      Volume: 7 Issue: 10 Pages: 1198-1202

    • DOI

      10.1021/acsmacrolett.8b00411

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Thermal Stability of Polystyrene by Interfacial Noncovalent Interactions2018

    • Author(s)
      Hong Yongming、Li Yawei、Wang Fengliang、Zuo Biao、Wang Xinping、Zhang Li、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Macromolecules

      Volume: 51 Issue: 15 Pages: 5620-5627

    • DOI

      10.1021/acs.macromol.8b01012

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Conformational Relaxation of Poly(styrene-co-butadiene) Chains at Substrate Interface in Spin-Coated and Solvent-Cast Films2018

    • Author(s)
      Zuo Biao、Inutsuka Manabu、Kawaguchi Daisuke、Wang Xinping、Tanaka Keiji
    • Journal Title

      Macromolecules

      Volume: 51 Issue: 6 Pages: 2180-2186

    • DOI

      10.1021/acs.macromol.7b02756

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Reorientation Kinetics of Local Conformation of Polyisoprene at Substrate Interface2017

    • Author(s)
      Sugimoto Shin、Inutsuka Manabu、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      ACS Macro Lett.

      Volume: 7 Issue: 1 Pages: 85-89

    • DOI

      10.1021/acsmacrolett.7b00927

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Characterization and Platelet Adhesion on Thin Hydrogel Films of Poly(vinyl ether)2017

    • Author(s)
      Itagaki Nozomi、Oda Yukari、Hirata Toyoaki、Nguyen Hung Kim、Kawaguchi Daisuke、Matsuno Hisao、Tanaka Keiji
    • Journal Title

      Langmuir

      Volume: 33 Issue: 50 Pages: 14332-14339

    • DOI

      10.1021/acs.langmuir.7b03427

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rotational Dynamics of a Probe in Rubbery Polymers Characterized by Time-Resolved Fluorescence Anisotropy Measurement2017

    • Author(s)
      Nguyen Hung K.、Konomi Asuka、Sugimoto Shin、Inutsuka Manabu、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Macromol. Chem. Phys.

      Volume: 219 Issue: 3 Pages: 1700329-1700329

    • DOI

      10.1002/macp.201700329

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] ナフィオン薄膜界面の凝集状態に及ぼす湿度の効果2020

    • Author(s)
      川口大輔,米盛茂樹,Keunwon Song,宮田 登,吉田鉄生,宮崎 司,青木裕之,田中敬二
    • Organizer
      2019年度量子ビームサイエンスフェスタ
    • Related Report
      2019 Annual Research Report
  • [Presentation] Impact of Solid Interface on Ion Transport in Polyelectrolyte Thin Films2019

    • Author(s)
      Daisuke Kawaguchi
    • Organizer
      Materials Research Meeting 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characterization of Tough Polymer Interfaces by Interface-Sensitive Spectroscopy2019

    • Author(s)
      Daisuke Kawaguchi, Shin Sugimoto, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      Materials Research Meeting 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aggregation States and Thermal Molecular Motion of Fluororubber Chains Adsorbed onto Model Carbon Interfaces2019

    • Author(s)
      Daiki Saito, Kazuki Sasahara, Yoshihisa Takeyama, Mitsugu Uejima, Daisuke Kawaguchi, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      Materials Research Meeting 2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 固体界面分子鎖の絶対配向評価2019

    • Author(s)
      笹原一輝, 川口大輔, 山本 智, 田中敬二
    • Organizer
      接着界面科学研究会PartⅥ第7回例会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 炭素フィラー界面におけるフッ素系ゴム分子鎖の凝集状態および熱運動性2019

    • Author(s)
      齋藤大輝, 笹原一輝, 武山慶久, 上島 貢, 山本 智, 川口大輔, 田中敬二
    • Organizer
      九州地区高分子若手研究会・冬の講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 半導体高分子ナノファイバーをフィラーとする高分子複合材料の調製と力学物性2019

    • Author(s)
      光木紘介, 川口大輔, 田中敬二
    • Organizer
      九州地区高分子若手研究会・冬の講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Aggregation states of thin polyamide films prepared by a layer-by-layer method2019

