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Preparation of photocatalysts for challenging substance conversions working under natural energy

Research Project

Project/Area Number 17H03462
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKindai University

Principal Investigator

KOMINAMI Hiroshi  近畿大学, 理工学部, 教授 (00257966)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2019: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2018: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
Keywords光触媒 / 自然エネルギー / 物質変換 / プラズモニック光触媒 / 可視光 / 太陽光 / バイオマス / メタルフリー / 水素フリー / 水素化 / 流通型反応器
Outline of Final Research Achievements

We investigated the following agendas: a) highly difficult selective conversion of substances, b) utilization of natural energy (light/heat) and waste, and c) visiblization of photocatalyst. We achieved the results shown below. 1) Various photocatalytic reactions proceed under metal-free and hydrogen-free conditions. 2) By introducing a co-catalyst, the reaction rate is significantly increased. 3) Various solvents including water can be used. 4) Under solar irradiation, the reaction proceeds even under passive conditions where no external energy is applied. 5) Waste can be used as a hydrogen source. 6) The reaction rate is greatly increased by elevating the reaction temperature by 30 K.

Academic Significance and Societal Importance of the Research Achievements

自然エネルギーと光触媒を組み合わせることにより、温和な条件において様々な高難度物質変換反応が可能であることを明らかにした。また、その処理にエネルギーを投入している廃棄物を目的反応の水素源に利用できることもわかった。本研究は、自然エネルギーを主な駆動源とする低エネルギー消費型化学工場への道程の第一歩となる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (107 results)

All 2020 2019 2018 2017 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (85 results) (of which Int'l Joint Research: 28 results,  Invited: 3 results) Remarks (5 results)

  • [Journal Article] A simple method for deoxygenation of amine oxides to amines free from precious metals and undesirable reductants: Photocatalytic reaction in alcohol suspensions of TiO2 under solar light2020

    • Author(s)
      Fukui Makoto、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      Applied Catalysis A: General

      Volume: 591 Pages: 117412-117412

    • DOI

      10.1016/j.apcata.2020.117412

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic hydrogenation of nitrobenzenes to anilines over noble metal-free TiO2 utilizing methylamine as a hydrogen donor2020

    • Author(s)
      Fukui Makoto、Koshida Wakiko、Tanaka Atsuhiro、Hashimoto Keiji、Kominami Hiroshi
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 268 Pages: 118446-118446

    • DOI

      10.1016/j.apcatb.2019.118446

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Accelerated Semihydrogenation of Alkynes over a Copper/Palladium/Titanium?(IV) Oxide Photocatalyst Free from Poison and H 2 Gas2020

    • Author(s)
      Imai Shota、Nakanishi Kousuke、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      ChemCatChem

      Volume: 12 Issue: 6 Pages: 1609-1616

    • DOI

      10.1002/cctc.201902175

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Reductive Defluorination of Fluorinated Compounds in Aqueous Alcohol Suspensions of a Metal‐loaded Titanium(IV) Oxide2020

    • Author(s)
      Fukui Makoto、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      ChemCatChem

      Volume: - Issue: 12 Pages: 3298-3305

    • DOI

      10.1002/cctc.202000299

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correction: A silver?manganese dual co-catalyst for selective reduction of carbon dioxide into carbon monoxide over a potassium hexatitanate photocatalyst with water2020

    • Author(s)
      Zhu Xing、Yamamoto Akira、Imai Shota、Tanaka Atsuhiro、Kominami Hiroshi、Yoshida Hisao
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 16 Pages: 2514-2514

    • DOI

      10.1039/d0cc90074e

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facet-selective deposition of a silver-manganese dual cocatalyst on potassium hexatitanate photocatalyst for highly selective reduction of carbon dioxide by water2020

    • Author(s)
      Zhu Xing、Yamamoto Akira、Imai Shota、Tanaka Atsuhiro、Kominami Hiroshi、Yoshida Hisao
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: - Pages: 119085-119085

    • DOI

      10.1016/j.apcatb.2020.119085

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of conduction band potential on cocatalyst-free plasmonic H2 evolution over Au loaded on Sr2+-doped CeO22019

    • Author(s)
      Fudo Eri、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      Catalysis Science & Technology

      Volume: 9 Issue: 12 Pages: 3047-3054

    • DOI

      10.1039/c9cy00673g

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cocatalyst-free Plasmonic H2 Production over Au/Ta2O5 under Irradiation of Visible Light2019

    • Author(s)
      Fudo Eri、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 8 Pages: 939-942

    • DOI

      10.1246/cl.190379

    • NAID

      130007687700

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen- and noble metal-free conversion of nitro aromatics to amino aromatics having reducible groups over an organically modified TiO2 photocatalyst under visible light irradiation2019

    • Author(s)
      Yamamoto Yuhei、Fukui Makoto、Tanaka Atsuhiro、Hashimoto Keiji、Kominami Hiroshi
    • Journal Title

      Catalysis Science & Technology

      Volume: 9 Issue: 4 Pages: 966-973

    • DOI

      10.1039/c8cy02135j

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Selective Ring Hydrogenation of Phenol to Cyclohexanone over a Palladium‐Loaded Titanium(IV) Oxide under Hydrogen‐Free Conditions2019

    • Author(s)
      Kinoshita Atsufumi、Nakanishi Kousuke、Tanaka Atsuhiro、Hashimoto Keiji、Kominami Hiroshi
    • Journal Title

      ChemPhotoChem

      Volume: 印刷中 Issue: 7 Pages: 559-567

    • DOI

      10.1002/cptc.201900069

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen-free ring hydrogenation of phenol to cyclohexanol over a rhodium-loaded titanium(IV) oxide photocatalyst2019

    • Author(s)
      Kinoshita Atsufumi、Nakanishi Kousuke、Yagi Ryosuke、Tanaka Atsuhiro、Hashimoto Keiji、Kominami Hiroshi
    • Journal Title

      Applied Catalysis A: General

      Volume: 578 Pages: 83-88

    • DOI

      10.1016/j.apcata.2019.04.001

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible light-induced diastereoselective semihydrogenation of alkynes to cis-alkenes over an organically modified titanium(IV) oxide photocatalyst having a metal co-catalyst2019

    • Author(s)
      Makoto Fukui, Yuya Omori, Shin-ya Kitagawa, Atsuhiro Tanaka, Keiji Hashimoto and Hiroshi Kominami
    • Journal Title

      Journal of Catalysis

      Volume: 印刷中

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Additive-free Semihydrogenation of an Alkynyl Group to an Alkenyl Group over Pd?TiO2 Photocatalyst Utilizing Temporary In-situ Deactivation2018

    • Author(s)
      Kojima Yasumi、Fukui Makoto、Tanaka Atsuhiro、Hashimoto Keiji、Kominami Hiroshi
    • Journal Title

      ChemCatChem

      Volume: 10 Issue: 16 Pages: 3605-3611

    • DOI

      10.1002/cctc.201800663

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Titanium(IV) oxide having a copper co-catalyst: a new type of semihydrogenation photocatalyst working efficiently at an elevated temperature under hydrogen-free and poison-free conditions2018

    • Author(s)
      Hiroshi Kominami, Misaki Shiba, Akimi Hashimoto,a Shota Imai, Kousuke Nakanishi, Atsuhiro Tanaka, Keiji Hashimoto and Kazuya Imamura
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 29 Pages: 19321-19325

    • DOI

      10.1039/c8cp02316f

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ring hydrogenation of aromatic compounds in aqueous suspensions of an Rh-loaded TiO2 photocatalyst without use of H2 gas2018

    • Author(s)
      K. Nakanishi, R. Yagi, K. Imamura, A. Tanaka, K. Hashimoto, H. Kominami
    • Journal Title

      Catalysis Science and Technology

      Volume: 8 Issue: 1 Pages: 139-146

    • DOI

      10.1039/c7cy01929g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Selective Hydrogenation of Furfural to Furfuryl Alcohol over Titanium(IV) Oxide2018

    • Author(s)
      Nakanishi Kousuke、Tanaka Atsuhiro、Hashimoto Keiji、Kominami Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 2 Pages: 254-256

    • DOI

      10.1246/cl.171053

    • NAID

      130006337747

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic hydrogenation of furan to tetrahydrofuran in alcoholic suspensions of metal-loaded titanium(iv) oxide without addition of hydrogen gas2017

