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Development and Calibration of the Polar Organic Chemical Integrative Sampler (POCIS) for highly hydrophilic chemicals

Research Project

Project/Area Number 17K00543
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental dynamic analysis
Research InstitutionResearch Institute of Environment, Agriculture and Fisheries, Osaka Prefecture

Principal Investigator

Yoshinori Yabuki  地方独立行政法人大阪府立環境農林水産総合研究所(環境研究部、食と農の研究部及び水産研究部), その他部局等, 主任研究員 (00360818)

Co-Investigator(Kenkyū-buntansha) 遠藤 智司  大阪市立大学, 大学院工学研究科, 准教授 (30748934)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsパッシブサンプリング / ネオニコチノイド系農薬 / 水環境監視 / 1,4-ジオキサン / 高親水性化合物 / 環境モニタリング / ネオニコチノイド / 化学物質モニタリング / 環境質定量化・予測 / 環境技術 / 環境分析
Outline of Final Research Achievements

Adsorption and permeation tests were carried out to select a suitable receiving phase and permeation phase to monitor neonicotinoid insecticides. ENVI-carb (EC) and PES membrane filter were selected as the receiving phase and permeation phase of POCIS (passive sampler). The sampling rate (Rs) of the new POCIS device was calculated by calibration tests. Static renewal experiments showed that the new POCIS device using ENVI-Carb with a PES membrane filter had 3 d (dinotefuran) to 28 d (clothianidin, imidacloprid, acetamiprid, and thiacloprid) linear range, which is longer than those of HLB POCIS (<1(dinotefuran) to 14 d). The time-weighted average concentrations in actual river water measured by the new POCIS were in good agreement with those obtained by repeated grab sampling within 30 %. Activated carbon and PTFE were selected for POCIS device to monitor 1,4-dioxane.

Academic Significance and Societal Importance of the Research Achievements

発がん性の疑われる1,4-ジオキサン、水環境中で検出頻度の高いネオニコチノイド系殺虫剤及び医薬品類など、水環境中に溶出しやすい親水性化合物の監視が求められている。本研究は、室内実験とフィールド試験を組合せて、環境監視技術として世界的に注目されているパッシブサンプリング法でこれまでモニタリングが困難であった高親水性化合物について対応できる新たなサンプラーを構築した。今後のデータの積み重ねにより、グラブサンプリングでは検出できないような短期間の流出、微量濃度の化学物質の検出が可能なパッシブサンプリング法の普及に貢献できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (13 results)

All 2020 2019 2018

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Development and Calibration of the Polar Organic Chemical Integrative Sampler (POCIS) for Neonicotinoid Pesticides2020

    • Author(s)
      Noro Kazushi、Endo Satoshi、Shikano Yohei、Banno Arisa、Yabuki Yoshinori
    • Journal Title

      Environmental Toxicology and Chemistry

      Volume: 00 Issue: 7 Pages: 1-9

    • DOI

      10.1002/etc.4729

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 新たな環境水中の農薬モニタリング手法 —水相パッシブサンプリング法が農薬モニタリングの未来を変える?—2019

    • Author(s)
      矢吹芳教
    • Journal Title

      Japanese Journal of Pesticide Science

      Volume: 44 Issue: 2 Pages: 250-251

    • DOI

      10.1584/jpestics.W19-36

    • NAID

      130007843645

    • ISSN
      2187-0365, 2187-8692
    • Year and Date
      2019-08-20
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Validation of the Application of a Polar Organic Chemical Integrative Sampler (POCIS) in Non-steady-state Conditions in Aquatic Environments2019

    • Author(s)
      Noro Kazushi、Yabuki Yoshinori、Banno Arisa、Tawa Yusuke、Nakamura Satoshi
    • Journal Title

      Journal of Water and Environment Technology

      Volume: 17 Issue: 6 Pages: 432-447

    • DOI

      10.2965/jwet.19-057

    • NAID

      130007760357

    • ISSN
      1348-2165
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mechanistic Model Describing the Uptake of Chemicals by Aquatic Integrative Samplers: Comparison to Data and Implications for Improved Sampler Configurations2019

    • Author(s)
      Endo S, Matsuura Y, Vermeirssen ELM
    • Journal Title

      Environ Sci Technol.

      Volume: 53 Issue: 3 Pages: 1482-1489

    • DOI

      10.1021/acs.est.8b06225

    • NAID

      120006783762

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019828

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 新規受容相のパッシブサンプラーによる高親水性農薬の河川水中モニタリング2020

    • Author(s)
      矢吹芳教、野呂和嗣、伴野有彩
    • Organizer
      日本農薬学会第45回大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Polar Organic Chemical Integrative Sampler (POCIS)への温度影響とその補正2020

    • Author(s)
      野呂和嗣、伴野有彩、矢吹芳教、中村智
    • Organizer
      第54回日本水環境学会年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] パッシブサンプリングとグラブサンプリングによる農薬濃度の数年分のデータ比較2020

    • Author(s)
      矢吹芳教、伴野有彩、野呂和嗣
    • Organizer
      第54回日本水環境学会年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Developing a Polar Chemical Integrative Sampler for Neonicotinoid Pesticides with New Sorbent2019

    • Author(s)
      Y. Yabuki, K. Noro, A. Banno, S. Endo
    • Organizer
      SETAC North America 40th Annual Meating
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Validation of the application of a polar organic chemical integrative sampler (POCIS) in unsteady state conditions2019

    • Author(s)
      K.Noro, A. Banno, Y. Yabuki, S. Nakamura
    • Organizer
      SETAC Ninth Biennial Meeting of SETAC Africa
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高親水性化合物のネオニコチノイド系農薬に対応したパッシブサンプラーの受容相の選定2019

    • Author(s)
      矢吹芳教、伴野有彩、野呂和嗣、遠藤智司
    • Organizer
      日本農薬学会第44回大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Developing Aquatic Integrative Passive Samplers for Neonicotinoid Pesticides: Initial Search for Suitable Sorbents and Filters2018

    • Author(s)
      Endo, S.; Shikano, Y.; Banno, A.; Yabuki, Y.
    • Organizer
      SETAC Asia-Pacific 2018 Conference, Daegu, Korea
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] “環農水研”での化学物質の新たな調査手法及び情報基盤整備に関する取組2018

    • Author(s)
      矢吹芳教
    • Organizer
      2018年度環境技術学会第18回年次大会
    • Related Report
      2018 Research-status Report 2017 Research-status Report
    • Invited
  • [Presentation] 設置期間の違いがパッシブサンプラーへの農薬の蓄積性に与える影響2018

    • Author(s)
      矢吹芳教、小野純子
    • Organizer
      第52回日本水環境学会年会
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2021-02-19  

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