• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Preparation, structure and catalysis of metal nanosheets intercalated graphite layers

Research Project

Project/Area Number 18H01782
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionIwate University

Principal Investigator

Shirai Masayuki  岩手大学, 理工学部, 教授 (70250850)

Co-Investigator(Kenkyū-buntansha) 七尾 英孝  岩手大学, 理工学部, 准教授 (50312509)
Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2021: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2020: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2019: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2018: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywords黒鉛層間化合物 / 金属ナノシート / ナノシート
Outline of Final Research Achievements

Graphite-intercalated noble metal particles (M-GIC) were obtained by the hydrogen reduction of metal chloride intercalated between graphite layers, the latter was prepared by the treatment of the mixture of metal chloride and graphite powder under chlorine atmosphere. Two-dimensional platinum nanosheets with 1-3 nm thickness and 5-300 nm width were formed between graphite layers. Iridium nanodisks with 1-3 nm thickness and 1-15 nm diameter, and spherical palladium nano particles with diameter 2 nm were obtained between graphite layers. The noble metal particles between the graphite layers showed higher selectivity and activity than those on the graphite surface in cinnamaldehyde hydrogenation.

Academic Significance and Societal Importance of the Research Achievements

医薬品や高分子などの化学原料は石油から合成されている。より高効率でかつ選択的に化学反応を進行させるために担持金属触媒が広く用いられている。担持金属触媒では金属微粒子の形状やサイズがその触媒作用(活性、選択性、耐久性)と密接に関係している。換言すれば担持金属触媒の微粒子の設計が化学反応の制御につながる。本研究では黒鉛層間を利用して活性、選択性が高いナノサイズの二次元微粒子の合成に成功した。本研究により得られた知見は、化学工業プロセス用触媒開発に大きく貢献するものである。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (33 results)

All 2021 2020 2019 2018 Other

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results) Presentation (27 results) (of which Int'l Joint Research: 5 results,  Invited: 5 results) Remarks (1 results)

  • [Journal Article] Platinum Nanosheets Intercalated into Natural and Artificial Graphite Powders2021

    • Author(s)
      M.Shirai, K.Kubo, M.Sodeno, and H.Nanao,
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 16 Issue: 15 Pages: 2035-2040

    • DOI

      10.1002/asia.202100504

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Structural Characterization of Platinum Nanosheets Intercalated between Graphite Powder with High Surface Area2021

    • Author(s)
      M.Sodeno, S.Kato, H.Nanao, and M.Shirai
    • Journal Title

      Catalysis Today

      Volume: 375 Pages: 48-55

    • DOI

      10.1016/j.cattod.2020.04.038

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Graphite Intercalated Iridium Nanodisks for Cinnamaldehyde Hydrogenation2019

    • Author(s)
      Kato Shusuke、Nanao Hidetaka、Shirai Masayuki
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 10 Pages: 1262-1265

    • DOI

      10.1246/cl.190527

    • NAID

      130007724076

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen reduction and chloride oxidation behaviors of platinum species between graphite interlayer speces2019

    • Author(s)
      Masayuki Shirai, Yusuke Yamazaki, Kazuki Takahashi, and Hidetaka Nanao
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 9 Pages: 1094-1096

    • DOI

      10.1246/cl.180484

    • NAID

      130007472086

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum Nanosheets between Graphite Layers2019

    • Author(s)
      Masayuki SHIRAI
    • Journal Title

      The Chemical record

      Volume: 印刷中 Issue: 7 Pages: 1263-1271

    • DOI

      10.1002/tcr.201800098

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Iridium nano disks intercalated between graphite layers2021

    • Author(s)
      Tomoki Sobu, Mika Sodeno, Hidetaka Nanao and Masayuki Shirai
    • Organizer
      Pacifichem2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structure and Catalysis of Two-dimensional Platinum Nano Sheets between Graphite Layers2021

    • Author(s)
      Mika Sodeno, Hidetaka Nanao, and Masayuki Shirai
    • Organizer
      Pacifichem2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 黒鉛層間ルテニウムナノシートの調製2021

    • Author(s)
      工藤さくら, 蘇武智樹, 林滉太, 谷口賢吉, Etty Kusumawati, 七尾英孝, 白井誠之
    • Organizer
      令和3年度化学系学協会東北大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Structure and Catalysis of Two-dimensional Metal Nano Particles Intercalated between Graphite Layers2020

    • Author(s)
      M.Shirai
    • Organizer
      International Webinar on Industrial Catalysis
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 黒鉛層間パラジウムナノ粒子の調製およびシンナムアルデヒド水素化反応2020

    • Author(s)
      袖野美果,七尾英孝,白井誠之
    • Organizer
      触媒学会第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 黒鉛層間二次元金属ナノ粒子の調製と触媒利用2020

    • Author(s)
      白井誠之
    • Organizer
      2020年度 第3回 CPC研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] PREPARATION AND HYDROGENAION PERFORMANCE OF METAL NANO SHEETS INTERCALATED BETWEEN GRAPHITE LAYERS2019

    • Author(s)
      Masayuki SHIRAI
    • Organizer
      The 8th Asia Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure and Catalysis of Two-dimensional Metal Nanoparticles between Graphite Layers2019

    • Author(s)
      Masayuki SHIRAI
    • Organizer
      A Workshop on "Green Synthesis and Catalysis Technology
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 黒鉛層間イリジウム微粒子の構造と シンナムアルデヒドの水素化反応活性2019

    • Author(s)
      加藤嵩介、七尾英孝、白井誠之
    • Organizer
      触媒学会第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation and structure of rhodium-graphite composite2019

    • Author(s)
      蘇武智樹,袖野美果,七尾英孝,白井誠之
    • Organizer
      2019年度 化学系学協会東北大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation and structure of ruthenium-graphite composite2019

    • Author(s)
      林滉太,七尾英孝,白井誠之
    • Organizer
      2019年度 化学系学協会東北大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation and Cinnamaldehyde Hydrogenation Performance of Platinum Nanosheets Between Graphite Layer2019

    • Author(s)
      Mika Sodeno, Kota Hayashi, Shusuke Kato, Yusuke Yamazaki, Hidetaka Nanao, and Masayuki Shirai
    • Organizer
      Recent Progress in Graphene & 2D Materials Research
    • Related Report
      2019 Annual Research Report
  • [Presentation] Two-dimensional Platinum Nanosheets Between Graphite Layer2019

    • Author(s)
      Masayuki Shirai, Mika Sodeno, Kota Hayashi, Shusuke Kato, Yusuke Yamazaki, and Hidetaka Nanao
    • Organizer
      Recent Progress in Graphene & 2D Materials Research
    • Related Report
      2019 Annual Research Report
  • [Presentation] 黒鉛層間金属パラジウム粒子の調製およびキャラクタリゼーション2019

    • Author(s)
      袖野美果, 七尾英孝, 白井誠之
    • Organizer
      第46回炭素材料学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 黒鉛層間における白金種の還元凝集と酸化分散挙動2019

    • Author(s)
      白井誠之, 袖野美果, 山崎悠輔, 七尾英孝
    • Organizer
      第46回炭素材料学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 黒鉛小片を利用した白金ナノシートの調製、構造、水素化触媒2019

    • Author(s)
      袖野美果,七尾英孝,白井誠之
    • Organizer
      第10回福島地区CEセミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] 黒鉛層間白金ナノシート微粒子の調製と構造2019

    • Author(s)
      袖野美果,加藤嵩介,七尾英孝,白井誠之
    • Organizer
      表面技術協会 東北支部講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 黒鉛層間を利用した二次元微粒子の調製と触媒利用2019

    • Author(s)
      白井誠之
    • Organizer
      2019年度千葉大学ソフト分子活性化セミナー
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Preparation and structure of platinum-graphene composite2018

    • Author(s)
      袖野美果, 加藤嵩介, 山崎悠輔, 七尾英孝, 白井誠之
    • Organizer
      平成30年度 化学系学協会東北大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Preparation and structure of gold-graphite composite2018

    • Author(s)
      林滉太, 加藤嵩介, 山崎悠輔, 七尾英孝, 白井誠之
    • Organizer
      平成30年度 化学系学協会東北大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 白金-黒鉛層間化合物の調製条件とシンナムアルデヒド水素化反応活性2018

    • Author(s)
      山崎悠輔, 七尾英孝, 白井誠之
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] イリジウム-黒鉛複合物の調製条件とシンナムアルデヒド水素化反応活性2018

    • Author(s)
      加藤嵩介, 七尾英孝, 白井誠之
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] グラファイト小片を用いた白金-黒鉛層間化合物の調製およびキャラクタリゼーション2018

    • Author(s)
      袖野美果, 七尾英孝, 白井誠之
    • Organizer
      第45回炭素材料学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 黒鉛層間における金微粒子形成2018

    • Author(s)
      林滉太, 七尾英孝, 白井誠之
    • Organizer
      第45回炭素材料学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Cinnamaldehyde hydrogenation over platinum nanosheets intercalated graphite2018

    • Author(s)
      Masayuki SHIRAI
    • Organizer
      International Symposium on Catalysis and Fine Chemicals
    • Related Report
      2018 Annual Research Report
  • [Presentation] 黒鉛担持イリジウム微粒子の構造とシンナムアルデヒド水素化反応2018

    • Author(s)
      加藤嵩介, 七尾英孝, 白井誠之
    • Organizer
      平成30年度日本表面真空学会東北・北海道支部学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 黒鉛小片を用いた黒鉛層間白金ナノシートの調製2018

    • Author(s)
      袖野美果, 七尾英孝, 白井誠之
    • Organizer
      平成30年度日本表面真空学会東北・北海道支部学術講演会
    • Related Report
      2018 Annual Research Report
  • [Remarks] 表面反応化学研究室

    • URL

      http://www.chem.iwate-u.ac.jp/labo_web/inorg_reaction/top.html

    • Related Report
      2021 Annual Research Report 2020 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2023-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi