• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of novel spin-probe techniques for organic devices by ESR-induced currents

Research Project

Project/Area Number 17H03135
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Device related chemistry
Research InstitutionOsaka City University

Principal Investigator

Kanemoto Katsuichi  大阪市立大学, 大学院理学研究科, 准教授 (40336756)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2020: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2019: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2018: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
KeywordsEDMR / ODMR / 有機デバイス / ESR / スピン流 / 逆スピンホール効果 / 電子スピン共鳴 / スピントロニクス / 電流検出ESR / 電子正孔対 / 酸素 / 誘起電流 / 有機EL / 有機LED
Outline of Final Research Achievements

In this study, we developed techniques to utilize the current change that occurs when the electron spin is reversed in organic semiconductor devices. We found that the current change in OLEDs is caused by the spin reversal of electron-hole pairs. The electron-hole pairs were found to decrease with increasing voltage, and the EL process was classified into three regions depending on the voltage: the pair accumulation region, the pair dissociation/recombination region, and the non-pair formation region. It was also found that the nature of the electron-hole pairs determines the magnetic field responsivity of the OLEDs. We also investigated the electromotive force generated by ferromagnetic resonance in metal bilayer thin films, and clarified the relationship between the excitation power and the electromotive force due to the resonance.

Academic Significance and Societal Importance of the Research Achievements

有機物質を代表とする半導体や導体には電子スピンをもつキャリヤやその複合体が存在しているが、そのスピンを磁気共鳴操作を用いて反転した際に素子にどのような影響が生じるか調べることは、新しいデバイスへの応用やデバイス内の物性を調べる手段を模索する意味で重要である。この研究ではその技術開拓を行うことを主眼とし、研究を行った結果、電子スピンの反転による電流変化を与える電子状態の起源を明らかにでき、さらには新たなスピン物性の開拓及び応用展開を行える手掛かりを得ることができた.

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (18 results)

All 2021 2020 2019 2018 2017

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (12 results) (of which Int'l Joint Research: 3 results,  Invited: 4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Quantifying Power Flow Processes Mediated by Spin Currents2021

    • Author(s)
      Kenta Nakahashi, Kohei Takaishi, Takayuki Suzuki, Katsuichi Kanemoto
    • Journal Title

      ACS Applied Electronic Materials

      Volume: 3 Issue: 4 Pages: 1663-1670

    • DOI

      10.1021/acsaelm.0c01138

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrically-detected and optically-detected magnetic resonance for organic semiconductor devices2020

    • Author(s)
      鐘本 勝一, 鈴木 貴之
    • Journal Title

      Oyo Buturi

      Volume: 89 Issue: 1 Pages: 25-29

    • DOI

      10.11470/oubutsu.89.1_25

    • NAID

      130007783775

    • ISSN
      0369-8009, 2188-2290
    • Year and Date
      2020-01-10
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron-Hole Pairs Generated in the Crystalline Phase of Polymer Diodes Studied by Electrically Detected Magnetic Resonance Techniques2019

    • Author(s)
      Kousuke Iwamoto, Yuto Hayakawa, Shuto Hatanaka, Takayuki Suzuki, and Katsuichi Kanemoto
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 123 Issue: 43 Pages: 26116-26123

    • DOI

      10.1021/acs.jpcc.9b07796

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlation between bias-dependent ESR signals and magnetic field effects in organic light emitting diodes2019

    • Author(s)
      Katsuichi Kanemoto, Shuto Hatanaka, Takayuki Suzuki
    • Journal Title

      Journal of Applied Physics

      Volume: 125 Issue: 12 Pages: 125501

    • DOI

      10.1063/1.5084216

    • NAID

      120006820376

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019948

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exploring the behavior of electron-hole pairs in working organic light emitting diodes2018

    • Author(s)
      Shuto Hatanaka, Keigo Kimura, Takayuki Suzuki, Katsuichi Kanemoto
    • Journal Title

      Physical Review Materials

      Volume: 2 Issue: 11 Pages: 115201

    • DOI

      10.1103/physrevmaterials.2.115201

    • NAID

      120006539745

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2020423

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] 強磁性金属/有機導体界面におけるスピン伝達2020

    • Author(s)
      高石晃平, 鐘本勝一, 鈴木貴之
    • Organizer
      電子スピンサイエンス学会2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 高強度パルスμ波励起による逆スピンホール効果の特性2020

    • Author(s)
      鐘本勝一,中橋健太,鈴木貴之
    • Organizer
      日本物理学会 第75回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機半導体素子における磁場効果と磁気キャパシタンス2019

    • Author(s)
      鐘本勝一
    • Organizer
      日本磁気学会第224回研究会 磁気キャパシタンス効果の新展開
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Origin of Electrically-Detected Magnetic Resonance Signals in Organic Semiconductor Diodes2019

    • Author(s)
      Katsuichi Kanemoto, Kousuke Iwamoto, Shuto Hatanaka, Takayuki Suzuki
    • Organizer
      the 13th Japanese-Russian International Workshop on Open Shell Compounds and Molecular Spin Devices
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高強度マイクロ波パルス照射下における逆スピンホール効果2019

    • Author(s)
      中橋 健太, 鐘本 勝一, 鈴木 貴之
    • Organizer
      応用物理学会 2019年秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高強度マイクロ波パルス照射下における逆スピンホール効果2019

    • Author(s)
      鐘本勝一, 中橋健太, 鈴木貴之
    • Organizer
      電子スピンサイエンス学会年会2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機LED中の電子正孔対に対する電流検出及びEL検出磁気共鳴2019

    • Author(s)
      鐘本 勝一, 畑中 秀人, 岩本 晃典, 鈴木 貴之
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 有機半導体におけるスピン流発生時の素子電流測定2018

    • Author(s)
      中橋健太, 鐘本勝一, 鈴木貴之
    • Organizer
      電子スピンサイエンス学会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 有機ダイオードにおける電流電圧特性とEDMR強度の関係2018

    • Author(s)
      岩本晃典,鐘本勝一
    • Organizer
      電子スピンサイエンス学会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] Field-Induced Dissociation of Electron-Hole Pairs in Organic Light Emitting Diodes Monitored Directly from Bias-Dependent Magnetic Resonance Techniques2017

    • Author(s)
      Katsuichi Kanemoto, Shuto Hatanaka
    • Organizer
      5th Awaji International Workshop on “Electron Spin Science & Technology (AWEST)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 発光検出ESRから探る有機LED動作下の電子-正孔ペア2017

    • Author(s)
      畑中秀人、鐘本勝一
    • Organizer
      第56回電子スピンサイエンス学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electron-Hole Pairs in Organic Light Emitting Diodes Monitored by Bias-Dependent Magnetic Resonance Techniques.2017

    • Author(s)
      Katsuichi Kanemoto, Shuto Hatanaka
    • Organizer
      The 11th Japanese-Russian International Workshop on Open Shell Compounds and Molecular Spin Devices, Awaji International Conference Center
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Patent(Industrial Property Rights)] スペクトル測定装置、スピン流デバイス測定システム及びスピン流デバイス測定方法2020

    • Inventor(s)
      鐘本勝一、鈴木貴之
    • Industrial Property Rights Holder
      日本電子株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2020-142653
    • Filing Date
      2020
    • Related Report
      2020 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2022-01-27  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi