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Synthesis of supported catalysts using zeolitic nanosheets

Research Project

Project/Area Number 17H03449
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

Ogino Isao  北海道大学, 工学研究院, 准教授 (60625581)

Co-Investigator(Kenkyū-buntansha) 岩村 振一郎  北海道大学, 工学研究院, 助教 (10706873)
向井 紳  北海道大学, 工学研究院, 教授 (70243045)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2019: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2017: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Keywords化学工学 / 反応・分離 / 触媒・化学プロセス / ナノ材料 / 反応・分離工学
Outline of Final Research Achievements

Atomically-dispersed metals on oxide supports have attracted significant interest as catalytic materials for energy and environmental applications. In this work, we aimed to develop a synthetic method to confine small metal species within zeolitic materials using layered zeolitic precursors. We studied the synthesis conditions of layered zeolitic precursors, extraction methods of organic structure-directing agents from interlayer spaces of layered precursors, the type and composition of amino alcohols and metal complexes, and thermal activation conditions of synthesized samples. We found that supported catalysts with highly dispersed metal species can be synthesized through a proper choice of amino alcohol and metal complex and adjustment of thermal activation condition. We found further that the synthesized catalyst exhibits significantly higher activity than other catalysts in a test reaction.

Academic Significance and Societal Importance of the Research Achievements

貴金属を担持した触媒は,環境・エネルギー分野の化学反応に多く利用されている。希少資源である貴金属の使用量を最小にし,かつ高性能な触媒を開発するため,貴金属が原子レベルで分散した触媒に関する研究が盛んに行われている。本研究では,層状構造を有するゼオライト前駆体の構造的な特徴を活かし,貴金属が高分散に担持した触媒を合成する手法創出を目指した。検討の結果,合成時に用いる添加剤の種類と量,そして試料の活性化処理条件を調節することで目的とする触媒が合成可能であることがわかった。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (41 results)

All 2020 2019 2018 2017

All Journal Article (17 results) (of which Peer Reviewed: 16 results,  Open Access: 4 results) Presentation (22 results) (of which Int'l Joint Research: 13 results,  Invited: 1 results) Book (2 results)

  • [Journal Article] Intercalation chemistry and thermal characteristics of layered double hydroxides possessing organic phosphonates and sulfonates2020

    • Author(s)
      Isao Ogino, Yuki Hirayama, Shin R. Mukai
    • Journal Title

      New Journal of Chemistry

      Volume: 44 Issue: 24 Pages: 10002-10010

    • DOI

      10.1039/c9nj06441a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Genesis of micropores by thermal activation of Mg-Al layered double hydroxides possessing interlayer organic sulfonates under oxygen-free environments2020

    • Author(s)
      Isao Ogino, Rei Tanaka, Shin R. Mukai
    • Journal Title

      Catalysis Today

      Volume: - Pages: 11-17

    • DOI

      10.1016/j.cattod.2019.12.015

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Continuous-flow separation of cesium ion by ammonium molybdophosphate immobilized in a silica microhoneycomb (AMP-SMH)2019

    • Author(s)
      Seiichiro Yoshida, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Journal Title

      Adsorption

      Volume: 25 Issue: 6 Pages: 1089-1098

    • DOI

      10.1007/s10450-019-00060-2

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Understanding atomically dispersed supported metal catalysts: structure and performance of active sites2019

    • Author(s)
      Isao Ogino
    • Journal Title

      Catalysis: Volume 31

      Volume: 31 Pages: 166-197

    • DOI

      10.1039/9781788016971-00166

    • ISBN
      9781788014540
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Activity for Oxygen Reduction Reaction of Ni-Mn-Fe Layered Double Hydroxide-Carbon Gel Composite2019

    • Author(s)
      Yu Iwai, Takuya Ikka, Akira Miura, N.C. Rosero-Navarro, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai, Kiyoharu Tadanaga
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 7 Pages: 696-699

    • DOI

      10.1246/cl.190036

    • NAID

      130007674967

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Carbon Gel Monoliths with Introduced Straight Microchannels for Phenol Adsorption2019

    • Author(s)
      Kazuya Takahashi, Seiichiro Yoshida, Kasama Urkasame, Shinichiroh Iwamura, Isao Ogino and Shin R Mukai
    • Journal Title

      Adsorption

      Volume: 25 Issue: 6 Pages: 1241-1249

    • DOI

      10.1007/s10450-018-00007-z

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Mg-Al Mixed Oxides with Markedly High Surface Areas from Layered Double Hydroxides with Organic Sulfonates2018

    • Author(s)
      Tanaka, R.; Ogino, I.; Mukai, S. R.
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 12 Pages: 16916-16923

    • DOI

      10.1021/acsomega.8b02557

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The impact of thermal activation conditions on physicochemical properties of nanosheet-derived Mg-Al mixed oxides2018

    • Author(s)
      Isao Ogino, Rei Tanaka, Shuichiroh Kudo, Shin R. Mukai
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 263 Pages: 181-189

    • DOI

      10.1016/j.micromeso.2017.12.014

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cost-effective synthesis of activated carbons with high surface areas for electrodes of nonaqueous electric double layer capacitors2018

    • Author(s)
      Takeshi Mori, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Journal Title

      Separation and Purification Technology

      Volume: 印刷中 Pages: 174-180

    • DOI

      10.1016/j.seppur.2018.04.022

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Critical Role of Bulk Density of Graphene Oxide in Tuning Its Defect Concentration through Microwave-driven Annealing2018

    • Author(s)
      Isao Ogino, Go Fukazawa, Shunsuke Kamatari, Shinichiroh Iwamura and Shin R Mukai
    • Journal Title

      Journal of Energy Chemistry

      Volume: 27 Issue: 5 Pages: 1468-1474

    • DOI

      10.1016/j.jechem.2017.09.010

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of TiO2-SiO2 Photocatalysts Having a Microhoneycomb Structure by the Ice Templating Method2018

    • Author(s)
      Urkasame, K.; Yoshida, S.; Takanohashi, T.; Iwamura, S.; Ogino, I.; Mukai S. R.
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 10 Pages: 14274-14279

    • DOI

      10.1021/acsomega.8b01880

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Esterification of Levulinic Acid with Ethanol Catalyzed by Sulfonated Carbon Catalysts: Promotional Effects of Additional Functional Groups2018

    • Author(s)
      Isao Ogino, Yukei Suzuki Shin R Mukai
    • Journal Title

      Catalysis Today

      Volume: 314 Pages: 62-69

    • DOI

      10.1016/j.cattod.2017.10.001

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbon Paper with a High Surface Area Prepared from Carbon Nanofibers Obtained through the Liquid Pulse Injection Technique2018

    • Author(s)
      Sakai Kazuki、Iwamura Shinichiroh、Sumida Ryo、Ogino Isao、Mukai Shin R.
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 1 Pages: 691-697

    • DOI

      10.1021/acsomega.7b01822

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] X-ray Absorption Spectroscopy for Single-Atom Catalysts: Critical Importance and Persistent Challenges2017

    • Author(s)
      Isao Ogino
    • Journal Title

      Chinese Journal of Catalysis

      Volume: 38 Issue: 9 Pages: 1481-1488

    • DOI

      10.1016/s1872-2067(17)62880-8

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimization of Practical Activation Depth for Effective CO2 Activation Using PMMA-templated Carbons with a Tailorable Pore System of Meso- and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      Journal of Porous Materials

      Volume: 24 Issue: 6 Pages: 1497-1506

    • DOI

      10.1007/s10934-017-0389-y

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PMMA-Templated Carbon Gel Monoliths with Independently Tunable Micro-, Meso-, and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 50 Issue: 4 Pages: 315-323

    • DOI

      10.1252/jcej.16we313

    • NAID

      130006837170

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] CO2 Separation in a Flow System by Silica Microhoneycombs Loaded with an Ionic Liquid Prepared by the Ice-Templating Method2017

    • Author(s)
      Yoshida, Seiichiro; Takahashi, Kazuya; Kudo, Shuichiro; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 56 Issue: 10 Pages: 2834-2839

    • DOI

      10.1021/acs.iecr.6b05001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] ゼオライト層状前駆体を利用したCu担持触媒の合成2020

    • Author(s)
      樋口 友輔、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      第29回化学工学・粉体研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Overcoming Two Challenges in Utilization of Two-dimensional Materials - Irreversible Restacking & Site-specific Functionalization2019

    • Author(s)
      Isao Ogino
    • Organizer
      The 3rd International Conference on Bioresources, Energy, Environment, and Materials Technology 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Scalable Synthesis of Metal Oxide Supports with High Surface Area and Basic Site Density from Mg-Al Layered Double Hydroxides2019

    • Author(s)
      Isao Ogino, Rei Tanaka, Shin R. Mukai
    • Organizer
      26th North American Catalysis Society Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Confined-Space Synthesis of Nanocrystalline Mo-V-O Mixed Oxides Using a Mesoporous Carbon2019

    • Author(s)
      Ryo Obunai, Keisuke Tamura, Isao Ogino, Shin R. Mukai, and Wataru Ueda
    • Organizer
      26th North American Catalysis Society Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Overcoming Irreversible Restacking of Mg-Al Double Hydroxide Nanosheets through Thermal Activation in H2 or N2: Synthesis of Mixed Metal Oxides with High Surface Area and Basic Site Density2019

    • Author(s)
      Isao Ogino, Rei Tanaka, Shuichiroh Kudo, Shin R. Mukai
    • Organizer
      19th International Zeolite Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Site-specific Functionalization of Lamellar Precursors of a Zeolitic Material2019

    • Author(s)
      Isao Ogino, Kazumasa Kikuhara, Taichi Shirobe, Yusuke Higuchi, Shin R. Mukai
    • Organizer
      APCChE2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ゼオライト層状前駆体の欠陥サイトを利用した金属担持触媒の合成2019