    • Author(s)
      Keunwon Song, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      2019 Pusan-Gyeongnam/Kyushu-Seibu Joint Symposium on High Polymers(19th) and Fibers(17th) (PGKS 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] パーフルオロスルホン酸薄膜のプロトン伝導特性に及ぼす湿潤環境効果2019

    • Author(s)
      川口大輔, 米盛茂樹, Keunwon Song, 山田悟史, 宮田 登, 吉田鉄生, 宮崎 司, 青木裕之, 田中敬二
    • Organizer
      第66回レオロジー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 束縛状態にある半導体高分子の熱運動と励起子ダイナミクスのカップリング2019

    • Author(s)
      川口大輔, 山口修平, 緒方雄大, 田中敬二
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] モデル炭素界面に吸着したフッ素ゴム分子鎖の凝集状態と熱運動性2019

    • Author(s)
      齋藤大輝, 笹原一輝, 武山慶久, 上島 貢, 山本 智, 川口大輔, 田中敬二
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 熱硬化性樹脂混合物における表面偏析2019

    • Author(s)
      中山峰花, 川口大輔, 岩下健一, 横澤 勉, 田中敬二
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高分子の界面形成過程における鎖吸着挙動2019

    • Author(s)
      織田ゆか里, 川口大輔, 田中敬二
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation and Mechanical Properties of All Polymer Nanocomposites2019

    • Author(s)
      Kosuke Mitsuki, Daisuke Kawaguchi, and Keiji Tanaka
    • Organizer
      Japan Taiwan Bilateral Polymer Symposium 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] オールポリマーナノコンポジットの調製と力学特性2019

    • Author(s)
      光木紘介, 川口大輔, 田中敬二
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 固体表面上へのポリメタクリル酸メチル鎖の吸着挙動2019

    • Author(s)
      山本晃平, 織田ゆか里, 川口大輔, 田中敬二
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 固体界面におけるゴム状分子鎖の熱運動特性2019

    • Author(s)
      川口大輔, 杉本 晋, Hung Kim Nguyen, 山本 智, 田中敬二
    • Organizer
      第57回日本接着学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 固体界面における分子鎖配向の絶対評価2019

    • Author(s)
      笹原一輝, 犬束 学, 山本 智, 川口大輔, 田中敬二
    • Organizer
      第57回日本接着学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 調湿環境下における高分子電解質薄膜の凝集状態とプロトン伝導特性2019

    • Author(s)
      川口大輔, 米盛茂樹, 山田悟史, 宮田 登, 宮崎 司, 田中敬二
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 位相敏感和周波発生分光測定によるポリメタクリル酸メチル鎖の固体界面局所コンフォメーション2019

    • Author(s)
      笹原一輝, 犬束 学, 川口大輔, 山本 智, 田中敬二
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 石英界面におけるアクリロニトリルブタジエンゴム鎖の熱運動特性2019

    • Author(s)
      川口大輔, 杉本 晋 , Hung Kim Nguyen, 犬束 学, 山本 智, 田中敬二
    • Organizer
      レオロジー学会第46年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] An Effect of Interfacial Aggregation States on Frictional Properties of Hydrogel Thin Films2019

    • Author(s)
      Daisuke Kawaguchi, Nozomi Itagaki, Yukari Oda, Norifumi L. Yamada, Keiji Tanaka
    • Organizer
      APS March Meeting 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子半導体の物性―機能相関と界面特性2018

    • Author(s)
      川口大輔
    • Organizer
      第91回高分子若手研究会[関西]
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子半導体薄膜の励起子ダイナミクスに寄与する分子鎖ダイナミクス2018

    • Author(s)
      川口大輔
    • Organizer
      第55回化学関連九州支部合同大会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子電解質膜の水膨潤挙動2018

    • Author(s)
      川口大輔
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] An Impact of Interfacial Relaxation on Bulk Mechanical Properties of Rubber Nanocomposites2018

    • Author(s)
      Daisuke Kawaguchi, Sin Sugimoto, Biao Zuo, Hung Kim Nguyen, Manabu Inutsuka, Xinping Wang, Keiji Tanaka
    • Organizer
      第28回 日本MRS年次大会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aggregation States of Fluororubber Adsorbed on Model Carbon Interfaces2018

    • Author(s)
      Daiki Saito, Kazuki Sasahara, Manabu Inutsuka, Yoshihisa Takeyama, Mitsugu Uejima, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第28回 日本MRS年次大会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evolution of Mesoscopic Heterogeneity in An Epoxy-Amine Polymer Network2018

    • Author(s)
      Mika Aoki, Atsuomi Shundo, Satoru Yamamoto, Riichi Kuwahara, Keiji Tanaka
    • Organizer
      第28回 日本MRS年次大会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relaxation Behavior of Nitrile-butadiene Rubber near a Solid Interface over Broad Temperature and Time Ranges2018

    • Author(s)
      Hung Kim Nguyen, Sin Sugimoto, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第28回 日本MRS年次大会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interfacial Aggregation States and Lubrication Properties of Hydrogel Thin Films2018

    • Author(s)
      Nozomi Itagaki, Yukari Oda, Norifumi L. Yamada, Tetsuo Yamaguchi, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第28回 日本MRS年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 界面選択振動分光測定および全原子分子動力学計算によるポリメタクリル酸メチルの界面局所コンフォメーション2018

    • Author(s)
      笹原一輝, 犬束 学, 川口大輔, 山本 智, 田中敬二
    • Organizer
      2018度高分子基礎物性研究会・高分子計算機科学研究会・高分子ナノテクノロジー研究会合同討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 液体界面におけるクロロスルホン化ポリエチレンの分子鎖凝集状態2018

    • Author(s)
      中山峰花, 國脇大樹, 鶴田貴志, 齋藤俊裕, 川口大輔, 田中敬二
    • Organizer
      繊維学会西部支部講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 中性子反射率法に基づくハイドロゲル薄膜の界面密度分布解析2018

    • Author(s)
      川口大輔, 板垣 望, 織田ゆか里, 山田悟史, 田中敬二
    • Organizer
      日本中性子科学会 第18回年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 機能性高分子グラフト層の設計による界面特性制御2018

    • Author(s)
      織田ゆか里,小草優希,川口大輔,山田悟史,田中敬二
    • Organizer
      接着界面科学研究会PartⅥ第3回例会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 液体界面におけるオレフィン系ポリマーアロイの分子鎖凝集状態2018

    • Author(s)
      中山峰花, 國脇大樹, 鶴田貴志, 齋藤俊裕, 川口大輔, 田中敬二
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] ハイドロゲル薄膜の界面密度分布と摩擦挙動2018

    • Author(s)
      川口大輔, 板垣 望, 織田ゆか里, 山田悟史, 田中敬二
    • Organizer
      第66回レオロジー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] モデル炭素界面におけるフッ素系ゴムの分子鎖凝集状態2018

    • Author(s)
      齋藤大輝, 笹原一輝, 武山慶久, 上島 貢, 犬束 学, 川口大輔, 藤原広匡, 西村 伸, 田中敬二
    • Organizer
      第30回ゴム技術・研究事例発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] かご型シルセスキオキサンを用いたポリメタクリル酸メチル表面の機能化2018

    • Author(s)
      川口大輔, 山本健太郎, 阿部建樹, 小簑 剛, 中 建介, 安達千波矢, 田中敬二
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] フィラー強化ゴム状複合材料における界面緩和挙動とバルク力学特性2018

    • Author(s)
      杉本 晋, 犬束 学, 川口大輔, 田中敬二
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ハイドロゲル薄膜の膨潤挙動と界面における分子鎖運動性2018

    • Author(s)
      板垣 望, 織田ゆか里, 山田悟史, 川口大輔, 田中敬二
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 液体界面におけるクロロスルホン化ポリエチレンの分子鎖凝集状態2018

    • Author(s)
      中山峰花, 國脇大樹, 鶴田貴志, 齋藤俊裕, 川口大輔, 田中敬二
    • Organizer
      第55回化学関連九州支部合同大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 界面特性制御に向けたビニルエーテル―アクリレート共重合体グラフト層の構築2018

    • Author(s)
      小草優希,織田ゆか里,川口大輔,田中敬二
    • Organizer
      日本接着学会第56回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] かご型シルセスキオキサン濃縮層を表面に有する高分子膜のゲート絶縁膜への応用2018

    • Author(s)
      阿部建樹, 山本健太郎, 小蓑 剛, 川口大輔, 中 建介, 安達千波矢, 田中敬二
    • Organizer
      平成30年度繊維学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アルコール界面におけるクロロスルホン化ポリエチレンの分子鎖凝集状態2018