    • Author(s)
      Nakanishi Kousuke、Tanaka Atsuhiro、Hashimoto Keiji、Kominami Hiroshi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Issue: 30 Pages: 20206-20212

    • DOI

      10.1039/c7cp02891a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Semihydrogenation of alkyne over titanium(IV) oxide photocatalyst having palladium core-silver shell nanoparticle co-catalyst2019

    • Author(s)
      今井翔太, 田中淳皓, 古南博
    • Organizer
      第10回触媒科学研究発表会[2019.6.8] (鳥取大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Water oxidation over gold core-chromium oxide shell plasmonic photocatalyst under irradiation of visible light2019

    • Author(s)
      不動愛理, 田中淳皓, 古南博
    • Organizer
      第10回触媒科学研究発表会[2019.6.8] (鳥取大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effect of organic modulator on reduction of furfural to furfuryl alcohol over titanium dioxide modified with organic compound under irradiation of visible light2019

    • Author(s)
      山本祐平, 田中淳皓, 古南博
    • Organizer
      第10回触媒科学研究発表会[2019.6.8] (鳥取大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 正孔移動助触媒修飾金プラズモニック光触媒による水の酸化反応2019

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第40回 触媒学会若手会 夏の研修会 [2019.7.31-8/2]
    • Related Report
      2019 Annual Research Report
  • [Presentation] 酸化チタン電極を用いたニトロ基を有する芳香化合物の電気化学的還元反応2019

    • Author(s)
      東林智也、田中淳皓、古南博
    • Organizer
      第40回 触媒学会若手会 夏の研修会 [2019.7.31-8/2]
    • Related Report
      2019 Annual Research Report
  • [Presentation] Deoxygenation of oxygen containing organic compounds over titanium(IV) oxide photocatalyst in aqueous suspension2019

    • Author(s)
      Makoto Fukui, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      The 8th Asia Pacific Congress on Catalysis (APCAT-8) [2019.8.4-8/7] (タイ バンコク)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic selective oxidation of alcohols to corresponding carbonyl compounds by visible light responsive bismuth vanadate2019

    • Author(s)
      Kazuki Morishita, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      EuropaCat 2019 [2019.8.18-23] (ドイツ アーヘン)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ruthenium and palladium bimetallic system achieving functional parity with a rhodium co-catalyst for TiO2-photocatalyzed ring hydrogenation of benzoic acid2019

    • Author(s)
      Sakae araki, Kousuke nakanishi, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      EuropaCat 2019 [2019.8.18-23] (ドイツ アーヘン)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic reduction of furfural to furfuryl alcohol over titanium dioxide modified with organic compounds under visible light irradiation2019

    • Author(s)
      Yuhei Yamamoto, Makoto Fukui, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      EuropaCat 2019 [2019.8.18-23] (ドイツ アーヘン)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] グリセリンを正孔捕捉剤に用いた光触媒的脱酸素反応2019

    • Author(s)
      小野木和寛、田中淳皓、古南博
    • Organizer
      第13回触媒道場 [2019.8.29-8/30] (滋賀 琵琶湖グランドホテル)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 可視光照射下における金ナノロッドプラズモニック光触媒を用いた水素生成2019

    • Author(s)
      小嶋友也、八木稜祐、田中淳皓、古南博
    • Organizer
      第13回触媒道場 [2019.8.29-8/30] (滋賀 琵琶湖グランドホテル)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Rapid semihydrogenation of alkynes over titanium(IV) oxide photocatalyst having palladium core-copper shell co-catalyst nanoparticles2019

    • Author(s)
      Shota Imai, Kousuke Nakanishi, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      SP7[2019.9.11-14](イタリア ミラノ)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen evolution from alcohol over copper species modified tungsten(VI) oxide photocatalyst under visible light irradiation2019

    • Author(s)
      Kazuki Hayami, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      SP7[2019.9.11-14](イタリア ミラノ)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of conduction band potential on cocatalyst-free plasmonic hydrogen evolution over gold particles loaded on strontium ion-doped cerium dioxide2019

    • Author(s)
      Eri fudo, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      SP7[2019.9.11-14](イタリア ミラノ)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of gold particles loaded on titania particles plasmonic photocatalysts working under irradiation of visible light in the range of 600-700 nm2019

    • Author(s)
      Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      SP7[2019.9.11-14](イタリア ミラノ)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 調製法の異なる金プラズモニック光触媒の特性比較2019

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      触媒討論会[2019.9.18-20](長崎大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] パラジウム担持酸化チタン光触媒の水素化特性に対するシェル金属の導入効果2019

    • Author(s)
      今井翔太、田中淳皓、古南博
    • Organizer
      触媒討論会[2019.9.18-20](長崎大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属助触媒担持酸化チタン(IV)光触媒による還元的脱フッ素反応2019

    • Author(s)
      福井誠、田中淳皓、古南博
    • Organizer
      触媒討論会[2019.9.18-20](長崎大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Reductive defluorination over metal-loaded titanium(IV) oxide (TiO2) photocatalyst2019

    • Author(s)
      Makoto Fukui, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      5th international congress on catalysis for Biorefineries[2019.9.23-27](フィンランド タルク)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 光触媒の開発と有用化学品製造2019

    • Author(s)
      古南博
    • Organizer
      会報光触媒発刊20周年記念・光機能材料研究会第75回講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] プラズモニック光触媒による水素生成および物質変換2019

    • Author(s)
      古南博
    • Organizer
      第17回プラズモニック化学シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] パラジウムコア-銀シェルナノ粒子担持酸化チタン(IV)光触媒を用いたアルキンの部分水素化反応2019

    • Author(s)
      今井翔太・小島矢純・田中淳皓・古南 博
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光触媒的核水素化反応における助触媒複合効果2019

    • Author(s)
      荒木 栄・中西康介・田中淳皓・古南 博
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金ナノロッド修飾酸化チタン光触媒を用いた可視光水素生成反応2019

    • Author(s)
      小嶋友也・田中淳皓・古南 博
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 各種有機修飾酸化チタンによるフルフラールの可視光光触媒還元2019

    • Author(s)
      山本祐平・福井 誠・田中淳皓・古南 博
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 酸化チタン電極を用いたニトロベンゼンスルホン酸の電気化学的還元反応2019

    • Author(s)
      東林智也・田中淳皓・古南 博
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金コア-酸化クロムシェル型プラズモニック光触媒による水の酸化反応2019

    • Author(s)
      不動愛理・田中淳皓・古南博
    • Organizer
      第124回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 酸化チタン(IV)光触媒によるアミンオキシド類の脱酸素反応の機構解析2019

    • Author(s)
      福井誠・田中淳皓・古南博
    • Organizer
      第124回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ring hydrogenation of aromatic compounds in aqueous suspensions of Rh-loaded TiO2 photocatalyst without use of H2 gas2018

    • Author(s)
      H. Kominami, K. Nakanishi, R. Yagi, K. Imamura, A. Tanaka, K. Hashimoto
    • Organizer
      10th European meeting on Solar Chemistry and Photocatalysis: Environmental Applications (SPEA10)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Reduction of Nitrate to Nitrite in an Aqueous Suspension of Ag-Loaded Titanium(IV) Oxide Nanoparticles2018

    • Author(s)
      S. Takenouchi, A. Tanaka, K. Hashimoto, H. Kominami
    • Organizer
      10th European meeting on Solar Chemistry and Photocatalysis: Environmental Applications (SPEA10)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoinduced Ring Hydrogenation of Phenol over Metal-loaded Titanium(IV) Oxide under Irradiation of UV Light2018

    • Author(s)
      A. Kinoshita, K. Nakanishi, A. Tanaka, K. Hashimoto, H. Kominami
    • Organizer
      10th European meeting on Solar Chemistry and Photocatalysis: Environmental Applications (SPEA10)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visible light induced semi-hydrogenation of alkynes to cis-alkenes over organically modified titanium(IV) oxide photocatalyst2018

    • Author(s)
      福井誠、田中淳皓、古南博
    • Organizer
      2018年度触媒学会西日本支部 第9回触媒科学研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Photocatalytic selective sulfoxide production from sulfide over tungsten(VI) oxide loaded with palladium nanoparticles under visible irradiation2018

    • Author(s)
      宮田直倫、田中淳皓、古南博
    • Organizer
      2018年度触媒学会西日本支部 第9回触媒科学研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] パラジウムコアー銅シェルナノ粒子を助触媒とする酸化チタン光触媒によるアルキンの部分水素化反応2018

    • Author(s)
      今井翔太、中西康介、田中淳皓、橋本圭司、古南博
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光照射による有機基修飾酸化チタン(IV)光触媒を用いた芳香族ニトロ化合物の化学選択的還元2018

    • Author(s)
      山本祐平、福井誠、田中淳皓、橋本圭司、古南博
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光応答型バナジン酸ビスマス光触媒によるアルコール選択酸化反応2018

    • Author(s)
      森下和輝、田中淳皓、橋本圭司、古南博
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光応答型有機基修飾TiO2光触媒を用いたアルキンの部分水素化反応2018

    • Author(s)
      福井誠、田中淳皓、古南博
    • Organizer
      第37回光がかかわる触媒化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] パラジウムコア-銅シェルナノ粒子担持酸化チタン(IV)光触媒を用いたアルキンの部分水素化反応2018

    • Author(s)
      今井翔太、中西康介、田中淳皓、古南博
    • Organizer
      第37回光がかかわる触媒化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 二波長光同時照射によるSrTiO3:Rh光触媒の水素生成挙動と励起機構考察2018

    • Author(s)
      速見一輝、田中淳皓、古南博
    • Organizer
      第37回光がかかわる触媒化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金プラズモニック光触媒による水素生成反応に対する金属酸化物伝導帯準位の影響2018

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第37回光がかかわる触媒化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Preparation of visible-light responding organically modified titania photocatalyst for meerwein-ponndorf-verley (MPV)-type reduction2018

    • Author(s)
      Makoto Fukui, Atsuhiro Tanaka, Keiji Hashimoto, Hiroshi Kominami
    • Organizer
      12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts" (PREPA12)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of metal loaded tungsten trioxide for selective oxidation of sulfides under visible light irradiation2018

    • Author(s)
      Naomichi Miyata, Atsuhiro Tanaka, Keiji Hashimoto, Hiroshi Kominami
    • Organizer
      12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of rhodium-modified titanium oxide for hydrogen formation under irradiation of visible light2018

    • Author(s)
      Takumi Nagai, Atsuhiro Tanaka, Syo Kitano, Keiji Hashimoto, Hiroshi Kominami
    • Organizer
      12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Cu/TiO2 with Cr species exhibiting strong surface plasmon resonance effective for photoinduced selective oxidation under irradiation of visible light2018

    • Author(s)
      Kohki Okabayashi, Atsuhiro Tanaka, Keiji Hashimoto, Hiroshi Kominami
    • Organizer
      12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of gold nanoparticles supported on titanium(IV) oxide with cocatalysts exhibiting strong surface plasmon resonance effective for visible light-induced water splitting2018

    • Author(s)
      Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Diastereoselective semi-hydrogenation of alkynes to cis-alkenes over visible-light responding organically modified titania photocatalyst2018

    • Author(s)
      Makoto FUKUI, Yuya OMORI, Keiji HASHIMOTO, Atsuhiro TANAKA, Hiroshi KOMINAMI
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective photocatalytic oxidation of aromatic alcohols to aldehydes over Ag-Au/TiO2, Au/TiO2 and Cu-Au/TiO2 under irradiation of visible light2018

    • Author(s)
      Atsuhiro TANAKA, Hiroshi KOMINAMI
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen-free Ring Hydrogenation of Aromatic Compounds in Aqueous Suspensions of Rh-loaded TiO2 Photocatalyst2018

    • Author(s)
      Hiroshi KOMINAMI, Kousuke NAKANISHI, Ryosuke YAGI, Kazuya IMAMURA, Atsuhiro TANAKA
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 可視光照射下における金プラズモニック光触媒を用いた水の酸化反応2018

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 部分水素化能を示すコアシェル粒子担持酸化チタン光触媒の構造および電子状態2018

    • Author(s)
      今井翔太、田中淳皓、古南博
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アルコールを水素源とするアミンオキシドの光触媒的脱酸素反応2018

    • Author(s)
      福井誠、田中淳皓、古南博
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 銅化合物修飾酸化タングステン(VI)光触媒を用いた水素生成反応2018

    • Author(s)
      速見一輝、田中淳皓、古南博
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光応答型有機基修飾酸化チタン(IV)光触媒を用いたフルフラールの還元2018

    • Author(s)
      山本祐平、福井誠、田中淳皓、古南博
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] ヒドロシランを用いたニトロベンゼンの触媒的還元反応2018

    • Author(s)
      田中俊彦、田中淳皓、古南博
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] Hydrogen formation over copper species modified tungsten(VI) oxide under visible light irradiation2018

    • Author(s)
      Kazuki Hayami, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      Osaka-Kansai International Symposium on Catalysis (OKCAT2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Water oxidation over gold plasmonic photocatalyst under visible light irradiation2018

    • Author(s)
      Eri Fudo, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      Osaka-Kansai International Symposium on Catalysis (OKCAT2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of structure and electronic state of core-shell cocatalyst on photocatalytic hydrogenation of alkyne2018

    • Author(s)
      Shota Imai, Kousuke Nakanishi, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      Osaka-Kansai International Symposium on Catalysis (OKCAT2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バナジン酸ビスマスの光触媒作用:アルコール酸化によるカルボニル化合物の合成2018

    • Author(s)
      森下和輝、田中淳皓、古南博
    • Organizer
      第24回シンポジウム「光触媒反応の最近の展開」
    • Related Report
      2018 Annual Research Report
  • [Presentation] 酸化チタン(IV)光触媒を用いたアルデヒドの化学選択的還元反応およびカップリング反応2018

    • Author(s)
      福井誠、田中淳皓、古南博
    • Organizer
      第24回シンポジウム「光触媒反応の最近の展開」
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pd@Cu/TiO2光触媒による高速部分水素化反応2018

    • Author(s)
      今井翔太、中西康介、田中淳皓、古南博
    • Organizer
      第24回シンポジウム「光触媒反応の最近の展開」
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光触媒を用いる化学選択的物質変換2018

    • Author(s)
      古南 博
    • Organizer
      第24回シンポジウム「光触媒反応の最近の展開」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Deoxygenation of Amine-N-oxides to Amines over Titanium(IV) Oxide Photocatalyst2018

    • Author(s)
      Makoto Fukui, Atsuhiro Takaka, Hiroshi Kominami
    • Organizer
      The International Symposium on Catalysis and Fine Chemicals 2018 (C&FC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バナジン酸ビスマス光触媒のアルコール選択酸化機能の解析2018

    • Author(s)
      森下和輝、田中淳皓、古南博
    • Organizer
      日本エネルギー学会関西支部 第63回研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光触媒的核水素化反応に対する助触媒の複合効果2018

    • Author(s)
      荒木栄、田中淳皓、古南博
    • Organizer
      日本エネルギー学会関西支部 第63回研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 有機修飾によるTiO2光触媒の可視光応答化とフルフラール還元への応用2018

    • Author(s)
      山本祐平、福井誠、田中淳皓、古南博
    • Organizer
      日本エネルギー学会関西支部 第63回研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光応答型有機基修飾酸化チタン(IV)光触媒を用いた芳香族ニトロ化合物の還元2018

    • Author(s)
      山本祐平、福井誠、田中淳皓、橋本圭司、古南博
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化チタン光触媒によるアルキンの部分水素化反応における助触媒協奏効果2018

    • Author(s)
      今井翔太、中西康介、田中淳皓、橋本圭司、古南博
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可視光アルコール選択酸化反応におけるバナジン酸ビスマス光触媒の物性の影響2018

    • Author(s)
      森下和輝、田中淳皓、橋本圭司、古南博
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化チタン(IV)光触媒によるピナコールカップリング反応2018

    • Author(s)
      福井誠、田中淳皓、橋本圭司、古南博
    • Organizer
      第121回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photocatalytic semi-hydrogenation of alkynes in the solid-gas flow-type reactor2017

    • Author(s)
      幸田秀紀、田中淳皓、橋本圭司、古南博
    • Organizer
      触媒学会西日本支部第8回触媒科学研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Stable loading of Au nanorods and evaluation of their performance as plasmonic photocatalysts2017

    • Author(s)
      八木稜祐、田中淳皓、橋本圭司、古南博
    • Organizer
      触媒学会西日本支部第8回触媒科学研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect on preparation conditions of Ag loaded on titanium (IV) oxide electrode for selective reduction nitrate ion to nitrite ion2017

    • Author(s)
      山田裕貴、田中淳皓、橋本圭司、古南博
    • Organizer
      触媒学会西日本支部第8回触媒科学研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 窒化炭素光触媒を用いるアルキンのジアステレオ選択的部分水素化反応2017

    • Author(s)
      渡邉章太郎、田中淳皓、橋本圭司、古南博
    • Organizer
      第36回光がかかわる触媒化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 銀担持有機基修飾酸化チタンを用いたエポキシドの脱酸素反応2017

    • Author(s)
      武久昂憲、田中淳皓、橋本圭司、古南博
    • Organizer
      第36回光がかかわる触媒化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 硝酸イオンの選択的光触媒還元および有機化合物への固定化2017

    • Author(s)
      竹之内翔、田中淳皓、橋本圭司、古南博
    • Organizer
      第36回光がかかわる触媒化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可視光照射下におけるオキシハロゲン化ビスマス(III)光触媒を用いた選択酸化反応2017

    • Author(s)
      重村航介、嶋津勇哉、田中淳皓、橋本圭司、古南博
    • Organizer
      第36回光がかかわる触媒化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photocatalytic hydrogenation of furan over palladium-loaded titanium dioxide without addition of H2 gas2017

    • Author(s)
      Kousuke Nakanishi, Atsuhiro Tanaka, Keiji Hashimoto, Hiroshi Kominami
    • Organizer
      28th International Conference on Photochemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化チタン光触媒上への二元素担持による新規助触媒機能の発現2017

    • Author(s)
      中西康介、田中淳皓、橋本圭司、古南博
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可視光応答型有機基修飾酸化チタン(IV)光触媒によるアルキンのジアステレオ選択的部分水素化反応2017

    • Author(s)
      福井誠、大森優也、北川慎也、田中淳皓、橋本圭司、古南博
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 助触媒担持光触媒フェノールからシクロヘキサノンへの選択的水素化2017

    • Author(s)
      木下敦文、中西康介、田中淳皓、橋本圭司、古南博
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Reaction temperature dependence in sulfide oxidation over metal-loaded WO3 photocatalyst under irradiation of visible light2017

    • Author(s)
      Naomichi Miyata, Atsuhiro Tanaka, Keiji Hashimoto, Hiroshi Kominami
    • Organizer
      第10回触媒表面化学研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Cuプラズモニック光触媒材料による化学反応2017

    • Author(s)
      岡林浩希、田中淳皓、橋本圭司、古南博
    • Organizer
      日本エネルギー学会関西支部 第62回研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photocatalytic hydrogenation of furan in alcoholic suspensions of Pd metal-loaded titanium(IV) oxide without addition of H2 gas2017

    • Author(s)
      H. Kominami, K. Nakanishi, A. Tanaka, K. Hashimoto
    • Organizer
      4th international congress on catalysis for Biorefineries
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Meerwein-Ponndorf-Verley-type reduction of aromatic aldehydes in ethanol suspensions of TiO2 photocatalyst2017

    • Author(s)
      M. Fukui, A. Tanaka, K. Hashimoto, H. Kominami
    • Organizer
      4th international congress on catalysis for Biorefineries
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective oxidation of ethanol and semi-hydrogenation of alkyne using TiO2 photocatalytic reactor2017

    • Author(s)
      H. Kouda, A. Tanaka, K. Hashimoto, H. Kominami
    • Organizer
      4th international congress on catalysis for Biorefineries
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 表面設計化学研究室

    • URL

      http://www.apch.kindai.ac.jp/surface-folder/surface-index.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 古南 博【究極は太陽の光だけで操業する「太陽光化学工場」。 光触媒で世界一を目指す。】

    • URL

      https://www.kindai.ac.jp/science-engineering/research/forefront-research/kominami-hiroshi/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 表面設計化学研究室

    • URL

      http://apsrv.apch.kindai.ac.jp/surface-folder/surface-index.html

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] スポットライト

    • URL

      https://www.kindai.ac.jp/sci/research/forefront_research/kominami_hiroshi.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] スポットライト

    • URL

      http://www.kindai.ac.jp/sci/research/forefront_research/kominami_hiroshi.html

    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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