    • Author(s)
      菊原 一将、荻野 勲、向井 紳
    • Organizer
      第35回ゼオライト研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゼオライト層状前駆体からの構造規定剤抽出と層間修飾2018

    • Author(s)
      菊原 一将,白部 大知,岩村 振一郎,荻野 勲,向井 紳
    • Organizer
      第58回オーロラセミナー
    • Related Report
      2018 Annual Research Report
  • [Presentation] Effects of Thermal Activation Conditions on Physicochemical Properties of Nanosheet-Derived Mg-Al Mixed Oxides2018

    • Author(s)
      Isao Ogino, Rei Tanaka, Shin R. Mukai
    • Organizer
      2nd Natural Gas Utilization Workshop
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Impact of Thermal Activation Conditions on Physicochemical Properties of Nanosheet-derived Mg-Al Mixed Oxides2018

    • Author(s)
      Rei Tanaka, Isao Ogino, Shuichiroh Kudo, Shin R. Mukai
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マイクロ波加熱による酸化グラファイト由来グラフェン系炭素材料の低欠陥化2018

    • Author(s)
      深澤 剛 ,皆上 昂ノ介,荻野 勲,岩村 振一郎,向井 紳
    • Organizer
      第58回オーロラセミナー
    • Related Report
      2018 Annual Research Report
  • [Presentation] Impact of Thermal Activation Conditions on Physicochemical Properties of Nanosheet-derived Mg-Al Mixed Oxides2018

    • Author(s)
      Rei Tanaka, Isao Ogino, Shuichiroh Kudo, Shin R. Mukai
    • Organizer
      International Symposium on Zeolites and Microporous Crystals 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マイクロ波加熱による酸化グラファイト由来グラフェン系炭素材料の低欠陥化2018

    • Author(s)
      深澤 剛,皆上 昂ノ介,荻野 勲,岩村 振一郎,向井 紳
    • Organizer
      化学工学会室蘭大会2018(3支部合同大会)
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノシートを利用した高表面積Mg-Al複合酸化物の合成2018

    • Author(s)
      田中怜,荻野勲,向井紳
    • Organizer
      第32回日本吸着学会研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] マイクロ波によるグラフェン系窒素ドープカーボンの高性能化を目指した検討2018

    • Author(s)
      一家 拓矢,荻野 勲,岩村 振一郎,小野博信,向井 紳
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] マイクロ波処理による炭素系触媒の酸素還元反応活性の向上2018

    • Author(s)
      荻野 勲,一家 拓矢,岩村 振一郎,小野 博信,向井 紳
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ゼオライト層状前駆体からの構造規定剤の抽出とその利用2018

    • Author(s)
      佐藤 裕貴、白部 大知、荻野 勲、向井 紳
    • Organizer
      第 27回化学工学・粉体研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Locations of Defective SiO- Sites in Lamellar Precursors of Pure-Silica MWW-Type Molecular Sieves2017

    • Author(s)
      Isao Ogino, Taichi Shirobe, Shin R. Mukai
    • Organizer
      25th North American Meeting of the Catalysis Society
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of an Efficient method to Support Metal Nano-Particles Using Layered MWW Precursors2017

    • Author(s)
      Hiroki Satoh, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Organizer
      Hokkaido University- Chulalongkorn University Learning Satellite Program
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CO2 Adsorption Characteristics of Nano-fiberized Mg/Al Mixed Metal Oxides for Sorption-Enhanced Water Gas Shift Reaction2017

    • Author(s)
      Rei Tanaka, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Organizer
      Hokkaido University- Chulalongkorn University Learning Satellite Program
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Esterification of Levulinic Acid with Ethanol Catalyzed by Sulfonated Carbon Catalysts: Promotional Effects of Additional Functional Groups2017

    • Author(s)
      Yukei Suzuki, Isao Ogino, Shin R. Mukai
    • Organizer
      APCChE2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Liquid-phase esterification of levulinic acid with ethanol catalyzed by sulfonated carbon catalysts: effects of additional surface functional groups2017

    • Author(s)
      Yukei Suzuki, Isao Ogino, Shin R. Mukai
    • Organizer
      8th International Symposium on Acid-Base Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] Understanding Atomically Dispersed Supported Metal Catalysts. In Catalysis: Volume 31. Spivey, J. J., Yi-Han Fan, Y.-H., Shekhawat, D. Eds,2019

    • Author(s)
      Isao Ogino
    • Total Pages
      31
    • Publisher
      The Royal Society of Chemistry
    • ISBN
      9781788014540
    • Related Report
      2018 Annual Research Report
  • [Book] Supported Catalysts in "Handbook of Solid State Chemistry, 6 Volume Set"2017

    • Author(s)
      Isao Ogino, Pedro Serna, Bruce C. Gates
    • Total Pages
      26
    • Publisher
      Wiley-VCH
    • ISBN
      9783527325870
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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