Ferroelectrics of charge ordering type and its non-linear response in triangular mixed valence iron oxide
Project/Area Number |
18340094
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Condensed matter physics I
|
Research Institution | Okayama University |
Principal Investigator |
IKEDA Naoshi Okayama University, Dept Phys., Professor (00222894)
|
Co-Investigator(Kenkyū-buntansha) |
MORI Shigeo Osaka Prefecture University, Graduate School of Science, Professor (20251613)
YOSHII Kenji Japan Atomic Energy Agency, Quantum Bean Science Directorate, Researcher (90354985)
|
Project Period (FY) |
2006 – 2007
|
Project Status |
Completed (Fiscal Year 2007)
|
Budget Amount *help |
¥15,710,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥510,000)
Fiscal Year 2007: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2006: ¥13,500,000 (Direct Cost: ¥13,500,000)
|
Keywords | RFe2O4 / Electronic Ferroelectricity / Triangular lattice / Chrage Ordering / Charge Frustration / 電子誘電性 / RFe2O4 |
Research Abstract |
We made a research for triangular mixed valence material RFe2O4 which exhibits a polar charge ordering from the frustrated charge interaction. In this two years we had built up an air tight furnace having sample weight measurement system. From the detailed information of the sample weight change during the various heat treatment, we developed couple of method in obtaining fine sample of RFe2O4. During the course of the research we found the various electronic phases and properties for YbFe2O4, RFeCoO4, RFeCuO4 and RGaCuO4 (R.= Yb, Lu) Recently the ferroelectricity arise from the polar ordering of electrons have got much attention, however the usability for the actual application on the ferroelectric material have still been an open question. For example high electronic conductivity that possibly exist in the correlated electron system may prevent the usual application for the ferroelectrics like as insulator, charge condenser and so on. This report is one of the possibility search for s
… More
uch quests. For example in some sample treatment condition can possibly realize a high resistivity states of electronic ferroelectrics. It is also interesting that the sample having less oxygen vacancy shows high activation energy than non-stoichiometric material. It has been explained that the origin of the dielectric dispersion for Rfe_2O_4 is the boundary motion for polar domains. The higher Q value for higher stoichiometric sample indicates that the less oxygen vacant sample has larger charge ordering coherence length. Which realizes lamer scale of the collective electron motion. We emphasize that such ferroelectricity, defined by the electron distribution, is crucially different from previously known ferroelectrics. The difference in the origin of ferroelectricity may enable the development of a new class of device application in the near future. For example an anomaly report exists in electron microscope observation, which revealed an extremely small ferroelectric domain having a coherent size of 10 nm scale. This is a consistent estimate from the X-ray diffraction experiments. The superlattice profile is wider than the fundamental Bragg spot. Using the Schemer's formula the coherence length was estimated as about 10 nm from the full width of the half maximum of the peak profile in the a-b plane. In this ferroelectric the Coulomb interactions between Fe^<3+> and Fe^<2+> dominate the total energy for the presence of the domain sizes, that is decoupled from the lattice distortion. This indicates a typical property of the ferroelectricity by ordered electrons, free of lattice distortion. Future study may reveal such an extremely small ferroelectric element in high density electric devices in such extremely small domains. The applicability of electronic ferroelectric material for conventional ferroelectrics is still an open question. We should continue to find out better method to realize high stoichiometric RFe_2O_4, or also we should find out more characteristic application that may suit for such material having electric polarization and good conductivity. Less
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Report
(3 results)
Research Products
(166 results)
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Author(s)
大和田謙二, 藤井保彦, 村岡次郎, 中尾裕則, 村上洋一, 野田幸男, 大隅寛幸, 池田直, 菖蒲敬久, 礒部正彦, 上田寛
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渡邉真史, 山本健一郎.伊藤崇芳, 花咲徳亮, 池田直, 野上由夫, 豊川秀訓, 野田幸男, 稲田太一, 須子友博, 寺崎一郎.森初果, 森健彦
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Year and Date
2007-03-19
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Year and Date
2006-09-25
Description
「研究成果報告書概要(欧文)」より
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[Presentation] International Physics Olympic (IPhO) and BUTURI-CHARENGE (2006)2006
Author(s)
I., Harada, N., Ikeda, M., Sakuda, M., Mino, M., Ninomiya, M., Ariyama, T., Namiki, K., Kitahara
Organizer
Meeting of Japan Physical Society
Place of Presentation
Chiba Univ
Year and Date
2006-09-24
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Crystal Structure analysis in ferroelectric phase Tb0.3Gd0.7Mn032006
Author(s)
T., Goto, T Arima, Y., Yamazaki, N., Ikeda, H., Ohsumi, Y., Tokura
Organizer
Meeting of Japan Physical Society
Place of Presentation
Chiba Univ
Year and Date
2006-09-23
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Local structure of (Bil-xLax)FeO32006
Author(s)
Y., Yoneda, K., Yoshii, H., Saitoh, and J., Mizuki
Organizer
The 5th Asian Meeting on Ferroelectrics
Place of Presentation
Tokyo Science Univ
Year and Date
2006-09-05
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Electronic structure and magnetism of CaMnl-xRux03 thin films2006
Author(s)
K. Terai. K. Yoshii, Y. Takeda. S.l. Fujimori, K. Oowada, T. Inami. T. Okane, M. Arita, K. Shimada. H. Namatame. M. Taniguchi, K. Kobayashi, M. Kobayashi and A. Fujimori
Organizer
International Conference on Magnetism 2006
Place of Presentation
京都 京都国際会館
Year and Date
2006-08-25
Description
「研究成果報告書概要(和文)」より
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[Presentation] Fujimori Electronic structure and magnetism of CaMnl-xRuxO3 thin films2006
Author(s)
K., Terai, K., Yoshii, Y., Takeda, S.,I., Fujimori, K., Oowada, T., Inami, T., Okane, M., Arita, K., Shimada, H., Namatame, M., Taniguchi, K .,Kobayashi, M., Kobayashi, A
Organizer
International Conference on Magnetism
Place of Presentation
Kyoto International Conference Hall
Year and Date
2006-08-25
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Magnetic ordering process in the charge-frustrated ferroelectric system LuFe2O42006
Author(s)
K., Kakurai, N., Ikeda, S., Nagai, M., Matsuda, Y., Ishii, K., Ohwada, T., Inami, K., Yoshii, Y., Murakami, H., Kito, Y., Yamada
Organizer
International Conference on Magnetism
Place of Presentation
Kyoto International Conference Hall
Year and Date
2006-08-24
Description
「研究成果報告書概要(欧文)」より
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[Presentation] Doping Effect on Ferroelectric Microstructure in YMnl-xTixO32006
Author(s)
S., Mori, J., Tokunaga, Y., Horibe, T., Katsufuji, T., Asada, Y., Koyama
Organizer
The 8th Russia/CIS/Baltic/Japan Symposium on Ferroelectricity (RCBJSF-8)
Place of Presentation
Tsukuba Univ
Year and Date
2006-05-16
Description
「研究成果報告書概要(欧文)」より
Related Report
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