    • Author(s)
      中山峰花, 鶴田貴志, 齋藤俊裕, 川口大輔, 田中敬二
    • Organizer
      日本ゴム協会2018年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] カーボンナノチューブ充填フッ素ゴムの界面状態2018

    • Author(s)
      笹原一輝, 犬束 学, 武山慶久, 上島 貢, 藤原広匡, 西村 伸, 田中敬二
    • Organizer
      日本ゴム協会2018年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Conformational Relaxation of Poly(styrene-co-butadiene) at Substrate Interface in Spin-coated and Solvent-cast Films2018

    • Author(s)
      Keiji Tanaka, Biao Zuo, Manabu Inutsuka, Daisuke Kawaguchi, Xinping Wang
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Thermal and Solvent Annealing Effects on Exciton Dynamics in Poly(3-hexylthiophene) Films2018

    • Author(s)
      Daisuke Kawaguchi, Shuhei Yamaguchi, Keiji Tanaka
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Conformational Relaxation of Polystyrene at Surface Probed by Sum-frequency Generation Spectroscopy2018

    • Author(s)
      Hung K. Nguyen, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] シリカ粒子を複合した無水マレイン酸変性ポリプロピレン鎖の凝集状態2018

    • Author(s)
      甲加晃一, 日笠茂樹, 織田ゆか里, 川口大輔, 田中敬二
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アクイヴィオン薄膜の水収着挙動2018

    • Author(s)
      米盛茂樹, 山田悟史, 川口大輔, 田中敬二
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高分子電解質薄膜の膨潤ダイナミクスに及ぼすイオン基数密度の影響2018

    • Author(s)
      川口大輔, 米盛茂樹, 山田悟史, 田中敬二
    • Organizer
      レオロジー学会第45回年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Interfacial Aggregation States and Frictional Properties of Poly(vinyl ether)Hydrogel Thin Films2018

    • Author(s)
      Nozomi Itagaki, Yukari Oda, Norifumi L. Yamada, Tetsuo Yamaguchi, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      1st Glowing Polymer Symposium in KANTO, Tokyo
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Novel Strategy to Function Polymer Surfaces Based on Non-solvent-induced Swelling2018

    • Author(s)
      Hisao Matsuno, Toyoaki Hirata, Hidenobu Taneda, Norifumi L. Yamada, Yasuhisa Minagawa, Keiji Tanaka
    • Organizer
      The 12th SPSJ International Polymer Conference (IPC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dynamics of Conformational Relaxation of Polystyrene at Surface2018

    • Author(s)
      Hung Kim Nguyen, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      The 12th SPSJ International Polymer Conference (IPC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Absolute Local Conformation of Poly(methyl methacrylate) Chains at Solid Interface Using Phase-sensitive Sum Frequency Generation Spectroscopy2018

    • Author(s)
      Kazuki Sasahara, Manabu Inutsuka, Daisuke Kawaguchi, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      2018 Taiwan-Japan Bilateral Polymer Symposium (TJBPS 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Novel Strategy to Function Polymer Surfaces Based on Gentle Swelling Using Its Non-solvent2018

    • Author(s)
      Hidenobu Taneda, Hisao Matsuno, Yasuhisa Minagawa, Keiji Tanaka
    • Organizer
      The 10th International Conference of Modification, Degradation and Stabilization of Polymers (MoDeSt2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aggregation States of Chlorosulfonated Polyethylene at Alcohol Interface2018

    • Author(s)
      Reika Nakayama, Hiroki Kuniwaki, Takashi Tsuruta, Toshihiro Saito, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      The 10th International Conference of Modification, Degradation and Stabilization of Polymers (MoDeSt2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relaxation Processes at Interfaces in Polymer Nanocomposites2018

    • Author(s)
      Hung Kim Nguyen, Shin Sugimoto, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      First International Conference on 4D Materials and Systems
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aggregation States of Chlorosulfonated Polyethylene Rubber in Contact with Alcohol2018

    • Author(s)
      Reika Nakayama, Hiroki Kuniwaki, Takashi Tsuruta, Toshihiro Saito, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      Japan-Korea Joint Symposium on Polymer Science 2018 (JKJS 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface and Interfacial Effects on Photo-carrier Generation in Poly(3-hexylthiophene) Thin Films2018

    • Author(s)
      Daisuke Kawaguchi, Shuhei Yamaguchi, Keiji Tanaka
    • Organizer
      The 13th International Symposium on Polymer Physics (PP'2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local Conformation and Dynamics of Polyisoprene at Solid Interface2018

    • Author(s)
      Shin Sugimoto, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      The 7th Pacific Rim Conference on Rheology (PRCR 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aggregation states of thin polyelectrolyte films by neutron reflectivity2018

    • Author(s)
      Daisuke Kawaguchi, Norifumi L. Yamada, Keiji Tanaka
    • Organizer
      The 8th Taiwan-Japan Joint Meeting on Neutron and X-ray Scattering
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Surface and Interfacial Effects on Photo-Carrier Formation in Poly(3-hexylthiophene) Films2018

    • Author(s)
      Daisuke Kawaguchi, Shuhei Yamaguchi, Yudai Ogata, Keiji Tanaka
    • Organizer
      APS March Meeting 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Frozen Local Conformation of Interfacial Polyisoprene Chains at Room Temperature2018

    • Author(s)
      Keiji Tanaka, Shin Sugimoto, Manabu Inutsuka, Daisuke Kawaguchi
    • Organizer
      APS March Meeting 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体界面におけるポリメタクリル酸メチルの局所コンフォメーション2018

    • Author(s)
      笹原一輝,犬束 学,川口大輔,山本 智,田中敬二
    • Organizer
      2017年度 高分子基礎物性研究会・高分子計算機科学研究会 合同討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 中性子反射率法による高分子/水界面の凝集構造2017

    • Author(s)
      川口大輔
    • Organizer
      分子研研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 調湿環境下のポリマーサイエンスで期待されること2017

    • Author(s)
      川口大輔
    • Organizer
      調湿環境下のポリマーサイエンスに関する研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Exciton Dynamics of Poly(3-hexylthiophene) in Ultrathin Films2017

    • Author(s)
      Daisuke Kawaguchi, Shuhei Yamaguchi, Yudai Ogata, Keiji Tanaka
    • Organizer
      The 15th International Conference on Advanced Materials (IUMRS-ICAM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 固体界面における高分子電解質の凝集状態とプロトン輸送特性2017

    • Author(s)
      川口大輔, 緒方雄大, 上村祥司, 山田悟史, 田中敬二
    • Organizer
      レオロジー学会第44年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Optical Properties of Surface-grafted Poly(3-hexylthiophene) by Oxidative Coupling Polymerization2017

    • Author(s)
      Yudai Ogata, Daisuke Kawaguchi, Jan Genzer, Keiji Tanaka
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリ(3-アルキルチオフェン)の光電荷生成に及ぼす側鎖基の偶奇効果2017

    • Author(s)
      山口修平, 時田 遊, 川口大輔, 横澤勉, 田中敬二
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリビニルエーテルハイドロゲル膜の膨潤挙動と摩擦特性2017

    • Author(s)
      板垣 望, 織田ゆか里, Nguyen Kim Hung, 川口大輔, 田中敬二
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Depth-resolved Thermal Relaxation of Polystyrene near Substrate Interface2017

    • Author(s)
      Hung Kim Nguyen, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 製膜過程で誘起されるポリスチレン薄膜の応力と緩和挙動2017

    • Author(s)
      許斐明日香, 種子田英伸, 川口大輔, 鷲見聡一, 後関頼太, 長村利彦, 大塚英幸, ○田中敬二
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリ(3―ヘキシルチオフェン)膜中の電荷移動に及ぼす薄膜化の効果2017

    • Author(s)
      阿部建樹, 川口大輔, 田中敬二
    • Organizer
      平成29年度繊維学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリ(3―アルキルチオフェン)薄膜の光電荷生成に及ぼす側鎖アルキル基の偶奇効果2017

    • Author(s)
      川口大輔, 山口修平, 緒方雄大, 時田 遊, 横澤 勉, 田中敬二
    • Organizer
      平成29年度繊維学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリ(3-ヘキシルチオフェン)薄膜中の電荷輸送特性2017

    • Author(s)
      阿部建樹, 川口大輔, 田中敬二
    • Organizer
      第54回化学関連支部合同九州大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Friction and Lubrication of Poly(vinyl ether) Hydrogel Thin Films2017

    • Author(s)
      Nozomi Itagaki, Yukari Oda, Hung Kim Nguyen, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      The 15th International Conference on Advanced Materials (IUMRS-ICAM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thinning Effect on Carrier Transport in Poly(3-hexylthiophene) Films2017

    • Author(s)
      Tatsuki Abe, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      The 15th International Conference on Advanced Materials (IUMRS-ICAM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Frictional Properties of Poly(vinyl ethers-co-acrylates)-Grafted Interfaces2017

    • Author(s)
      Yuki Ogusa, Yukari Oda, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      Japan-Taiwan Bilateral Polymer Symposium 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ビニルエーテル―アクリレート共重合体グラフト界面の摩擦特性2017

    • Author(s)
      小草優希, 織田ゆか里, 川口大輔, 田中敬二
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリ(3-ヘキシルチオフェン)中の電荷移動特性における表面・界面効果2017

    • Author(s)
      川口大輔, 阿部建樹, 田中敬二
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ハイドロゲル薄膜の界面デザインと摩擦特性2017

    • Author(s)
      板垣 望, 織田ゆか里, Nguyen Kim Hung, 川口大輔, 田中敬二
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 固体界面に形成されるポリジメチルシロキサン吸着層の凝集状態2017

    • Author(s)
      角田純一, 八百板 隆俊, 松山祥孝, 山本 清, 犬束 学, 川口大輔, 田中敬二
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリ(3-アルキルチオフェン)の光電荷生成挙動に及ぼす側鎖の偶奇効果2017

    • Author(s)
      山口修平, 時田 遊, 川口大輔, 横澤 勉, 田中敬二
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 奇数炭素鎖を有するポリ(3-アルキルチオフェン)の分子運動特性と励起子ダイナミクス2017

    • Author(s)
      川口大輔, 山口修平, 時田 遊, 横澤 勉, 田中敬二
    • Organizer
      第65回レオロジー討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Fluorescence Anisotropy and Dielectric Relaxation Studies on Segmental Dynamics at Silica/polymer Interfaces2017

    • Author(s)
      Hung K. Nguyen, Asuka Konomi, Shin Sugimoto, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      平成29年度繊維学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Relaxation of Local Orientation of Polymers at Solid Interfaces2017

    • Author(s)
      Shin Sugimoto, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      平成29年度繊維学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ポリ(3-ヘキシルチオフェン)の電荷生成に及ぼす薄膜化の効果と支配因子2017

    • Author(s)
      山口修平, 川口大輔, 田中敬二
    • Organizer
      平成29年度繊維学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 単分散ポリ(3-ヘキシルチオフェン)における結晶構造の乱れと光電荷生成2017

    • Author(s)
      川口大輔, 日笠山綾乃, 山口修平, 緒方雄大, 松下裕秀, 田中敬二
    • Organizer
      平成29年度繊維学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 固体界面におけるポリイソプレンの凝集状態とダイナミクス2017

    • Author(s)
      杉本 晋, 犬束 学, 川口大輔, 田中敬二
    • Organizer
      第28回エラストマー討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ハイドロゲル薄膜の界面凝集状態と摩擦特性2017

    • Author(s)
      川口大輔, 板垣 望, 織田ゆか里, Hung Kim Nguyen, 松野寿生, 山田悟史, 田中敬二
    • Organizer
      日本中性子科学会第17回年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photo-Carrier Transport Property in Poly(3-hexylthiophene) Thin Films2017

    • Author(s)
      Tatsuki Abe, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      15th Pacific Polymer Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Thinning Effect on Exciton Dynamics of Poly(3-hexylthiophene) in Films2017

    • Author(s)
      Daisuke Kawaguchi, Shuhei Yamaguchi, Keiji Tanaka
    • Organizer
      2017 Kyushu-Seibu/Pusan-Gyeongnam Joint Symposium on High Polymers(18th) and Fibers(16th)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] 基礎高分子科学 第2版 (第2版 11.5節)2020

    • Author(s)
      高分子学会
    • Total Pages
      496
    • Publisher
      東京化学同人
    • ISBN
      9784807909629
    • Related Report
      2019 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

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