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Fabrication of ferromagnetic CNT (carbon nanotube)-IL (ionic liquid) composites using anomalous Coulombic fields of carbon nanopores

Research Project

Project/Area Number 17H04953
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Composite materials/Surface and interface engineering
Research InstitutionShinshu University

Principal Investigator

Futamura Ryusuke  信州大学, 学術研究院理学系, 助教 (90647223)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥23,790,000 (Direct Cost: ¥18,300,000、Indirect Cost: ¥5,490,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2017: ¥21,190,000 (Direct Cost: ¥16,300,000、Indirect Cost: ¥4,890,000)
Keywords複合材料 / 磁性材料 / イオン液体 / X線散乱測定 / 磁化率測定 / カーボンナノチューブ / 1次元構造 / 分子シミュレーション / 異常クーロン力空間 / 磁性イオン液体 / 異常クーロン相互作用 / 超イオン状態 / 強磁性材料 / ハイブリッドリバースモンテカルロ / 異常クーロン力場
Outline of Final Research Achievements

In this study, we aim to create hybrid materials of magnetic ionic liquids in carbon nanotubes, which show high magnetic response due to the unique 1 dimensional ordering of magnetic ions. For this purpose, we attempted following three studies; 1) The elucidation for the anomalous ionic liquid structure confined in carbon nanospaces. 2) The 1D order structure formation of ionic liquids in carbon nanotubes and understanding of the ordered structure. 3) Synthesis for the hybrid materials of magnetic ionic liquid in carbon nanotubes. In particular for 3), we succeeded to obtain the hybrid materials with crystal-like ordered structures, implying the possibility for the developments of the bland-new memory devises with ultra-high capacity.

Academic Significance and Societal Importance of the Research Achievements

本研究により、カーボンナノチューブを含むナノカーボン細孔中でのイオン液体構造の特異性を明らかにした。具体的には、導電性を有するナノカーボン細孔中でイオン液体は、同種イオンが近接した超イオン状態を形成することを解明した。これはナノ空間を利用することで、お互いにクーロン斥力が働く磁性イオンを密に配列させ、結果として強磁性を示すナノカーボン複合材料を合成可能であることを強く支持する。さらに本研究では磁性イオン液体とカーボンナノチューブの複合材料が秩序構造を形成することを明らかにし、既存の磁気記憶デバイスを凌ぐ新規超高容量記憶デバイスの開発に向け大きく前進した。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (37 results)

All 2020 2019 2018 2017 Other

All Journal Article (9 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 9 results,  Open Access: 4 results) Presentation (25 results) (of which Int'l Joint Research: 14 results,  Invited: 1 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Configurational evidence for antiferromagnetic interaction in disordered magnetic ionic liquids by X-ray scattering-aided hybrid reverse Monte Carlo simulation2020

    • Author(s)
      Futamura Ryusuke、Takasaki Yuma、Otsuka Hayato、Ozeki Sumio、Kaneko Katsumi、Iiyama Taku
    • Journal Title

      Journal of Molecular Liquids

      Volume: 311 Pages: 113321-113321

    • DOI

      10.1016/j.molliq.2020.113321

    • NAID

      120007099486

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mesoscopic cage-like structured single-wall carbon nanotube cryogels2020

    • Author(s)
      Kamijyou Yuito、Stevic Dragana、Kukobat Radovan、Urita Koki、Chotimah Nurul、Hattori Yoshiyuki、Futamura Ryusuke、Vallejos-Burgos Fernando、Moriguchi Isamu、Utsumi Shigenori、Sakai Toshio、Kaneko Katsumi
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 293 Pages: 109814-109814

    • DOI

      10.1016/j.micromeso.2019.109814

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A water-resilient carbon nanotube based strain sensor for monitoring structural integrity2019

    • Author(s)
      Ahuja Preety、Akiyama Shingo、Ujjain Sanjeev Kumar、Kukobat Radovan、Vallejos-Burgos Fernando、Futamura Ryusuke、Hayashi Takuya、Kimura Mutsumi、Tomanek David、Kaneko Katsumi
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 7 Issue: 34 Pages: 19996-20005

    • DOI

      10.1039/c9ta06810d

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 517.Unusual hygroscopic nature of nanodiamonds in comparison with well-known porous materials2019

    • Author(s)
      E.-Z. Piña-Salazar, T. Sakai, E. Osawa, R. Futamura, K. Kaneko
    • Journal Title

      J. Colloid Interface Science

      Volume: 549 Pages: 133-139

    • DOI

      10.1016/j.jcis.2019.04.053

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrical conductivity changes of water-adsorbed nanodiamonds with thermal treatment2019

    • Author(s)
      Pina-Salazar Elda-Zoraida、Sagisaka Kento、Hattori Yoshiyuki、Sakai Toshio、Futamura Ryusuke、Osawa Eiji、Kaneko Katsumi
    • Journal Title

      Chemical Physics Letters: X

      Volume: 2 Pages: 100018-100018

    • DOI

      10.1016/j.cpletx.2019.100018

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 514.X-ray absorption anomaly of well-characterized multiwall carbon nanotubes2018

    • Author(s)
      F. Lhoerunnisa, R. Futamura, S.Mukai, T. Konishi, T. Fujikawa, K. Kaneko
    • Journal Title

      Carbon

      Volume: 145 Pages: 209-217

    • DOI

      10.1016/j.carbon.2019.01.021

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Charge-transfer mediated nanopore-controlled pyrene derivatives/graphene colloids2018

    • Author(s)
      Putri Austina D.、Chotimah Nurul、Ujjain Sanjeev Kumar、Wang Shuwen、Futamura Ryusuke、Vallejos-Burgos Fernando、Khoerunnisa Fitri、Morimoto Masafumi、Wang Zhipeng、Hattori Yoshiyuki、Sakai Toshio、Kaneko Katsumi
    • Journal Title

      Carbon

      Volume: 139 Pages: 512-521

    • DOI

      10.1016/j.carbon.2018.07.001

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 512.Water-selective adsorption sites on detonation nanodiamonds2018

    • Author(s)
      E.Z.Pina-Salazar, R. Kukobat, R. Futamura, T. Hayashi, S. Toshio, E. Osawa, K. Kaneko
    • Journal Title

      Carbon

      Volume: 139 Pages: 53-860

    • DOI

      10.1016/j.carbon.2018.07.036

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores2017

    • Author(s)
      Ryusuke Futamura, Taku Iiyama, Yuma Takasaki, Yury Gogotsi, Mark Biggs, Mathieu Salanne, Julie Segalini, Patrice Simon, Katsumi Kaneko
    • Journal Title

      Nature Materials

      Volume: 16 Issue: 12 Pages: 1225-1232

    • DOI

      10.1038/nmat4974

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Elucidation of the polar molecules structure in nanospacees2019

    • Author(s)
      Shoichi Tonegawa, Ryusuke Futamura, Taku Iiyama
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of structure and molecular selectivity of carbon nanospace by introducing hydrophobic molecules2019

    • Author(s)
      Yuuki Ishihara, Minoru Deguchi, Ryusuke Futamura, Taku Iiyama
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic Ionic Liquids in Carbon Nanospaces2019

    • Author(s)
      Ryusuke Futamura, Yuma Takasaki and Taku Iiyama
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 吸着分子径・分子間相互作用の SWCNT 細孔中における分子集団構造への影響2019

    • Author(s)
      岩下 浩章、吉元 政嗣、二村 竜祐、飯山 拓
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] SBA-15 の細孔内における磁性イオン液体 emim FeCl4 の磁気特性2019

    • Author(s)
      大塚 隼人、高崎 優真、二村 竜祐、飯山 拓
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ナノ空間で同種イオンが形成する超イオン状態の解明と電場印加in-situ X線散乱測定法の開発2019

    • Author(s)
      二村 竜祐
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 温度を変数とした吸着現象の解明/新規現象の開拓2019

    • Author(s)
      糸島 和真、二村竜佑、飯山 拓
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] SBA-15へのイオン液体添加による親水性/疎水性のスイッチング機能発現2019

    • Author(s)
      石井 誠一郎、二村竜佑、飯山 拓
    • Organizer
      第50回中部化学関係学協会支部連合秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Adsorption and magnetic properties of SBA-15 functionalized by magnetic ionic liquid2019

    • Author(s)
      Hayato Otsuka, Yuma Takasaki, Ryusuke Futamura, Taku Iiyama
    • Organizer
      Fundamentals of Adsorption (FOA) 13
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In-situ X-ray Diffraction Evidenced GO/H2O Concerted Nanoporosity2019

    • Author(s)
      Ryusuke Futamura, Taku Iiyama, Takahiro Ueda, Katsumi Kaneko
    • Organizer
      Fundamentals of Adsorption (FOA) 13
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pore Size Dependent Superionic State of Ionic liquids in Carbon nanopores with Hybrid Reverse Monte Carlo Simulation-aided X-ray Scattering2019

    • Author(s)
      Ryusuke Futamura, Taku Iiyama, Yury Gogotsi, Mark J. Biggs, Mathieu Salanne, Patrice Simon, Katsumi Kaneko
    • Organizer
      Japan Adsorption 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Adsorption and Magnetic properties of ACF and SBA-15 Functionalized by Magnetic Ionic Liquid2019

