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Development of synthesis processes of raw material and carbon fiber composite material contributing to environmental conservation

Research Project

Project/Area Number 18H01777
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27020:Chemical reaction and process system engineering-related
Research InstitutionNagoya University

Principal Investigator

Yamamoto Tetsuya  名古屋大学, 工学研究科, 准教授 (10432684)

Co-Investigator(Kenkyū-buntansha) 入澤 寿平  名古屋大学, 工学研究科, 助教 (30737333)
荒川 賢治  広島大学, 統合生命科学研究科(先), 准教授 (80346527)
Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2020: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2019: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2018: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
KeywordsCFRTP / ポリマーコロイド / ソープフリー乳化重合 / 低環境負荷型プロセス / 界面接着性 / マルチマテリアル / 微生物毒性 / 高分子中空微粒子 / 複合材料 / 延性破壊 / 破壊挙動 / 電気泳動 / 表面修飾 / 分散安定性 / 高分子コロイド / リサイクル / マイクロプラスチック汚染 / 炭素繊維 / シリカナノコロイド / 界面制御 / バイオアッセイ試験
Outline of Final Research Achievements

To enhance the strength of carbon fiber reinforced thermoplastic resin (CFRTP), it is necessary to improve the surface adhesion between the carbon fiber (CF) and thermoplastic resin (TP) and TP resin impregnation property. Surface modification technique for CF was developed. To improve the recyclability of CFRTP, we succeeded in maintaining the strength of recycled CF by surface modification CF with silica nanocolloid with heat-resistance. To make CFRTP multi-material, the metal surface was modified with TP colloid to improve the surface adhesion between the metal and CFRTP. Regarding the environmental load of the effluents prepared from these TP colloidal materials, it was found that polymers containing cationic aromatic rings with a molecular weight of less than 1000 show microbial toxicity.

Academic Significance and Societal Importance of the Research Achievements

二酸化炭素排出量削減に向けて,輸送機の軽量化が必要不可欠である。本技術は炭素繊維と熱可塑性樹脂の界面に着目し,熱可塑性樹脂成分を含む高分子コロイド溶液を調製することで界面特性を強化することに成功した。本技術開発による軽量・高強度・リサイクル性に優れたCFRTPは時代の要請に応える材料であると言える。現在,最大曲げ応力で800MPaを示すCFRTPに更に高強度・高性能・高付加価値を付与させることで社会実装が加速度的に進むと考えられる。また高分子コロイドを調製する際にも環境負荷に注意を払い,持続可能な発展を可能にするプロセス設計の指針を本研究成果から与えることができたと考えられる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (65 results)

All 2021 2020 2019 2018 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Open Access: 1 results) Presentation (41 results) (of which Int'l Joint Research: 11 results,  Invited: 3 results) Book (8 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis of Polystyrene Nanoparticles using Thermally Reversible Hydrogel as Polymerization Field2021

    • Author(s)
      Yamada Naoki、Ouchi Shinya、Yamamoto Tetsuya
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 47 Issue: 1 Pages: 11-16

    • DOI

      10.1252/kakoronbunshu.47.11

    • NAID

      130007970881

    • ISSN
      0386-216X, 1349-9203
    • Year and Date
      2021-01-20
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Creating a laminated carbon fiber-reinforced thermoplastic using polypropylene and nylon with a polypropylene colloid2021

    • Author(s)
      Yamamoto Tetsuya、Ota Yusuke
    • Journal Title

      Composite Structures

      Volume: 255 Pages: 113038-113038

    • DOI

      10.1016/j.compstruct.2020.113038

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Making hollows using nitrogen gas emitted by the decomposition of VAm-110 in polystyrene particles2020

    • Author(s)
      Yamamoto Tetsuya、Tsutsumi Kazuya、Kawai Yusuke
    • Journal Title

      Polymer

      Volume: 202 Pages: 122761-122761

    • DOI

      10.1016/j.polymer.2020.122761

    • NAID

      120006941042

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Size Control of Polystyrene Nanoparticles Synthesized in Melamine Foam2020

    • Author(s)
      Ouchi Shinya、Yamada Naoki、Yamamoto Tetsuya
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 59 Issue: 40 Pages: 17927-17933

    • DOI

      10.1021/acs.iecr.0c03560

    • NAID

      120006957732

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of porous carbon hollow particles maintaining their structure using hyper-cross-linked Poly(St-DVB) hollow particles2020

    • Author(s)
      Kawai Yusuke、Yamamoto Tetsuya
    • Journal Title

      Advanced Powder Technology

      Volume: 31 Issue: 2 Pages: 614-620

    • DOI

      10.1016/j.apt.2019.11.016

    • NAID

      120006812137

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved metal-resin adhesion via electroplating-induced polymer particle adsorption2020

