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Development and high strength of non-twisted CNT fiber reinforced composite material by innovative synthetic method

Research Project

Project/Area Number 18H01341
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 18010:Mechanics of materials and materials-related
Research InstitutionWaseda University

Principal Investigator

Kawada Hiroyuki  早稲田大学, 理工学術院, 教授 (20177702)

Co-Investigator(Kenkyū-buntansha) 白須 圭一  東北大学, 工学研究科, 准教授 (20757679)
荒尾 与史彦  早稲田大学, 理工学術院, 准教授 (40449335)
細井 厚志  早稲田大学, 理工学術院, 准教授 (60424800)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2020: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2019: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2018: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Keywordsカーボンナノチューブ / 強度特性 / CVD法 / 強度発現メカニズム / 分子間力 / 紡績糸 / 気相合成法 / 強化繊維 / 複合材料 / 分子動力学 / 引張強度 / 複合材料工学 / ナノカーボン材料 / 化学気相合成法
Outline of Final Research Achievements

The purpose of this study is to develop high-strength untwisted CNT yarn, and so far, we have examined CNT synthesis conditions, optimized CNT spun yarn production conditions, and increased the strength of untwisted CNT yarn by polymer impregnation (PAA / DMSO treatment). To improve the mechanical properties of untwisted CNT yarn. In addition, using thin-walled and small-diameter CNTs as raw materials, we evaluated the strength of CNT spun yarns obtained by the substrate method, evaluated various physical properties of CNT yarns produced by the wet spinning method, and examined the treatment conditions for increasing the strength. It was. We constructed a strength prediction model based on the fracture morphology of CNT yarn, evaluated its validity, and examined the conditions for increasing the strength of his CNT yarn.

Academic Significance and Societal Importance of the Research Achievements

本研究成果の学術的意義は,これまでポリアクリルニトリルを原糸材料とした炭素繊維に対して,ナノ材料である合成されたカーボンナノチューブ(CNT)を用いて新たな高強度繊維を開発し,高強度化のいくつかの手法を提案し,その強度発現メカニズムを解明することにある.これは従来の連続体力学に立脚したCNT紡績糸の強度予測が適用できる事象に加え,一方で新たに分子間力を考慮した力学モデルを援用して説明を試みる内容となっている.また,今後来るべく脱炭素社会や水素を主燃料とするパラダイムシフトに大いに貢献できる内容となっている.

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (10 results)

All 2021 2019 2018

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results)

  • [Journal Article] Functionalization and strengthening of graphitized untwisted carbon nanotube yarn with hot mixed acid treatment2019

    • Author(s)
      OKUMO Kouichi、TAKAHASHI Yui、KIM Taesung、NIKAWA Hidefumi、HOSOI Atsushi、KAWADA Hiroyuki
    • Journal Title

      Transactions of the JSME (in Japanese)

      Volume: 85 Issue: 874 Pages: 19-00029-19-00029

    • DOI

      10.1299/transjsme.19-00029

    • NAID

      130007667094

    • ISSN
      2187-9761
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of graphitization on mechanical properties of untwisted carbon nanotube yarn and its strength development mechanism2018

    • Author(s)
      金 太成、林 晏理、二川 秀史、白須 圭一、山本 剛、橋田 俊之、細井 厚志、川田 宏之
    • Journal Title

      Transactions of the JSME (in Japanese)

      Volume: 84 Issue: 860 Pages: 17-00585-17-00585

    • DOI

      10.1299/transjsme.17-00585

    • NAID

      130006726276

    • ISSN
      2187-9761
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 合成法の違いによるカーボンナノチューブを用いた高強度繊維の現状と将来展望2021

    • Author(s)
      川田宏之
    • Organizer
      SAMPE
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Reducing diameter and layers of CNTs and impregnating with PAA solution for fabrication of high strength CNT yarn2019

    • Author(s)
      Kazuyoshi Sogo, Naruki Hisaji, Kazuhiko Takahashi, Hirotaka Inoue,Yasuhiko Hayashi, Atsushi Hosoi, Hiroyuki Kawada
    • Organizer
      International Mechanical Engineering Congress & Exposition (IMECE)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selection of synthesis conditions for improving mechanical properties of untwisted CNT yarn2019

    • Author(s)
      Naruki Hisaji, Kazuyoshi Sogo, Kouichi Okumo, Kazuhiko Takahashi, Keiichi Shirasu, Atsushi Hosoi, Hiroyuki Kawada
    • Organizer
      1st Russia-Japan Joint Workshop on Composite Materials (RJCM-1)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PAN含浸と熱処理による高強度CNT糸の作製2019

    • Author(s)
      十河和嘉,林晏理,金太成,細井厚志,川田宏之
    • Organizer
      日本複合材料学会第44回日本複合材料シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effect of intermolecular force on mechanical properties of CNT/polymer composite yarn2018

    • Author(s)
      Taesung Kim, Hidefumi Nikawa, Atsushi Hosoi, Hiroyuki Kawada
    • Organizer
      The 5th International Conference on Nanomechanics and Nanocomposites (ICNN5)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CVD synthesis of few-walled carbon nanotubes for creating high-strength untwisted carbon nanotube yarn2018

    • Author(s)
      Kouichi Okumo, Tae Sung Kim, Kazuhiko Takahashi, Atsushi Hosoi, Hiroyuki Kawada
    • Organizer
      2018 2nd International Conference on Mechanical Engineering and Applied Composite Materials (MEACM2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高強度無撚 CNT 糸の創製に向けた薄層 CNT 合成条件の検討2018

    • Author(s)
      奥茂洸一,金太成,高橋和彦,細井厚志,川田宏之
    • Organizer
      日本機械学会 機械材料・材料加工部門 第26回機械材料・材料加工技術講演会(M&P2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 無燃CNT糸の高強度化に向けた合成条件の選定及び機械的特性評価2018

    • Author(s)
      久司成輝,奥茂洸一,金太成,高橋和彦,細井厚志,川田宏之
    • Organizer
      第10回日本複合材料会議(JCCM-10)
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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