    • Author(s)
      Hayato Otsuka, Yuma Takasaki, Ryusuke Futamura, and Taku Iiyama
    • Organizer
      Japan Adsorption 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Concerted Nanoporosity of H2O-adsorbed GOs, Evidenced by in-situ X-ray Diffractions2019

    • Author(s)
      R. Futamura, T. Iiyama, T. Ueda, K. Kaneko
    • Organizer
      MRM2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Superionic States Formation of Ionic Liquids in 1 Dimensional Nanopores of Carbon Nanotubes2019

    • Author(s)
      Futamura, T. Iiyam, R. Okumura, Y. Gogotsi, M. J. Biggs, M. Salanne, P. Simon and K. Kaneko
    • Organizer
      ICAC2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Water adsorption induced nanogaps between inter layer space of graphene oxide2019

    • Author(s)
      FUTAMURA, Ryusuke; IIYAMA, Taku; UEDA, Takahiro; KANEKO, Katsumi
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Co-ion Association Structure of Ionic Liquids in Monolayer Sized Carbon Nanopores2018

    • Author(s)
      R. Futamura, T. Iiyama, Y. Gogotsi, M. J. Biggs, M. Salanne, P. Simon, K. Kaneko
    • Organizer
      8th Pacific Basin Conference on Adsorption Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pore Size Sensitive Co-ion Association of Ionic Liquids in Carbon Nanopores2018

    • Author(s)
      R. Futamura, T. Iiyama, Y. Gogotsi, M. J. Biggs, M. Salanne, P. Simon, K. Kaneko
    • Organizer
      Carbon 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pore Size Effects on the Partial Breaking of Coulombic Ordering Structure of Ionic Liquids in Carbon Nanopores2018

    • Author(s)
      R. Futamura, T. Iiyama, Y. Gogotsi, M. J. Biggs, M. Salanne, P. Simon, K. Kaneko
    • Organizer
      The 8th international workshop characterization of porous materials: from angstroms to millimeters
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノカーボンの導電性が誘起する同種イオンの稠密構造に対する細孔サイズ依存性2018

    • Author(s)
      二村竜祐、飯山拓、P. Simon、M. Salanne、M. J. Biggs、Y. Gogotsi、金子克美
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 細孔ジオメトリがイオン液体の超イオン状態に与える影響2018

    • Author(s)
      二村竜祐, 飯山拓, P. Simon, M. Salanne, M. J. Biggs, Y. Gogotsi, 金子克美
    • Organizer
      第32回日本吸着学会研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] スーパーキャパシタの高容量化につながる同種イオンの濃縮状態-カーボン細孔中でイオン液体が形成する超イオン状態の解明2018

    • Author(s)
      R. Futamura, T. Iiyama,M. Salann, M. J. Biggs, Y. Gogotsi, P. Simon, K. Kaneko
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pore Size Effects on Superionic States of Ionic Liquids in Carbon Nanopores2018

    • Author(s)
      R. Futamura, T. Iiyama,M. Salann, M. J. Biggs, Y. Gogotsi, P. Simon, K. Kaneko
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Polarization Effects on Superionic-State of Ionic Liquids in Carbon Nanopores.2017

    • Author(s)
      R. Futamura, T. Iiyama, Y. Gogotsi, M. Salanne, P. Simon, K. Kaneko
    • Organizer
      Carbon2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microscopic Evidence for the Superionic-State Formation of Ionic Liquids in Carbon Nanopores2017

    • Author(s)
      R. Futamura, T. Iiyama, Y. Gogotsi, M. J. Biggs, M. Salanne, P. Simon, K. Kaneko.
    • Organizer
      The 6th symposium on Future Challenges for Carbon-Based Nanoporous Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カーボンナノ細孔中でイオン液体が形成する“非クーロン的”構造の制約依存性2017

    • Author(s)
      二村竜祐, 飯山拓, Patrice Simon, Mathieu Salanne, Mark J. Biggs, Yury Gogotsi, 金子克美
    • Organizer
      第31回日本吸着学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Book] 『PCP/MOFおよび各種多孔性材料の作り方、使い方、評価解析』「ナノ空間内の分子やイオンの特異構造解析」2019

    • Author(s)
      二村竜祐、飯山拓
    • Total Pages
      9
    • Publisher
      株式会社NTS
    • Related Report
      2019 Annual Research Report
  • [Remarks] 微小空間を最大限に利用しよう!

    • URL

      https://www.shinshu-u.ac.jp/faculty/science/quest/research/post-76.php

    • Related Report
      2019 Annual Research Report
  • [Remarks] 飯山・二村研ホームページ

    • URL

      http://science.shinshu-u.ac.jp/~tiiyama/

    • Related Report
      2019 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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