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New Development of Synthesis of New Compounds by Hydrothermal Reaction

Research Project

Project/Area Number 17H03388
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionUniversity of Yamanashi

Principal Investigator

Kumada Nobuhiro  山梨大学, 大学院総合研究部, 教授 (90161702)

Co-Investigator(Kenkyū-buntansha) 武井 貴弘  山梨大学, 大学院総合研究部, 教授 (50324182)
柳田 さやか  山梨大学, 大学院総合研究部, 助教 (40579794)
Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2019: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2018: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2017: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Keywords水熱反応 / 結晶構造解析 / 超伝導体 / 光触媒 / 廃棄物 / リサイクル / ビスマス酸化物 / 物質探査 / 第一原理計算 / 新規化合物 / 結晶構造 / 電子構造 / 遷移金属フッ化物 / 赤色蛍光体 / 無機化合物 / 超伝導 / 蛍光体
Outline of Final Research Achievements

"Hydrothermal Reaction" is an academic term used in geology for reactions inside the earth, and is a reaction mainly using water as a solvent under high temperature and high pressure condition. Inside the earth mineralization and crystal growth occur by hydrothermal reactions and they have been used for synthesis and crystal growth for inorganic compounds. In this study, the following results were obtained in the synthesis of inorganic compounds using hydrothermal reaction. (1) Discovery of new bismuth oxide and its characterization, (2) Synthesis of pyrochlore-type niobium and tantalum oxides and antibacterial properties of their silver ion-exchanged derivatives, (3) Discovery of new alkali metal niobium and tantalum fluorides and fluorescent properties of their Mn4+ doped derivatives

Academic Significance and Societal Importance of the Research Achievements

水熱反応を用いた無機化合物の合成に関する研究は、ナノ粒子の粒子径および形態制御が主流である。それに対して一貫して物質探査を行い、新たな超伝導ビスマス酸化物や赤色蛍光を示すMn4+を含む新たな金属フッ化物を見い出すことができた。さらに半導体製造プロセスに使われる高純度シリカ製品の端材を出発物質として層状アルカリケイ酸塩を合成することができ、さらにその銀イオン交換体が抗菌性を有することを示した。以上のように水熱反応を用いて新たな化合物を合成し、その特性評価を行うと同時に廃棄物の再利用に関する知見を得ることができた。

Report

(5 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (34 results)

All 2022 2021 2020 2019 2018 2017 Other

All Journal Article (20 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 20 results,  Open Access: 20 results) Presentation (10 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results) Book (1 results) Remarks (3 results)

  • [Journal Article] Hydrothermal synthesis and crystal structure of a new rubidium sodium niobium fluoride, RbNaNbF<sub>7</sub>2022

    • Author(s)
      KUMADA Nobuhiro、TAKEI Takahiro
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 130 Issue: 2 Pages: 232-235

    • DOI

      10.2109/jcersj2.21147

    • NAID

      130008150409

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2022-02-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrothermal synthesis and crystal structure of a novel double-perovskite-type bismuth oxide with 3:1 ordering at the B-site2022

    • Author(s)
      Hossain Khandaker Monower、Saiduzzaman Md、Kumada Nobuhiro、Takei Takahiro、Yamane Hisanori
    • Journal Title

      New Journal of Chemistry

      Volume: 46 Issue: 8 Pages: 3595-3601

    • DOI

      10.1039/d1nj05648d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photocatalytic activity of RBi<sub>2</sub>O<sub>4</sub>NO<sub>3</sub> (R: Tb, Dy, Er, Gd, and Ho) for phenol degradation under visible light irradiation2021

    • Author(s)
      SAIDUZZAMAN Md、TSUCHIOKA Nami、NORITAKE Fumiya、KUMADA Nobuhiro、TAKEI Takahiro
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 129 Issue: 3 Pages: 181-186

    • DOI

      10.2109/jcersj2.20210

    • NAID

      130007993749

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2021-03-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Controllable antimicrobial properties of silver ion-exchanged niobate and tantalate compounds2021

    • Author(s)
      Isuru Udakara Withanage Withanage、Ariyapala Kuda Durayalage Sulasa Devi、Kumada Nobuhiro、Takei Takahiro、Ueda Mayu、Aizawa Mamoru
    • Journal Title

      Journal of Asian Ceramic Societies

      Volume: 10 Issue: 1 Pages: 49-57

    • DOI

      10.1080/21870764.2021.2006877

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrothermal Synthesis and Crystal Structure of a Novel Bismuth Oxide: (K0.2Sr0.8)(Na0.01Ca0.25Bi0.74)O32021

    • Author(s)
      Hossain Khandaker Monower、Saiduzzaman Md、Kumada Nobuhiro、Takei Takahiro、Yamane Hisanori、Kabir Rubel Mirza Humaun
    • Journal Title

      ACS Omega

      Volume: 6 Issue: 24 Pages: 15975-15980

    • DOI

      10.1021/acsomega.1c01694

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrothermal magic for the synthesis of new bismuth oxides2021

    • Author(s)
      Saiduzzaman Md、Takei Takahiro、Kumada Nobuhiro
    • Journal Title

      Inorganic Chemistry Frontiers

      Volume: 8 Issue: 11 Pages: 2918-2938

    • DOI

      10.1039/d1qi00337b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrical properties of pyrochlore-type silver tantalate and fluorite-type silver niobate2020

    • Author(s)
      W. I. U. WITHANAGE, Nobuhiro Kumada, Takahiro Takei, Sayaka YANAGIDA, Kiyoharu Tadanaga, Akira Miura, Nataly Carolina Rosero-Navarro and Masaki Azuma
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 128 Issue: 1 Pages: 46-50

    • DOI

      10.2109/jcersj2.19139

    • NAID

      130007779341

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2020-01-01
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Mechanical, electronic, optical, and thermodynamic properties of orthorhonmbic LiCuBiO4 crystal ; a first priciples study2019

    • Author(s)
      Md. Mijanur Rahaman, Mirza H. K. Rubel, Md. Abdur Rashid, M. Ashraful Alamd Khandaker, Monower Hossaina, Md. Imran, Hossaina Anjuman AraKhatun, Md. Mukter Hossain, A. K. M. Azharul Islam, Seiji Kojima, Nobuhiro Kumada
    • Journal Title

      J. Mater. Res. and Tech.

      Volume: 6 Issue: 5 Pages: 3783-3794

    • DOI

      10.1016/j.jmrt.2019.06.039

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrothermal Synthesis of KTi2(PO4)3, a-Zr(HPO4)2H2O and g-TiPO4(H2PO4)2H2O from a lepidocrocite-type titanate2019

    • Author(s)
      Nobuhiro Kumada, Sayaka Yanagida, Takahiro Takei, Akira Miura, Nobuki Itoi and Toshiki Goto
    • Journal Title

      J. Asian Ceram. Soc.

      Volume: 7 Issue: 3 Pages: 361-367

    • DOI

      10.1080/21870764.2019.1649041

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrothermal Synthesis and Crystal Structure of a BKBO (Ba0.54K0.46)4Bi4O12 Double Perovskite Superconductor with Onset of the Transition Tc ~ 30 K2019

    • Author(s)
      Md Saiduzzaman, Yoshida Hikaru, Takahiro Takei, Sayaka Yanagida, Nobuhiro Kumada, Masanori Nagao, Hisanori Yamane, Masaki Azuma, Mirza H. K. Rubel, Chikako Moriyoshi, and Yoshihiro Kuroiwa
    • Journal Title

      Inorg. Chem.

      Volume: 58 Issue: 18 Pages: 11997-12001

    • DOI

      10.1021/acs.inorgchem.9b01768

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Frustrated magnetic interactions in an S=3/2 bilayer honeycomb lattice compound Bi3Mn4O12(NO3)2019

    • Author(s)
      M. Matsuda, S. E. Dissanayake, D. L. Abernathy, Y. Qiu, J. R. D. Copley, N. Kumada, and M. Azuma
    • Journal Title

      Phys. Rev. B

      Volume: 100 Issue: 13 Pages: 134430-134430

    • DOI

      10.1103/physrevb.100.134430

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrothermal Synthesis and Crystal Structure of A Fluorite-type Pb0.35Bi0.65O1.59 Compound with Photocatalytic Activity2019

    • Author(s)
      Md. Saiduzzaman, Sayaka Yanagida, Takahiro Takei, Nobuhiro Kumada
    • Journal Title

      Mater. Lett.

      Volume: 257 Pages: 126688-126688

    • DOI

      10.1016/j.matlet.2019.126688

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrothermal Synthesis of Pyrochlore-Type Pentavalent Bismuthates Ca2Bi2O7 and Sr2Bi2O72019

    • Author(s)
      Saiduzzaman Md、Takei Takahiro、Yanagida Sayaka、Kumada Nobuhiro、Das Hena、Kyokane Hirokazu、Wakazaki Shogo、Azuma Masaki、Moriyoshi Chikako、Kuroiwa Yoshihiro
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 3 Pages: 1759-1763

    • DOI

      10.1021/acs.inorgchem.8b03596

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] First principles study: Structural, mechanical, electronic and thermodynamic properties of simple?cubic?perovskite (Ba0.62K0.38)(Bi0.92Mg0.08)O32019

    • Author(s)
      Rubel Mirza H.K.、Mozahar Ali M.、Ali M.S.、Parvin R.、Rahaman M.M.、Hossain K.M.、Hossain M.I.、Islam A.K.M.A.、Kumada N.
    • Journal Title

      Solid State Communications

      Volume: 288 Pages: 22-27

    • DOI

      10.1016/j.ssc.2018.11.008

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrothermal synthesis and crystal structure of new red phosphors, KNaMF7:Mn4+ (M: Nb, Ta)2019

    • Author(s)
      Kumada N.、Yanagida S.、Takei T.、Hong B.
    • Journal Title

      Materials Research Bulletin

      Volume: 115 Pages: 170-175

    • DOI

      10.1016/j.materresbull.2019.02.023

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrothermal reaction of NaBiO<sub>3</sub>·<i>n</i>H<sub>2</sub>O with transition-metal (Co, Ni, Cu) salts2018

    • Author(s)
      YAMAMOTO Yo、WITHANAGE Withanage Isuru Udakara、TAKEI Takahiro、YANAGIDA Sayaka、KUMADA Nobuhiro、YAMANE Hisanori
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 126 Issue: 12 Pages: 1005-1012

    • DOI

      10.2109/jcersj2.18052

    • NAID

      130007539618

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2018-12-01
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrothermal doping of Ag into three types of potassium niobates2018

    • Author(s)
      WITHANAGE W. I. U.、YANAGIDA Sayaka、TAKEI Takahiro、KUMADA Nobuhiro
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 126 Issue: 10 Pages: 784-788

    • DOI

      10.2109/jcersj2.18065

    • NAID

      130007494574

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2018-10-01
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal Structure, thermal behavior and photocatalytic activity of NaBiO3nH2O2018

    • Author(s)
      Md. Saiduzzaman, Sayaka Yanagida, Takahiro Takei, Nobuhiro Kumada, Kazuya Ogawa, Chikako Moriyoshi, Yoshihiro Kuroiwa, Shogo Kawaguchi
    • Journal Title

      INORGANIC CHEMISTRY

      Volume: 57 Issue: 15 Pages: 8903-8908

    • DOI

      10.1021/acs.inorgchem.8b00799

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrothermal Synthesis, Crystal Structure, and Visible-Region Photocatalytic Activity of BaBi2O62017

    • Author(s)
      Md. Saiduzzaman, Sayaka Yanagida, Takahiro Takei, Chikako Moriyoshi, Yoshihiro Kuroiwa, and Nobuhiro Kumada
    • Journal Title

      Chem. Select

      Volume: 2 Issue: 17 Pages: 4843-4846

    • DOI

      10.1002/slct.201700973

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and crystal structure of pyrochlore-type silver niobate and tantalate2017

    • Author(s)
      Isuru Withanage, Nobuhiro Kumada, Sayaka Yanagida, Takahiro Takei, Chikako Moriyoshi, Yoshihiro Kuroiwa
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 10 Pages: 776-778

    • DOI

      10.2109/jcersj2.17063

    • NAID

      130006110739

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 水熱合成による新しいビスマス酸化物Na3Bi3O8の合成と特性評価2020

    • Author(s)
      阿久津修平・M. Saiduzzaman・武井貴弘・柳田さやか・熊田伸弘・山根久典・草野圭弘
    • Organizer
      第57回セラミックス基礎科学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 廃ガラスを用いた Ba2TiSi2O8の水熱合成2020

    • Author(s)
      米山 悠聖・武井 貴弘・柳田 さやか・中野目 滉介・熊田 伸弘
    • Organizer
      日本セラミックス協会2020年年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Antibacterial and photocatalytic properties of silver niobate and silver tantalate2019

    • Author(s)
      Isuru Withanage, Nobuhiro Kumada, Sayaka Yanagida, Takahiro Takei, Mayu Ueda, Mamoru Aizawa
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocaralytic activity of transition metal doped potassium niobate2018

    • Author(s)
      Isuru Withanage, Sayaka Yanagida, Takahiro Takei, Nobuhiro Kumada
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水熱合成による新しいビスマス酸ナトリウムの合成と特性評価2018

    • Author(s)
      阿久津 修平,熊田 伸弘,柳田 さやか,武井 貴弘,山根 久典,草野 圭弘
    • Organizer
      日本セラミックス協会2018年秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Preparation and Photocatalytic Properties of Potassium Niobates2018

    • Author(s)
      Isuru Withanage, Sayaka Yanagida, Takahiro Takei, Nobuhiro Kumada
    • Organizer
      ICIE2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrothermal Synthesis of New Bismuthates2017

    • Author(s)
      N. Kumada
    • Organizer
      STAC-10
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydrothermal Synthesis and Visible Regoin Photocatalytic Activity of New Pentavalent Bismuthates2017

    • Author(s)
      Md Saiduzzaman, N. Kumada, T. Takei, S. Yanagida
    • Organizer
      STAC-10
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and crystal structure of pyrochlore-type silver niobate and tantalate2017

    • Author(s)
      I. WITHANAGE, N. KUMADA, T. TAKEI, S. YANAGIDA
    • Organizer
      STAC-10
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation and photocatalytic properties of pyrochlore-type AgMO3(M = Nb,Ta)2017

    • Author(s)
      Isuru Withanage, Nobuhiro Kumada, Sayaka Yanagida, Takahiro Takei
    • Organizer
      ECers2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] Handbook of Solid State Chemistry Volume 22017

    • Author(s)
      Nobuhiro Kumada
    • Total Pages
      13
    • Publisher
      Wiley-VCH
    • Related Report
      2017 Annual Research Report
  • [Remarks] ソフト化学的手法を用いた結晶構造制御に関する研究

    • URL

      https://www.inorg.yamanashi.ac.jp/research/17/

    • Related Report
      2020 Annual Research Report
  • [Remarks] ソフト化学的手法を用いた結晶構造制御に関する研究

    • URL

      https://www.inorg.yamanashi.ac.jp/research/17

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
  • [Remarks] ソフト化学的手法を用いた結晶構造制御に関する研究

    • URL

      http://www.inorg.yamanashi.ac.jp/research/17

    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2023-01-30  

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