Electronic Dynamics Study by NMR using isotope substitution
| Project/Area Number |
18540306
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Condensed matter physics I
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| Research Institution | Hokkaido University |
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Principal Investigator |
KAWAMOTO Atsushi Hokkaido University, Faculty of Science, Associate Professor (60251691)
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| Project Period (FY) |
2006 – 2007
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| Project Status |
Completed (Fiscal Year 2007)
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| Budget Amount *help |
¥3,500,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2006: ¥2,200,000 (Direct Cost: ¥2,200,000)
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| Keywords | NMR / Electronic Dynamics / Deuterium Substitution / Nuclear Quadrupole / TTF-TCNQ / TTF=TCNQ / 重水素 |
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| Research Abstract |
In order to investigate the charge dynamics, we planned to ^2D-NMR on TTF-TCNQ salts. TTF-TCNQ is a most famous charge transfer salt, which shows CDW transition at low temperature. However there are few spectroscopic studies on the dynamics o CDW. NMR is one of the most powerful tools for magnetism. NMR also can probe the charge dynamics via nuclear quadrupole interaction. Therefore ^2D-NMR is good idea for the charge dynamics. ^2D-NMR probes the both of the magnetism and the charge. On the other hands, ^1H-NMR probes only the magnetism. Comparing the results ^2D and ^1H NMR on same sites, we can extract the information of only charge. First we synthesized the ^2D substituted TTF molecule and prepared the single crystal of TTF-TCNQ complex. We also tried to synthesize the 2D substituted TTF. We found more easy synthetic route for TCNQ-d. ^2D NMR on the complex is now in progress.
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Report
(3 results)
Research Products
(52 results)