    • Author(s)
      Ota Yusuke、Yamamoto Tetsuya
    • Journal Title

      Surface and Coatings Technology

      Volume: 388 Pages: 125591-125591

    • DOI

      10.1016/j.surfcoat.2020.125591

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between dispersion-forming capability of poly(4-vinylaniline) colloids and antimicrobial activity2020

    • Author(s)
      Tetsuya Yamamoto, Ryo Furuta, Kenji Arakawa, Aiko Teshima
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: 596 Pages: 124736-124736

    • DOI

      10.1016/j.colsurfa.2020.124736

    • NAID

      120006884958

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Preparation of PVA/Polymer Colloid nanocomposite Hydrogel Using PS-PNVA Particles2019

    • Author(s)
      Naoya Toyoda, Tetsuya Yamamoto, Kenji Arakawa, Aiko Teshima
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 4 Pages: 378-381

    • DOI

      10.1246/cl.181042

    • NAID

      130007624440

    • ISSN
      0366-7022, 1348-0715
    • Year and Date
      2019-04-05
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of bending strength, thermal stability and recyclability of carbon-fiber-reinforced thermoplastics by using silica colloids2019

    • Author(s)
      Yamamoto Tetsuya、Yabushita Sho、Irisawa Toshihira、Tanabe Yasuhiro
    • Journal Title

      Composites Science and Technology

      Volume: 181 Pages: 107665-107665

    • DOI

      10.1016/j.compscitech.2019.05.022

    • NAID

      120006765142

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controlling Porous Hollow Silica Particles through Soap-free Emulsion Polymerization with Polymer Core Particles2019

    • Author(s)
      Yamamoto Tetsuya、Takahashi Yuya
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 10 Pages: 1229-1231

    • DOI

      10.1246/cl.190513

    • NAID

      130007724079

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of the morphology and size of polystyrene synthesized through soap-free emulsion polymerization on antimicrobial activity2019

    • Author(s)
      Tetsuya Yamamoto, Kenji Arakawa, Ryo Furuta, Aiko Teshima
    • Journal Title

      Materials Today Communications

      Volume: 20 Pages: 100572-100572

    • DOI

      10.1016/j.mtcomm.2019.100572

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Initiator Charge on Dispersion Stability of Polymer Particles Formed by Soap-free Emulsion Polymerization of 4-Vinylaniline or 4-Vinylpyridine2019

    • Author(s)
      Yamamoto Tetsuya、Furuta Ryo、Kawai Yusuke
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 3 Pages: 208-210

    • DOI

      10.1246/cl.180917

    • NAID

      130007607801

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Antimicrobial activities of polymers synthesized through soap-free emulsion polymerization using a cationic initiator and styrene derivative monomers2018

    • Author(s)
      Tetsuya Yamamoto, Kenji Arakawa, Ryo Furuta, Aiko Teshima
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 11 Pages: 1402-1404

    • DOI

      10.1246/cl.180762

    • NAID

      130007504970

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] CFRTPの力学物性を向上させる構造設計2021

    • Author(s)
      吉良亘平,金スルチャン,山本徹也
    • Organizer
      第23回化学工学会学生発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] メラミンフォームを反応場とした 高分子ナノ粒子のサイズコントロール2021

    • Author(s)
      大内慎也,山田尚輝,山本徹也
    • Organizer
      化学工学会 第86年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] メチルセルロースゲルを反応場とした高分子ナノ粒子の合成2021

    • Author(s)
      山本徹也,山田尚輝
    • Organizer
      化学工学会 第86年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] シリカコロイドを利用したCFRTPのマテリアルリサイクル2020

    • Author(s)
      山本徹也,薮下翔
    • Organizer
      2020年度粉体工学会春期研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] シリカナノコロイドを利用したCFRTPのマテリアルリサイクル2020

    • Author(s)
      山本徹也,薮下翔
    • Organizer
      繊維学会年次大会2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 粒子内で発生した窒素ガスによる高分子微粒子の中空化2020

    • Author(s)
      堤和也,山本徹也
    • Organizer
      化学工学会 第51回秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ナノボイドがCFRTPの力学特性に及ぼす影響2020

    • Author(s)
      寺田悠悟,山本徹也
    • Organizer
      化学工学会 第51回秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 高分子微粒子の中空化と炭素化2020

    • Author(s)
      山本徹也,河合優介
    • Organizer
      化学工学会 第51回秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ラジカルを利用した炭素繊維と熱可塑性樹脂間の接着性向上2020

    • Author(s)
      金スルチャン,山本徹也
    • Organizer
      2020年 繊維学会秋季研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 三次元網目構造を反応場とした高分子ナノ粒子のサイズコントロール2020

    • Author(s)
      大内慎也,山田尚輝,山本徹也
    • Organizer
      2020年度粉体工学会秋期研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 熱可逆性ハイドロゲルを重合場としたポリスチレンナノ粒子の合成2020

    • Author(s)
      山田尚輝,大内慎也,山本徹也
    • Organizer
      化学工学会広島大会2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 高分子を構成する官能基が微粒子分散安定性,微生物毒性に与える影響2020

    • Author(s)
      山本徹也,古田凌,荒川賢治
    • Organizer
      化学工学会 第85年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Enhancement of Bending Strength, Thermal Stability and Recyclability of Carbon-Fiber-Reinforced Thermoplastics by Using Silica Nano Colloids2020

    • Author(s)
      Tetsuya Yamamoto, Sho Yabushita
    • Organizer
      44th International Conference on Advanced Ceramics and Composites (ICACC- 2020)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] コロイドを利用したカーボンナノチューブの樹脂中分散2019

    • Author(s)
      山本徹也,豊田直也
    • Organizer
      第57回粉体に関する討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effect of Functional Group of Polymer Particles on Dispersion Stability and Antimicrobial Activity2019

    • Author(s)
      Tetsuya Yamamoto, Ryo Furuta, and Kenji Arakawa
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Carbon Hollow Particles by Template Free Method2019

    • Author(s)
      Yusuke Kawai, Tetsuya Yamamoto
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dispersion of nano-materials in polymer composite materials2019

    • Author(s)
      Tetsuya YAMAMOTO, Yuya TAKAHASHI, and Naoya TOYODA
    • Organizer
      18th APCChE Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of New Synthesis Method for Hollow Polymer Particles2019

    • Author(s)
      Yusuke Kawai, Tetsuya Yamamoto
    • Organizer
      18th APCChE Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Colloidal Technique for Applying CFRTP to Multi-Material structure2019

    • Author(s)
      Yusuke Ota, Tetsuya Yamamoto
    • Organizer
      18th APCChE Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子中空微粒子の炭素化による多孔質炭素中空微粒子の合成2019

    • Author(s)
      河合優介,山本徹也
    • Organizer
      粉体工学会秋期研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] コロイド技術を利用したマルチマテリアル構造用途のCFRTP作製2019

    • Author(s)
      太田悠介,山本徹也
    • Organizer
      粉体工学会秋期研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] シリカコロイドを利用したCFRTPのマテリアルリサイクル2019

    • Author(s)
      山本徹也, 薮下翔
    • Organizer
      第44回複合材料シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高分子を構成する官能基が微粒子分散安定性,微生物に与える影響2019

    • Author(s)
      山本徹也, 古田凌, 高橋侑椰, 荒川賢治
    • Organizer
      粉体工学会春期研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] コロイドテクニックによる 炭素材料/熱可塑性樹脂界面物性の強化2019

    • Author(s)
      山本徹也
    • Organizer
      第5回 スマート材料アクチュエータ実用化研究会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリマー微粒子の界面設計による低環境負荷型社会の構築2019

    • Author(s)
      山本徹也
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] コロイド技術を利用したCFRTPのマテリアルリサイクル2019

    • Author(s)
      山本徹也, 薮下翔
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 両親媒性モノマーを用いた多孔質中空シリカ粒子の調製2018

    • Author(s)
      山本徹也, 高橋侑椰
    • Organizer
      2018年度 粉体工学会秋期研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 分散安定性を維持した高分子微粒子表面ゾルゲル反応のための表面設計2018

    • Author(s)
      山本徹也, 高橋侑椰
    • Organizer
      第20回高分子ミクロスフェア討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 分散安定性を維持した高分子微粒子表面ゾル-ゲル反応のための微粒子設計2018

    • Author(s)
      山本徹也, 高橋侑椰
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Enhancement of mechanical properties of carbon fiber reinforced thermoplastic using colloidal techniques2018

    • Author(s)
      etsuya Yamamoto, Katsumasa Uematsu, Syo Yabushita
    • Organizer
      Metal Forming 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子コロイドによる炭素繊維/熱可塑性樹脂界面物性の強化2018

    • Author(s)
      山本徹也
    • Organizer
      第4回複合材料界面科学研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子コロイドを利用した高強度CFRTPの作製2018

    • Author(s)
      山本徹也, 上松克匡
    • Organizer
      平成30年度繊維学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Preparation of PVA hydrogel in polymer colloid solution for biomedical materials2018

    • Author(s)
      Naoya Toyoda, Tetsuya Yamamoto
    • Organizer
      13th Korea-Japan Symposium on Materials and Interfaces
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reduction of environmental load in activated carbon production process from waste biomass2018

    • Author(s)
      Yuta Makino, Tetsuya Yamamoto
    • Organizer
      13th Korea-Japan Symposium on Materials and Interfaces
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Novel synthesis method of nonspherical polymer particles2018

    • Author(s)
      Yusuke Kawai, Tetsuya Yamamoto
    • Organizer
      13th Korea-Japan Symposium on Materials and Interfaces
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 木質バイオマス由来の活性炭製造プロセスにおける環境負荷の低減化の検討2018

    • Author(s)
      牧野雄太,山本徹也
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 炭素繊維-PPの界面特性を向上するコロイド技術2018

    • Author(s)
      太田悠介,山本徹也
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] コロイド技術による CFRTPのリサイクル性の向上2018

    • Author(s)
      薮下翔,山本徹也,上松克匡
    • Organizer
      化学工学会室蘭大会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高分子コロイドを利用したCFRTPのマテリアルリサイクル2018

    • Author(s)
      薮下翔,上松克匡,山本徹也
    • Organizer
      第20回高分子ミクロスフェア討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高機能複合材料のための高分子ミクロスフェアの帯電制御2018

    • Author(s)
      河合優介,山本徹也
    • Organizer
      第20回高分子ミクロスフェア討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 廃棄バイオマス由来の活性炭製造プロセスの環境負荷低減の検討2018

    • Author(s)
      牧野雄太,山本徹也
    • Organizer
      第56回炭素材料夏季セミナー
    • Related Report
      2018 Annual Research Report
  • [Book] CFRP/CFRTPの界面制御、成形加工技術と部材応用2020

    • Author(s)
      山本徹也ら
    • Total Pages
      586
    • Publisher
      株式会社技術情報協会
    • ISBN
      9784861048111
    • Related Report
      2020 Annual Research Report
  • [Book] ラジカル重合を中心とした ポリマー・微粒子・コーティング材の 合成,応用,トラブル対策2020

    • Author(s)
      山本 徹也,他
    • Total Pages
      658
    • Publisher
      技術情報協会
    • ISBN
      9784861047763
    • Related Report
      2019 Annual Research Report
  • [Book] 炭素繊維およびその繊維複合材料における分析試験,評価解析に関する最新事例集2019

    • Author(s)
      山本 徹也,他
    • Total Pages
      612
    • Publisher
      技術情報協会
    • ISBN
      9784861047527
    • Related Report
      2019 Annual Research Report
  • [Book] ナノ粒子塗工液の調整とコーティング技術2019

    • Author(s)
      山本 徹也,他
    • Total Pages
      650
    • Publisher
      技術情報協会
    • ISBN
      486104751X
    • Related Report
      2019 Annual Research Report
  • [Book] 分離プロセスの最適化とスケールアップの進め方2019

    • Author(s)
      山本 徹也,他
    • Total Pages
      600
    • Publisher
      技術情報協会
    • ISBN
      9784861047664
    • Related Report
      2019 Annual Research Report
  • [Book] 炭素繊維・炭素繊維複合材料の未来2018

    • Author(s)
      山本 徹也,他
    • Total Pages
      342
    • Publisher
      S&T出版
    • ISBN
      9784907002749
    • Related Report
      2018 Annual Research Report
  • [Book] 防汚・防水・防曇性向上のための材料とコーティング,評価・応用2018

    • Author(s)
      山本 徹也,他
    • Total Pages
      584
    • Publisher
      技術情報協会
    • ISBN
      9784861047183
    • Related Report
      2018 Annual Research Report
  • [Book] 粉体の表面処理・複合化技術集大成 -基礎から応用まで-2018

    • Author(s)
      山本 徹也,他
    • Total Pages
      752
    • Publisher
      株式会社テクノシステム
    • Related Report
      2018 Annual Research Report
  • [Remarks] 発表論文

    • URL

      http://www.material.nagoya-u.ac.jp/Tanabe_Yamamoto_Lab/paper.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 研究成果発表論文リスト

    • URL

      http://www.material.nagoya-u.ac.jp/Tanabe_Yamamoto_Lab/paper.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 高分子化合物の製造方法、多孔質体、及び高分子化合物の粒子2020

    • Inventor(s)
      山本徹也, 大内慎也, 山田尚輝
    • Industrial Property Rights Holder
      山本徹也, 大内慎也, 山田尚輝
    • Industrial Property Rights Type
      特許
    • Filing Date
      2020
    • Related Report
      2020 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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