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Control of Molecular Arrangement in Crystals and Functional Exploration Using Supramolecular Structures

Research Project

Project/Area Number 18H01949
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 32020:Functional solid state chemistry-related
Research InstitutionHokkaido University

Principal Investigator

Nakamura Takayoshi  北海道大学, 電子科学研究所, 教授 (60270790)

Project Period (FY) 2018-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2021: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2020: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2019: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2018: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywords超分子 / 誘電性 / 極性結晶 / 磁性 / マルチフェロイック / プロトン移動
Outline of Final Research Achievements

In crystalline molecular materials, not only the structure and electronic state of individual molecules, but also the molecular arrangement within the crystal is the root of functional expression. The molecular arrangement within a crystal is fundamentally determined by intermolecular interactions. Supramolecular structures are generated when multiple molecules assemble through intermolecular interactions. Therefore, it is natural to design crystals using supramolecular structures as a starting point. In this study, we constructed a dynamic space of molecules using extremely flexible supramolecular structures while utilizing the symmetry of crystals, and developed functionalities, such as ferroelectricity, that are manifested by the dynamic processes of molecules in crystals. The validity and universality of this approach were clearly demonstrated.

Academic Significance and Societal Importance of the Research Achievements

分極反転を伴う強誘電転移、結晶内でのプロトン移動に基づくイオン伝導、結晶内でのトポケミカル反応による絶対不斉合成、固相フォトクロミズムなど、結晶内のイオンや分子の動的過程に着目した機能開拓は極めて重要な科学技術分野を形成する。これら機能の発現には、結晶内において分子やイオンの動的な空間を確保する必要があり、物質開発のネックとなっている。本研究は、フレキシブルな超分子構造を利用して、動的空間を有する分子集合構造を結晶内において自在に構築し、結晶の対称性と結晶内での分子の動的過程を制御すできることを示した。本手法により、誘電性・磁性・光機能等、多様な物性・機能を開拓することが可能となる。

Report

(5 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report

Research Products

(50 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (39 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 39 results,  Open Access: 31 results) Presentation (9 results) (of which Int'l Joint Research: 9 results,  Invited: 9 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] 武漢紡織大学(中国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Two-dimensional Porous Framework Assembled through Hydrogen-bonds and Dipole-dipole Interactions2021

    • Author(s)
      Yang Zhuxi、Moriyama Ayana、Oketani Ryusei、Nakamura Takayoshi、Hisaki Ichiro
    • Journal Title

      Chem. Lett.

      Volume: 50 Issue: 11 Pages: 1909-1912

    • DOI

      10.1246/cl.210465

    • NAID

      130008113757

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal Structures and Physical Properties of (M+)(Crown Ethers)x(TCNQ)y Salts with M+ = Li+, Na+, K+, Rb+, and Cs+2021

    • Author(s)
      Kohei Sambe, Norihisa Hoshino, Takashi Takeda, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      Crystal Growth & Design

      Volume: 21 Pages: 5928-5942

    • DOI

      10.1021/acs.cgd.1c00812

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal structure of a 1,6-bis(phenylethynyl)pyrene-based cyclophane that exhibits mechanochromic luminescence2021

    • Author(s)
      Shimizu Shohei、Thazhathethil Shakkeeb、Takahashi Kiyonori、Nakamura Takayoshi、Sagara Yoshimitsu
    • Journal Title

      Molecular Systems Design & Engineering

      Volume: 6 Pages: 1039-1046

    • DOI

      10.1039/d1me00131k

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dipole fluctuation and structural phase transition in hydrogen-bonding molecular assemblies of mononuclear CuII complexes with polar fluorobenzoate ligands2021

    • Author(s)
      Takahashi Kiyonori、Miyazaki Yuji、Noro Shin-ichiro、Nakano Motohiro、Nakamura Takayoshi、Akutagawa Tomoyuki
    • Journal Title

      Dalton Transactions

      Volume: 50 Pages: 13680-13685

    • DOI

      10.1039/d1dt02118d

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A proton conductive hydrogen-bonded framework incorporating 18-crown-6-ether and dicarboxy-o-terphenyl moieties2021

    • Author(s)
      Chen, Xin; Takahashi, Kiyonori; Kokado, Kenta; Nakamura, Takayoshi; Hisaki, Ichiro
    • Journal Title

      Materials Advances

      Volume: 2 Pages: 5639-5644

    • DOI

      10.1039/d1ma00411e

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Hydrogen-Bonded Organic Framework Based on Pyrazinopyrazine2021

    • Author(s)
      Ji, Qin; Takahashi, Kiyonori ; Noro, Shin-ichiro ; Ishigaki, Yusuke ; Kokado, Kenta ; Nakamura, Takayoshi; Hisaki, Ichiro
    • Journal Title

      Crystal Growth & Design

      Volume: 21 Pages: 4656-4664

    • DOI

      10.1021/acs.cgd.1c00506

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Molecular motion of halogenated ethylammonium/[18]crown-6 supramolecular ions in nickel dithiolate magnetic crystals2021

    • Author(s)
      Hasuo Naohiro、Takahashi Kiyonori、Hisaki Ichiro、Kokado Kenta、Nakamura Takayoshi
    • Journal Title

      CrystEngComm

      Volume: in press Pages: 2756-2763

    • DOI

      10.1039/d1ce00253h

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Substituent Effect on Molecular Motions of m-Halogenated Anilinium/Dibenzo[18]crown-6 Supramolecular Cations in [Ni(dmit)2]- Crystals2021

    • Author(s)
      Kubo Kazuya、Takahashi Kiyonori、Nakagawa Shota、Sakai Ken-ichi、Noro Shin-ichiro、Akutagawa Tomoyuki、Nakamura Takayoshi
    • Journal Title

      Crystal Growth Design

      Volume: 21 Pages: 2340-2347

    • DOI

      10.1021/acs.cgd.0c01739

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Temporarily Pore-Openable Porous Coordination Polymer for Guest Adsorption/Desorption2021

    • Author(s)
      Noro Shin-ichiro、Meng Yu、Suzuki Kazushige、Sugiura Minori、Hijikata Yuh、Pirillo Jenny、Zheng Xin、Takahashi Kiyonori、Nakamura Takayoshi
    • Journal Title

      Inorganic Chemistry

      Volume: 60 Pages: 4531-4538

    • DOI

      10.1021/acs.inorgchem.0c03420

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Gas sorption of nano-porous supramolecules formed by multi-hydrogen bonded coordination capsules2021

    • Author(s)
      Tadokoro Makoto、Machida Hironobu、Toyofuku Ryuji、Murakami Megumi、Kamebuchi Hajime、Isoda Kyosuke、Kobayashi Fumiya、Takahashi Kiyonori、Noro Shin'ichiro、Nakamura Takayoshi
    • Journal Title

      Chemical Communications

      Volume: 57 Pages: 2249-2252

    • DOI

      10.1039/d0cc07869g

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione2021

    • Author(s)
      Shivakumar Kilingaru I.、Noro Shin-ichiro、Yamaguchi Yuna、Ishigaki Yusuke、Saeki Akinori、Takahashi Kiyonori、Nakamura Takayoshi、Hisaki Ichiro
    • Journal Title

      Chemical Communications

      Volume: 57 Pages: 1157-1160

    • DOI

      10.1039/d0cc07776c

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Two-step mechanoresponsive luminescence and mechanical stimuli-induced release of small molecules exhibited by a luminescent cyclophane2021

    • Author(s)
      Sagara Yoshimitsu、Takahashi Kiyonori、Seki Atsushi、Muramatsu Tatsuya、Nakamura Takayoshi、Tamaoki Nobuyuki
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 9 Pages: 1671-1677

    • DOI

      10.1039/d0tc04853d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Nonradiative Energy Transfer through Distributed Bands in Piezochemically Synthesized Cesium and Formamidinium Lead Halide Perovskites2020

    • Author(s)
      Sankaramangalam Balachandran Bhagyalakshmi, Sushant Ghimire, Kiyonari Takahashi, Ken-ichi Yuyama, Yuta Takano, Takayoshi Nakamura, and Vasudevanpillai Biju
    • Journal Title

      Chemistry A European Journal

      Volume: 26 Pages: 2133-2137

    • DOI

      10.1002/chem.201904300

    • NAID

      120006958364

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Mechanochromic Luminescence from Crystals Consisting of Intermolecular Hydrogen‐Bonded Sheets2020

    • Author(s)
      Yoshimitsu Sagara, Kiyonori Takahashi,Takayoshi Nakamura, Nobuyuki Tamaoki
    • Journal Title

      Chemistry An Asian Journal

      Volume: 15 Pages: 478-482

    • DOI

      10.1002/asia.201901679

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Stable Ferromagnetic Crystal of Two-Dimensional Manganese-Chromium Oxalate with Supramolecular Cation2020

    • Author(s)
      Kubo Kazuya、Yoshitake Masashi、Hoshino Norihisa、Noro Shin-ichiro、Akutagawa Tomoyuki、Nakamura Takayoshi
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: - Pages: 1670-1675

    • DOI

      10.1002/ejic.202000149

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Positional Effects of Annelated Pyrazine Rings on Structure and Stability of Hydrogen-Bonded Frameworks of Hexaazatrinaphthylene Derivatives2020

    • Author(s)
      Ichiro Hisaki, Qin Ji, Kiyonori Takahashi, Norimitsu Tohnai, Takayoshi Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 20 Pages: 3190-3198

    • DOI

      10.1021/acs.cgd.0c00055

    • NAID

      120007034037

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Synchronous Change in Fluid Space and Encapsulated Anions in a Crystalline Polymethylene Unit Containing Metal-Organic Framework2020

    • Author(s)
      Zheng Xin、Sato Hiroyasu、Takahashi Kiyonori、Noro Shin-ichiro、Nakamura Takayoshi
    • Journal Title

      Crystal Growth & Design

      Volume: 20 Pages: 3596-3600

    • DOI

      10.1021/acs.cgd.0c00334

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structural Modulation of Electrically Conducting TCNQ Salts Using Na+(crown ether) Supramolecular Cations2020

    • Author(s)
      Sambe Kohei、Hoshino Norihisa、Takeda Takashi、Nakamura Takayoshi、Akutagawa Tomoyuki
    • Journal Title

      Cryst. Grow. Des.

      Volume: 20 Pages: 3625-3634

    • DOI

      10.1021/acs.cgd.0c00169

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dynamics and Structural Diversity of Li+(Crown Ether) Supramolecular Cations in Electrically Conducting Salts2020

    • Author(s)
      Sambe Kohei, Hoshino Norihisa, Takeda Takashi, Nakamura Takayoshi, Akutagawa Tomoyuki
    • Journal Title

      J. Phys. Chem. C.

      Volume: 124 Pages: 13560-13571

    • DOI

      10.1021/acs.jpcc.0c02686

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Controlling the gate-sorption properties of solid solutions of Werner complexes by varying component ratios2020

    • Author(s)
      Noro Shin-ichiro、Song Yu、Tanimoto Yutaro、Hijikata Yuh、Kubo Kazuya、Nakamura Takayoshi
    • Journal Title

      Dalton Transactions

      Volume: 49 Pages: 9438-9443

    • DOI

      10.1039/d0dt01355b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mechanical and thermal stimuli-induced release of toluene included in luminescent crystals as one-dimensional solvent channels2020

    • Author(s)
      Sagara Yoshimitsu、Takahashi Kiyonori、Nakamura Takayoshi、Tamaoki Nobuyuki
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 8 Pages: 10039-10046

    • DOI

      10.1039/d0tc02473b

    • NAID

      120007126836

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Coordinated Water as New Binding Sites for the Separation of Light Hydrocarbons in Metal-Organic Frameworks with Open Metal Sites2020

    • Author(s)
      Pia Vervoorts, Andreas Schneemann, Inke Hante, Jenny Pirillo, Yuh Hijikata, Takashi Toyao, Kenichi Kon, Ken-ichi Shimizu, Takayoshi Nakamura, Shin-ichiro Noro* and Roland A. Fischer*
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 12 Pages: 9448-9456

    • DOI

      10.1021/acsami.9b21261

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Understanding the interactions between the bis(trifluoromethylsulfonyl)imide anion and absorbed CO2 using X-ray diffraction analysis of a soft crystal surrogate2020

    • Author(s)
      Zheng Xin、Fukuhara Katsuo、Hijikata Yuh、Pirillo Jenny、Sato Hiroyasu、Takahashi Kiyonori、Noro Shin-ichiro、Nakamura Takayoshi
    • Journal Title

      Communications Chemistry

      Volume: 3 Pages: 143-143

    • DOI

      10.1038/s42004-020-00390-1

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structural Phase Transitions of a Molecular Metal Oxide2020

    • Author(s)
      Fujibayashi Masaru、Watari Yu、Tsunashima Ryo、Nishihara Sadafumi、Noro Shin‐ichiro、Lin Chang‐Gen、Song Yu‐Fei、Takahashi Kiyonori、Nakamura Takayoshi、Akutagawa Tomoyuki
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 59 Pages: 22446-22450

    • DOI

      10.1002/anie.202010748

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]2020

    • Author(s)
      Li Simin、Takahashi Kiyonori、Hisaki Ichiro、Kokado Kenta、Nakamura Takayoshi
    • Journal Title

      Dalton Transactions

      Volume: 49 Pages: 16772-16777

    • DOI

      10.1039/d0dt03386c

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Organic Ferroelectric Vortex-Antivortex Domain Structure2020

    • Author(s)
      Tang Yuan-Yuan、Xie Yongfa、Ai Yong、Liao Wei-Qiang、Li Peng-Fei、Nakamura Takayoshi、Xiong Ren-Gen
    • Journal Title

      Journal of the American Chemical Society

      Volume: 142 Pages: 21932-21937

    • DOI

      10.1021/jacs.0c11416

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Crystal structure and thermoresponsive luminescence of a 9,10-bis(phenylethynyl)anthracene-based cyclophane2020

    • Author(s)
      Yoshimitsu Sagara, Kiyonori Takahashi,Takayoshi Nakamura, Nobuyuki Tamaoki
    • Journal Title

      Mol. Syst. Des. Eng.

      Volume: 1 Pages: 205-211

    • DOI

      10.1039/c9me00105k

    • NAID

      120006950868

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Switching by Desorption/Adsorption of an Organic Solvent Molecule from/on [Ni(dmit)<sub>2</sub>]<sup>−</sup> Salt2019

    • Author(s)
      Katsuya Ichihashi, Takumi Nishimura, Daisuke Konno, Katsuya Inoue, Tomoyuki Akutagawa, Takayoshi Nakamura, and Sadafumi Nishihara
    • Journal Title

      Chem. Lett.

      Volume: 48 Issue: 4 Pages: 329-332

    • DOI

      10.1246/cl.181031

    • NAID

      130007624436

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Acid Responsive Hydrogen-bonded Organic Framework2019

    • Author(s)
      Ichiro Hisaki, Yuto Suzuki, Eduardo Gomez, Qin Ji, Norimitsu Tohnai, Takayoshi Nakamura, Abderrazzak Douhal
    • Journal Title

      J. Am. Chem. Soc

      Volume: 141 Pages: 2111-2121

    • DOI

      10.1021/jacs.8b12124

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hydrogen‐Bonded Polyrotaxane Cation Structure in Nickel Dithiolate Anion Radical Salts: Ferromagnetic and Semiconducting Behavior Associated with Structural Phase Transition2019

    • Author(s)
      Shirakawa Yuki、Takahashi Kiyonori、Sato Hiroyasu、Hoshino Norihisa、Anetai Hayato、Noro Shin‐ichiro、Akutagawa Tomoyuki、Nakamura Takayoshi
    • Journal Title

      Chem. Eur. J.

      Volume: - Pages: 6920-6927

    • DOI

      10.1002/chem.201806230

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Ion Exchange in Supramolecular Channels in the Crystalline State2019

    • Author(s)
      Katsuya Ichihashi, Daisuke Konno, Kseniya Yu. Maryunina, Katsuya Inoue, Kazuhiro Toyoda, Shogo Kawaguchi, Yoshiki Kubota, Yoko Tatewaki, Tomoyuki Akutagawa, Takayoshi Nakamura, and Sadafumi Nishihara
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Pages: 4169-4172

    • DOI

      10.1002/anie.201813709

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis, Structure, and Electrochemical Properties of [Na(SO<sub>3</sub>)<sub>2</sub>(RPO<sub>3</sub>)<sub>4</sub>Mo<sup>V</sup><sub>4</sub>Mo<sup>VI</sup><sub>14</sub>O<sub>49</sub>]<sup>5−</sup> (R = Propyl or <i>t</i>-Butyl)2019

    • Author(s)
      Fujibayashi Masaru、Shiga Misaki、Tsunashima Ryo、Nakamura Takayoshi
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 92 Issue: 5 Pages: 918-922

    • DOI

      10.1246/bcsj.20180347

    • NAID

      130007649780

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mixed-halide perovskite synthesis by chemical reaction and crystal nucleation under an optical potential2019

    • Author(s)
      Islam Md Jahidul、Yuyama Ken-ichi、Takahashi Kiyonori、Nakamura Takayoshi、Konishi Katsuaki、Biju Vasudevanpillai
    • Journal Title

      NPG Asia Materials

      Volume: 11 Pages: 31-31

    • DOI

      10.1038/s41427-019-0131-0

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Two Supramolecular Inorganic-Organic Hybrid Crystals Based on Keggin Polyoxometalates and Crown Ethers2018

    • Author(s)
      Xiong Jun、Luo Teng、Zhang Jun、Li Xiao-Xia、Lv Shao-Fang、Peng Jun-Jun、Li Ming、Li Wei、Nakamura Takayoshi
    • Journal Title

      Crystals

      Volume: 8 Pages: 17-17

    • DOI

      10.3390/cryst8020017

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Supramolecular self-assembly for designing non-centrosymmetric crystals based on Keggin polyoxometallates and crown ether2018

    • Author(s)
      Xiong Jun、Kubo Kazuya、Lue Shao-Fang、Li Ming、Nakamura Takayoshi
    • Journal Title

      Dalton Trans.

      Volume: 47 Pages: 14001-14007

    • DOI

      10.1039/c8dt02910e

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Optimizing Lithium Ion Conduction through Crown Ether-Based Cylindrical Channels in [Ni(dmit)2]- Salts2018

    • Author(s)
      Katsuya Ichihashi, Daisuke Konno, Takuya Date, Takumi Nishimura, Kseniya Yu. Maryunina, Katsuya Inoue, Toshimi Nakaya, Kazuhiro Toyoda, Yoko Tatewaki, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara,
    • Journal Title

      Chemistry of Materials

      Volume: 30 Pages: 7130-7137

    • DOI

      10.1021/acs.chemmater.8b03027

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Enhancement of Electrocatalytic Oxygen Reduction Activity and Durability of Pt-Ni Rhombic Dodecahedral Nanoframes by Anchoring to Nitrogen-Doped Carbon Support2018

    • Author(s)
      Kato Masaru、Ogura Kazuya、Nakagawa Shogo、Tokuda Shoichi、Takahashi Kiyonori、Nakamura Takayoshi、Yagi Ichizo
    • Journal Title

      ACS Omega

      Volume: 3 Pages: 9052-9059

    • DOI

      10.1021/acsomega.8b01373

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystallization of Methylammonium Lead Halide Perovskites by Optical Trapping2018

    • Author(s)
      Yuyama Ken-ichi、Islam Md Jahidul、Takahashi Kiyonori、Nakamura Takayoshi、Biju Vasudevanpillai
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Pages: 13424-13424

    • DOI

      10.1002/anie.201806079

    • NAID

      120006729575

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemo-chromism in an orthogonal dabco-based Co(ii) network assembled by methanol-coordination and hydrogen bond formation2018

    • Author(s)
      Shiga Misaki、Kawaguchi Shogo、Fujibayashi Masaru、Nishihara Sadafumi、Inoue Katsuya、Akutagawa Tomoyuki、Noro Shin-ichiro、Nakamura Takayoshi、Tsunashima Ryo
    • Journal Title

      Dalton Trans.

      Volume: 47 Pages: 7656-7662

    • DOI

      10.1039/c8dt01220b

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ferroelectric and Ferromagnetic Crystals with Supramolecular Structures2021

    • Author(s)
      Takayoshi Nakamura
    • Organizer
      Pacifichem 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Crystalline Molecular Electronic Materials Based on Supramolecular Structures2019

    • Author(s)
      Takayoshi Nakamura
    • Organizer
      10th International Conference on Molecular Electronics and Bioelectronics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Supramolecular Crystals for Molecular Electronic Materials2019

    • Author(s)
      Takayoshi Nakamura
    • Organizer
      15th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XV)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Molecular Electronic Materials Based on Supramolecular Cation Structures2019

    • Author(s)
      Takayoshi Nakamura
    • Organizer
      The 11th International Symposium on Nano & Supramolecular Chemistry
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ferromagnetic and Ferroelectric Properties of [MnCr(oxalate)3] Crystals with Supramolecular Cation2019

    • Author(s)
      Takayoshi Nakamura
    • Organizer
      7th Asian Conference on Coordination Chemistry
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Constructing Crystalline Molecular Electronic Materials Based on Heteroaromatic Cations in Large-Cavity Crown Ethers2018

    • Author(s)
      T. Nakamura
    • Organizer
      The 10th International Symposium on Nano & Supramolecular Chemistry, Dresden Germany
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Crown Ether Based Supramolecular Cations Salts of Ni(dmit)22018

    • Author(s)
      T. Nakamura
    • Organizer
      43rd International Conference on Coordination Chemistry, Sendai, Japan
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Crystalline Molecular Electronic Materials Based on the Supramolecular Structures of Heteroaromatic Cations and Large-Cavity Crown Ethers2018

    • Author(s)
      T. Nakamura
    • Organizer
      8th International Workshop “Organic Electronics of Highly -Correlated Molecular Systems”, Suzdal, Russia
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Heteroaromatic Cation/Large-Cavity Crown Ether Supramolecules in Ni(dmit)2 Salts2018

    • Author(s)
      T. Nakamura
    • Organizer
      14th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XIV), Guangzhou, China
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Patent(Industrial Property Rights)] 分子性有機導体の融解助剤、分子性有機導体含有固体材料及びそれらの利用2018

    • Inventor(s)
      中村貴義、白川祐基、高橋仁徳
    • Industrial Property Rights Holder
      中村貴義、白川祐基、高橋仁徳
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-162355
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2018-04-23   Modified: 2023-01-30  

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