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Study of transparent conductive polymer/nanocarbon hybirid actuator

Research Project

Project/Area Number 17K05983
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Naohiro Terasawa  国立研究開発法人産業技術総合研究所, 材料・化学領域, 主任研究員 (10357543)

Project Period (FY) 2017-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsactuator / アクチュエータ / 有機材料化学 / 電子・電気材料
Outline of Final Research Achievements

This research presents the development of new hybrid-type poly(3,4-ethylenedioxythiophene) (PEDOT) actuators produced, in which both electrostatic double-layer (EDLC) and faradaic capacitors (FCs) occur simultaneously. The electrochemical and electromechanical properties of PEDOT:poly(4-styrenesulfonate)(PSS):PSS/ionic liquid (IL), and PEDOT:PSS/single-walled carbon nanotubes (SWCNTs)/IL actuators were developed. It is found that the PEDOT:PSS/SWCNT/IL actuator provides a better actuation strain performance, as its electrode is an electrochemical capacitor (EC) composed of an EDLC and FC. The PEDOT:PSS polymer helps produce a high specific capacitance, actuation strain and maximum generated stress that surpass the performance of a conventional PVdF(HFP) actuator. The flexible and robust films created by the synergistic combination of PEDOT and SWCNT may therefore have significant potential as actuator materials for wearable energy-conversion devices.

Academic Significance and Societal Importance of the Research Achievements

誘電エラストマーや圧電アクチュエータが数kVの高電圧で駆動するのに対し、PEDOT・PSSハイブリッドアクチュエータは100 分の1の低電圧で駆動する。加えて、電磁アクチュエータやピエゾアクチュエータに比べ構造が単純なことから、微細化、軽量化、薄型化に適しており、イオン液体ゲルにすることにより、空気中で駆動する新規なEAP アクチュエータや人工筋肉として、センサやバルブ、スイッチ、ポンプ(工学)の他、能動カテーテルやガイドワイヤー(医療)、指触ディスプレイ(福祉)、パワーアシストスーツ(介護)等への応用が見通せた。

Report

(8 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Products Report
  • Research Products

    (24 results)

All 2023 2022 2021 2020 2019 2018 2017

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Open Access: 3 results) Presentation (8 results) (of which Int'l Joint Research: 4 results) Patent(Industrial Property Rights) (5 results)

  • [Journal Article] Nanocomposite electrodes using highly conductive sub-millimetre-long single-walled carbon nanotubes pasted with PEDOT:PSS and high-performance actuators2022

    • Author(s)
      Terasawa Naohiro
    • Journal Title

      Diamond and Related Materials

      Volume: 126 Pages: 109039-109039

    • DOI

      10.1016/j.diamond.2022.109039

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-performance TEMPO-oxidised cellulose nanofibre/PEDOT:PSS/ionic liquid gel actuators2021

    • Author(s)
      Terasawa Naohiro
    • Journal Title

      Sensors and Actuators B: Chemical

      Volume: 343 Pages: 130105-130105

    • DOI

      10.1016/j.snb.2021.130105

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of ruthenium on superior performance of cellulose nanofibers/poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate)/ruthenium oxide/ionic liquid actuators2020

    • Author(s)
      Terasawa Naohiro
    • Journal Title

      Synthetic Metals

      Volume: 261 Pages: 116306-116306

    • DOI

      10.1016/j.synthmet.2020.116306

    • Related Report
      2020 Research-status Report 2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Self-Standing High-Performance Transparent Actuator Based on Poly(dimethylsiloxane)/TEMPO-Oxidized Cellulose Nanofibers/Ionic Liquid Gel2020

    • Author(s)
      Terasawa Naohiro
    • Journal Title

      Langmuir

      Volume: 36 Issue: 22 Pages: 6154-6159

    • DOI

      10.1021/acs.langmuir.0c00559

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] High-Performance Cellulose Nanofibers, Single-Walled Carbon Nanotubes and Ionic Liquid Actuators with a Poly(vinylidene fluoride-co-hexafluoropropylene)/Ionic Liquid Gel Electrolyte Layer2019

    • Author(s)
      寺澤 直弘、安積 欣志
    • Journal Title

      RSC Advances

      Volume: 9 Pages: 8215-8221

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrochemical and electromechanical properties of high-performance fluoropolymer/ionic liquid (with wide electrochemical window of 6 V) gel hybrid actuators based on single-walled carbon nanotubes,2019

    • Author(s)
      寺澤 直弘
    • Journal Title

      DIAMOND AND RELATED MATERIALS

      Volume: 95 Pages: 77-82

    • DOI

      10.1016/j.diamond.2019.04.002

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Performance Enhancement of PEDOT:Poly(4-styrenesulfonate) Actuators by Using Ethylene Glycol2018

    • Author(s)
      寺澤 直弘、安積 欣志
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 32 Pages: 17732-17738

    • DOI

      10.1039/c8ra02714e

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Self-Standing Cellulose Nanofiber/Poly(3,4-ethylenedioxythiophene):Poly(4-styrenesulfonate)/Ionic Liquid Actuators with Superior Performance2018

    • Author(s)
      寺澤 直弘、安積 欣志,
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 58 Pages: 33149-33155

    • DOI

      10.1039/c8ra06981f

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] High-performance graphene oxide/vapor-grown carbon fiber composite polymer actuator2018

    • Author(s)
      寺澤 直弘、安積 欣志
    • Journal Title

      SENSORS AND ACTUATORS B-CHEMICAL

      Volume: 255 Pages: 2829-2837

    • DOI

      10.1016/j.snb.2017.09.100

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] High-Performance Transparent Actuator made from Poly(dimethylsiloxane)/Ionic Liquid Gel2018

    • Author(s)
      寺澤 直弘
    • Journal Title

      SENSORS AND ACTUATORS B-CHEMICAL

      Volume: 257 Pages: 815-819

    • DOI

      10.1016/j.snb.2017.11.003

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Superior Performance of PEDOT:Poly(4-styrenesulfonate)/Vapor-Grown Carbon Fibre/Ionic Liquid Actuators Exhibiting Synergistic Effects2017

    • Author(s)
      寺澤 直弘、安積 欣志
    • Journal Title

      SENSORS AND ACTUATORS B-CHEMICAL

      Volume: 248 Pages: 273-279

    • DOI

      10.1016/j.snb.2017.03.174

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] High Performance of Cellulose Nanofibers/poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate)/ ruthenium oxide/ionic liquid Actuators2019

    • Author(s)
      寺澤 直弘
    • Organizer
      Euro EAP2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] High Performance of Cellulose Nanofibers/poly(3,4-ethylenedioxy-thiophene):poly(4-styrenesulfonate)/metal oxide/ionic liquid Actuators2019

    • Author(s)
      寺澤 直弘
    • Organizer
      SEIA'2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高機能ポリシラン・イオン液体ゲル透明アクチュエータ2019

    • Author(s)
      寺澤 直弘
    • Organizer
      第28回ポリマー材料フォーラム
    • Related Report
      2019 Research-status Report
  • [Presentation] Fluoropolymer/ionic liquid (with wide electrochemical window of 6 V) gel hybrid actuators based on single-walled carbon nanotubes2019

    • Author(s)
      寺澤 直弘
    • Organizer
      第29回日本MRS年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] High-performance ionic and non-ionic fluoropolymer/ionic liquid (with quaternary cation and perfluoroalkyltrifluoroborate anion) gel hybrid actuators with electrochemical window of 6 V2018

    • Author(s)
      寺澤 直弘、安積 欣志
    • Organizer
      ANM2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrochemical and electromechanical properties of high-performance fluoropolymer/ionic liquid (with wide electrochemical window of 6 V) gel hybrid actuators based on single-walled carbon nanotubes2018

    • Author(s)
      寺澤 直弘、安積 欣志
    • Organizer
      The 29th International Conference on Diamond and Carbon Materials
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] ポリシラン・イオン液体ゲル透明アクチュエータ2018

    • Author(s)
      寺澤 直弘
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] 寺澤 直弘、安積 欣志2018

    • Author(s)
      Cellulose Nanofibers/Poly(3,4-ethylenedioxythiophene): Poly(4-styrenesulfonate)/Ionic Liquid Actuators
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Research-status Report
  • [Patent(Industrial Property Rights)] 導電性薄膜、積層体、アクチュエータ素子及びその製造方法2023

    • Inventor(s)
      寺澤直弘
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Acquisition Date
      2023
    • Related Report
      Products Report
  • [Patent(Industrial Property Rights)] 導電性薄膜、積層体、アクチュエータ素子及びその製造方法2018

    • Inventor(s)
      寺澤直弘
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-121455
    • Filing Date
      2018
    • Related Report
      2018 Research-status Report
  • [Patent(Industrial Property Rights)] 透明な積層体及び透明ゲルアクチュエータ素子並びにその製造法2017

    • Inventor(s)
      寺澤 直弘
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Acquisition Date
      2022
    • Related Report
      2022 Annual Research Report
  • [Patent(Industrial Property Rights)] 透明な積層体及び透明ゲルアクチュエータ素子並びにその製造法2017

    • Inventor(s)
      寺澤直弘
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-182297
    • Filing Date
      2017
    • Related Report
      2017 Research-status Report
  • [Patent(Industrial Property Rights)] 透明な積層体及び透明ゲルアクチュエータ素子並びにその製造法2017

    • Inventor(s)
      寺澤 直弘
    • Industrial Property Rights Holder
      国立研究開発法人産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-182297
    • Filing Date
      2017
    • Related Report
      Products Report

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Published: 2017-04-28   Modified: 2024-03-28  

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