• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

An approach for real time analysis of multi-component volatiles from solid fuels towards ultimately efficient biomass gasification

Research Project

Project/Area Number 17H03454
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionNagoya University

Principal Investigator

Norinaga Koyo  名古屋大学, 工学研究科, 教授 (00312679)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥14,430,000 (Direct Cost: ¥11,100,000、Indirect Cost: ¥3,330,000)
Fiscal Year 2019: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2018: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2017: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Keywords炭素資源転換技術 / 反応速度モデル / 反応機構 / 反応シミュレーション / バイオマス / 炭素資源 / ガス化 / 多環芳香族 / 改質反応 / 反応速度
Outline of Final Research Achievements

To improve the efficiency of biomass gasification, a series of research on reaction prediction methods and measurement methods of multi-component gas mixture generated upon biomass gasification were performed. The main achievements can be sumerized as: (1) The first comprehensive chemical kinetic model of lignin, which uses only the elemental composition as input information, is used to quantitatively predict the thermal decomposition of lignin including both primary and secondary pyrolysis. (2) Ion attachment mass spectrometry using Li+ ions was applied for the first time to real-time quantitative analysis of volatile components generated by solid fuel pyrolysis, and succeeded in fragment-free measurement of volatile which exhibit multi-component gas mixtures.

Academic Significance and Societal Importance of the Research Achievements

本研究は、まず初期熱分解反応モデルの妥当性をモデルによる予測と熱分解実験結果との比較によって検証した。次いで、計算化学に基づきモノリグノール二次気相分解の詳細化学反応モデルを構築し、これを初期熱分解の反応モデルに加えることによって生成物組成の予測精度が向上することを明らかにした。加えて、Li+付着イオン化質量分析法を揮発成分のリアルタイム定量分析に初めて適用し、多成分混合物である揮発成分のフラグメントフリー計測に成功した。本研究で得られた新知見や提案された計測手法は、バイオマス熱化学転換の基盤技術として有用であり、炭素資源利用に関する化学反応工学の発展に寄与する。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (21 results)

All 2019 2018 2017 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 1 results) Presentation (11 results) (of which Int'l Joint Research: 3 results,  Invited: 7 results) Remarks (3 results)

  • [Journal Article] Quantitative Analyses of Chemical Structural Change and Gas Generation Profile of Coal upon Heating toward Gaining New Insights for Coal Pyrolysis Chemistry2019

    • Author(s)
      Fukuoka Tetsuya、Takeda Norihiro、Zhang Lu、Machida Hiroshi、Zhang Wei、Watanabe Masahiko、Nishibata Yuko、Hayashi Jun-ichiro、Norinaga Koyo
    • Journal Title

      ISIJ International

      Volume: 59 Issue: 8 Pages: 1376-1381

    • DOI

      10.2355/isijinternational.ISIJINT-2018-816

    • NAID

      130007691445

    • ISSN
      0915-1559, 1347-5460
    • Year and Date
      2019-08-15
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Predicting molecular composition of primary product derived from fast pyrolysis of lignin with semi-detailed kinetic model2018

    • Author(s)
      Furutani Yuki、Kudo Shinji、Hayashi Jun-ichiro、Norinaga Koyo
    • Journal Title

      Fuel

      Volume: 212 Pages: 515-522

    • DOI

      10.1016/j.fuel.2017.10.079

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study on Elementary Reaction Steps in Thermal Decomposition Processes of Syringol-Type Monolignol Compounds2018

    • Author(s)
      Furutani Yuki、Dohara Yuki、Kudo Shinji、Hayashi Jun-ichiro、Norinaga Koyo
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 122 Issue: 3 Pages: 822-831

    • DOI

      10.1021/acs.jpca.7b09450

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Computational Study on the Thermal Decomposition of Phenol-Type Monolignols2018

    • Author(s)
      Furutani Yuki、Dohara Yuki、Kudo Shinji、Hayashi Jun-Ichiro、Norinaga Koyo
    • Journal Title

      International Journal of Chemical Kinetics

      Volume: 50 Issue: 4 Pages: 304-316

    • DOI

      10.1002/kin.21164

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An approach for on-line analysis of multi-component volatiles from coal pyrolysis with Li+ -attachment ionization mass spectrometry2017

    • Author(s)
      Zhang Lu, Qi Shi-Chao, Iwanaga Keita, Uemura Kazuhiro, Zhang Li-Xin, Kudo Shinji, Hayashi Jun-ichiro, Furuya Kenji, Norinaga Koyo
    • Journal Title

      FUEL PROCESSING TECHNOLOGY

      Volume: 158 Pages: 141-145

    • DOI

      10.1016/j.fuproc.2016.12.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study on Hydrogenolytic Cleavage of Intermonomer Linkages in Lignin2017

    • Author(s)
      Shi-Chao Qi, Lu Zhang, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi*
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 5 Issue: 15 Pages: 2868-2877

    • DOI

      10.1021/acs.jpca.7b00602

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Theoretical Study on the Kinetics of Thermal Decomposition of Guaiacol and Catechol2017

    • Author(s)
      Furutani Yuki, Dohara Yuki, Kudo Shinji, Hayashi Jun-ichiro, Norinaga Koyo
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY A

      Volume: 121 Issue: 44 Pages: 8495-8503

    • DOI

      10.1021/acs.jpca.7b08112

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 詳細反応化学速度モデルを用いた噴流床石炭ガス化炉における芳香族炭化水素の改質およびスス生成シミュレーション2019

    • Author(s)
      安達希美, 町田洋, 則永行庸
    • Organizer
      第56回石炭科学会議
    • Related Report
      2019 Annual Research Report
  • [Presentation] 石炭ガス化炉内硫黄化合物転換特性の詳細化学反応速度モデルに基づく解析2019

    • Author(s)
      安達希美, 町田洋, 則永行庸
    • Organizer
      第28回日本エネルギー学会大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Chemical Reaction Engineering Toward Realizing Carbon Circulation2019

    • Author(s)
      Koyo Norinaga
    • Organizer
      The First International Symposium of Young Scholars on Carbon Resources Conversion (YSCRC-2019) October 11th-14th, 2019, Shenyang University of Chemical Technology (SYUCT), Liaoning Province, China.
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 炭素資源、CO2分離、利用プロセスの統合2019

    • Author(s)
      則永行庸
    • Organizer
      第57回炭素材料夏季セミナー 九州大学筑紫キャンパス
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Mechanistic level understanding of biomass thermochemical reactions with detailed chemical kinetic modeling2019

    • Author(s)
      Koyo Norinaga
    • Organizer
      Seminar “Biomass to Energy” in Indonesia JICA-JST SATREPS
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 炭素資源転換と炭素循環利用に関する基礎研究2018

    • Author(s)
      則永行庸
    • Organizer
      化学工学会産学官連携センターグローバルテクノロジー委員会 名古屋工業大学
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Modeling reactive flows in carbon resources conversion2018

    • Author(s)
      Koyo Norinaga
    • Organizer
      KIChE-SCEJ joint session, KIChE Fall conference in 2018 25th October 2018 Daegu
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] リグニン急速熱分解の生成物組成を予測可能とする素反応モデル構築2018

    • Author(s)
      古谷 優樹・ 堂原 祐騎・ 工藤 真二・林 潤一郎・則永 行庸
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] これからの石炭・炭素資源の熱化学2017

    • Author(s)
      則永行庸
    • Organizer
      石炭・炭素資源利用技術第148委員会第162回研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Understanding thermochemical conversion of solid fuels at mechanistic level2017

    • Author(s)
      Koyo Norinaga
    • Organizer
      Seminar at School of Engineering, THE UNIVERSITY OF EDINBURGH, UK
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 初期熱分解及び二次気相分解の素反応モデル連成によるリグニン急速熱分解生成物 組成の予測2017

    • Author(s)
      古谷優樹,堂原裕騎,工藤真二,林潤一郎,則永行庸
    • Organizer
      第26回日本エネルギー学会大会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      https://www.material.nagoya-u.ac.jp/nori_lab/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 研究室HP

    • URL

      https://www.material.nagoya-u.ac.jp/nori_lab/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.nuce.nagoya-u.ac.jp/e6/e6_nori.htm

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi