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Construction and Functions of Hierarchical Supramolecules by Using Helical Supramolecular Units

Research Project

Project/Area Number 18H01959
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 33010:Structural organic chemistry and physical organic chemistry-related
Research InstitutionUniversity of Tsukuba

Principal Investigator

Nabeshima Tatsuya  筑波大学, 数理物質系, 教授 (80198374)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2020: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2019: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2018: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywords超分子 / 分子集積 / ラセン分子 / 金属錯体 / ラセン錯体 / 自己集積 / 分子集合体 / 分子認識 / ラセン構造 / 錯形成 / ビピリジン錯体 / 分子ケージ / ビピリジン / ラセン
Outline of Final Research Achievements

We synthesized tripodands bearing metal binding sites to quantitatively prepare helical metal complexes which were utilized for a new method to create large supramolecular assemblies in a stepwise fashion. We have found essential factors to form such helical complexes and hierarchical supramolecules, which would be useful to design and synthesize supramolecules and materials with sophisticated functions based on the properties of the helical complexes.

Academic Significance and Societal Importance of the Research Achievements

構造が厳密に決まった巨大超分子を、小さな分子のユニットから、様々な構造体へ高収率で変換する手法は、高機能な分子や材料を開発する上で重要である。しかし、高機能化を実現するために、集合体の構造を巨大で複雑にしようとすればするほど、その合成は多数の副生成物を生じるなど、飛躍的に困難になる。本研究では光学活性なラセン構造を活かし、不斉構造がそろった分子集合体の高収率、高選択的合成を実現して、不斉構造をもつ機能性分子や材料の開発に有力となる手法を開発した。また、その反応の選択性の要因を明らかにするなど、得られた成果の学術的な意義も大きい。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report

Research Products

(134 results)

All 2021 2020 2019 2018 Other

All Journal Article (20 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 20 results,  Open Access: 1 results) Presentation (113 results) (of which Int'l Joint Research: 18 results,  Invited: 12 results) Remarks (1 results)

  • [Journal Article] Synthesis of Single Isomeric Complexes with Dissymmetric Structures Using Macrocyclic Homooligomers2021

    • Author(s)
      NAKAMURA, Takashi; YONEMURA, Sota; AKATSUKA, Shunya; NABESHIMA, Tatsuya
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Pages: 3080-3086

    • DOI

      10.1002/anie.202011348

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Sandwich-Shaped Hexanuclear Silver Complex with a Giant Cavity Constructed from a Macrocycle with Inward Chelating Units2021

    • Author(s)
      NAKAMURA, Takashi; FENG, Rui Yun; NABESHIMA, Tatsuya
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2021 Pages: 308-313

    • DOI

      10.1002/ejic.202000882

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exclusive formation of a meridional complex of a tripodand and perfect suppression of guest recognition2021

    • Author(s)
      MORITA, Hiroki; AKINE, Shigehisa; NAKAMURA, Takashi; NABESHIMA, Tatsuya
    • Journal Title

      Chemical Communications

      Volume: 57 Pages: 2124-2127

    • DOI

      10.1039/d1cc00146a

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Functions of Oligomeric and Multidentate Dipyrrin Derivatives and their Complexes2020

    • Author(s)
      Nabeshima Tatsuya、Chiba Yusuke、Nakamura Takashi、Matsuoka Ryota
    • Journal Title

      Synlett

      Volume: 31 Pages: 1663-1680

    • DOI

      10.1055/s-0040-1707155

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Threading/Folding Recognition Modes of Phosphodiesters by a <i>p</i>-Nitrophenylamide Cyclodextrin Derivative2020

    • Author(s)
      YONEMURA, Sota; NAKAMURA, Takashi; NABESHIMA, Tatsuya
    • Journal Title

      Chem. Lett.

      Volume: 49 Issue: 5 Pages: 493-496

    • DOI

      10.1246/cl.200085

    • NAID

      130007840172

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Double-Circularly Connected Saloph-Belt Macrocycles Generated from a Bis-Armed Bifunctional Monomer2019

    • Author(s)
      NAKAMURA, Takashi; TSUKUDA, Shinnosuke; NABESHIMA, Tatsuya
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Pages: 6462-6467

    • DOI

      10.1021/jacs.9b00171

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bpytrisalen/Bpytrisaloph: A Triangular Platform That Spatially Arranges Different Multiple Labile Coordination Sites2019

    • Author(s)
      NAKAMURA, Takashi; KAWASHIMA, Yuto; NISHIBORI, Eiji; NABESHIMA, Tatsuya
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Pages: 7863-7872

    • DOI

      10.1021/acs.inorgchem.9b00549

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Luminescent Properties and Cation Recognition Ability of Heavy Group 13 Element Complexes of N2O2- and N2O4-Type Dipyrrins2019

    • Author(s)
      Sumiyoshi Akinobu, Chiba Yusuke, Matsuoka Ryota, Noda Takumu, Nabeshima Tatsuya
    • Journal Title

      Dalton Transactions

      Volume: 48 Pages: 13169-13175

    • DOI

      10.1039/c9dt02403d

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polychromatic Photoluminescence of Polymorph Boron Dipyrromethene Crystals and Heterostructures2019

    • Author(s)
      Aswin Asaithambi, Daichi Okada, Gunther Prinz, Hiroyasu Sato, Akinori Saeki, Takashi Nakamura, Tatsuya Nabeshima, Yohei Yamamoto, Axel Lorke*
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Pages: 5061-5066

    • DOI

      10.1021/acs.jpcc.8b09202

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Heterodinuclear Group 13 Element Complexes of N4O6-Type Dipyrrin with an Unsymmetrical Twisted Structure2019

    • Author(s)
      Makoto Saikawa, Takumu Noda, Ryota Matsuoka, Takashi Nakamura, and Tatsuya Nabeshima
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2019 Pages: 766-769

    • DOI

      10.1002/ejic.201801062

    • NAID

      120007128210

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Closed Metallomolecular Cage that can Open its Aperture by Disulfide Exchange2019

    • Author(s)
      Shigehisa Akine, Masato Miyashita, and Tatsuya Nabeshima
    • Journal Title

      Chemistry, A European Journal

      Volume: 25 Pages: 1432-1435

    • DOI

      10.1002/chem.201806184

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Conformationally Flexible Macrocyclic Dipyrrin Tetramer and Its Unsymmetrically Twisted Luminescent Zinc(II) Complex2019

    • Author(s)
      Tomohiro Hojo, Ryota Matsuoka, and Tatsuya Nabeshima
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Pages: 995-998

    • DOI

      10.1021/acs.inorgchem.8b02736

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ligand Exchange Strategy for Tuning of Helicity Inversion Speeds of Dynamic Helical Tri(saloph) Metallocryptands2019

    • Author(s)
      Sakata Yoko、Chiba Shunsuke、Miyashita Masato、Nabeshima Tatsuya、Akine Shigehisa
    • Journal Title

      Chemistry, A European Journal

      Volume: 25 Pages: 2962-2966

    • DOI

      10.1002/chem.201805799

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands2019

    • Author(s)
      Akira Nagai, Takashi Nakamura, and Tatsuya Nabeshima
    • Journal Title

      Chemical Communications

      Volume: 55 Pages: 2421-2424

    • DOI

      10.1039/c8cc09643k

    • NAID

      120007128043

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of per(5-N-carboxamide-5-dehydroxylmethyl)-β-cyclodextrins and their selective recognition ability utilizing multiple hydrogen bonds2019

    • Author(s)
      Takashi Nakamura, Sota Yonemura,and Tatsuya Nabeshima
    • Journal Title

      Chemical Communications

      Volume: 55 Pages: 3872-3875

    • DOI

      10.1039/c9cc00517j

    • NAID

      120007127947

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Unique Optical Properties of Selenophenyl BODIPYs and Their Linear Oligomers2018

    • Author(s)
      Taguchi Daisuke、Nakamura Takashi、Horiuchi Hiroaki、Saikawa Makoto、Nabeshima Tatsuya
    • Journal Title

      J. Org. Chem.

      Volume: in press Pages: 5331-5337

    • DOI

      10.1021/acs.joc.8b00782

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A novel graphite-like stacking structure in a discrete molecule and its molecular recognition behavior2018

    • Author(s)
      Akine Shigehisa、Onuma Takahiro、Nabeshima Tatsuya
    • Journal Title

      New Jouranl of Chemistry

      Volume: 42 Pages: 9369-9372

    • DOI

      10.1039/c8nj01315b

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and chiroptical properties of phenanthrene-fused N2O-type BODIPYs2018

    • Author(s)
      Yuki Gobo, Ryota Matsuoka, Yusuke Chiba, Takashi Nakamura, and Tatsuya Nabeshima
    • Journal Title

      Tetrahedron Letters

      Volume: 59 Pages: 4149-4152

    • DOI

      10.1016/j.tetlet.2018.10.003

    • NAID

      120007128440

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Uniquely folded shapes, photophysical properties, and recognition abilities of macrocyclic BODIPY oligomers2018

    • Author(s)
      Tomohiro Hojo, Takashi Nakamura, Ryota Matsuoka, and Tatsuya Nabeshima
    • Journal Title

      Heteroatom Chemistry

      Volume: 29

    • DOI

      10.1002/hc.21470

    • NAID

      120007128180

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functional Supramolecular Architectures of Dipyrrin Complexes2018

    • Author(s)
      Ryota Matsuoka and Tatsuya Nabeshima
    • Journal Title

      Frontiers in Chemistry

      Volume: 6 Pages: 349-349

    • DOI

      10.3389/fchem.2018.00349

    • NAID

      120007133821

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 歪んだ構造をもつ大環状ジピリンホウ素錯体のゲスト認識能2021

    • Author(s)
      増本正輝・鍋島達弥
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ホウ素と白金を有する環状ジピリンヘテロ六核錯体の合成とゲスト認識能2021

    • Author(s)
      芹澤航平・千葉湧介・鍋島達弥
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 三脚型ピリジルピラゾールらせん錯体の脱プロトン化を伴う二量化挙動2021

    • Author(s)
      田原航太・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 三脚型トリスビピリジンFe(II)錯体のカウンターアニオンによるfac/mer異性化の制御2021

    • Author(s)
      金哲輝・千葉湧介・鍋島達弥
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ビピリジンとサレンを3つずつ有する三角形大環状分子の配位能と錯体の構造2021

    • Author(s)
      矢野周平・中村貴志・鍋島達弥
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] A Sandwich-Shaped Hexanuclear Silver Complex Constructed from a Macrocycle with Six Inward Chelating Units2021

    • Author(s)
      NAKAMURA, Takashi; FENG, Rui Yun; NABESHIMA, Tatsuya
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ピリジルウレア部位をもつ三脚型トリスビピリジン鉄(II)錯体の配位結合による自己集積化2021

    • Author(s)
      千葉湧介・藤井広輝・鍋島達弥
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ホウ素と白金を有する環状ジピリンヘテロ六核錯体の合成と機能2020

    • Author(s)
      芹澤航平・千葉湧介・鍋島達弥
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ジピリン環状三量体の非対称錯体の合成と分子認識能2020

    • Author(s)
      増本正輝・松岡亮太・鍋島達弥
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 強いブレンステッド酸性を示すトリス(ピリジルピラゾール)亜鉛(II)錯体の合成2020

    • Author(s)
      田原航太・松岡亮太・鍋島達弥
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 6,7,8つのビピリジル基をもつシクロデキストリン配位子を用いた単一の異性体錯体の形成と分子認識2020

    • Author(s)
      中村貴志・赤塚竣哉・米村颯太・鍋島達弥
    • Organizer
      錯体化学会第70回討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 2,2’-ビピリジンをスペーサーにもつ環状BODIPYの錯形性能と機能2020

    • Author(s)
      芹澤航平・千葉湧介・鍋島達弥
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] ジピリン環状三量体のホウ素錯体の合成と分子認識能2020

    • Author(s)
      増本正輝・松岡亮太・鍋島達弥
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 低い対称性をもつ環状ジピリン三量体錯体の合成と分子認識能2020

    • Author(s)
      増本正輝・鍋島達弥
    • Organizer
      基礎有機化学会若手オンラインシンポジウム(第0回)
    • Related Report
      2020 Annual Research Report
  • [Presentation] 特異な構造をもつ環状BODIPYホストの合成と分子認識2020

    • Author(s)
      増本正輝・鍋島達弥
    • Organizer
      第47回有機典型元素化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 多数の配位部位を導入した大環状配位子を用いた単一の異性体錯体の形成2020

    • Author(s)
      中村貴志・赤塚竣哉・米村颯太・鍋島達弥
    • Organizer
      第47回有機典型元素化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ジピリン環状三量体と種々の元素との錯形成とその機能2020

    • Author(s)
      増本正輝・鍋島達弥
    • Organizer
      第80回有機合成化学協会関東支部シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 6つまたは8つのビピリジル基をもつシクロデキストリン金属錯体の構造2020

    • Author(s)
      赤塚竣哉・中村貴志・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ビピリジンとサレンで構成される剛直な大環状配位子を用いた多核金属錯体の合成2020

    • Author(s)
      矢野周平・中村貴志・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] C3v対称BODIPY環状三量体の擬ロタキサン形成における速度論的向き選択性と置換基効果2020

    • Author(s)
      松岡亮太・檜森宗・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] トリアゾリウムを集積させた三脚型らせん金属錯体の水中におけるアニオン認識2020

    • Author(s)
      青木孝介・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] C3v対称ジピリン環状三量体の非対称的錯体形成2020

    • Author(s)
      増本正輝・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] C3v対称BODIPY環状三量体の擬ロタキサン形成における置換基効果2020

    • Author(s)
      タンテンセイ・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 含2,2’-ビピリジン環状ジピリン多量体とそのBODIPY誘導体の合成2020

    • Author(s)
      芹澤航平・千葉湧介・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] トリポダンド型トリスビピリジン錯体の溶媒依存的fac/mer異性化2020

    • Author(s)
      両角拓磨・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 7つのビピリジルアミド基をもつシクロデキストリン錯体の非対称化された構造を利用したアニオンのキラル認識2020

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] シッフ塩基形成を利用した三重らせん錯体の自己集積挙動2020

    • Author(s)
      石原拓磨・千葉湧介・鍋島達弥
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジシリンとハロゲン化亜鉛の反応2020

    • Author(s)
      東條翔磨・鍋島達弥・一戸雅聡
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] シリル基とアルキル基で非対称に置換されたジシレンの合成2020

    • Author(s)
      日比風弥・鍋島達弥・一戸雅聡
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] アルキル置換1,2-ジリチオジシランの合成2020

    • Author(s)
      東條翔磨・鍋島達弥・一戸雅聡
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 分子の世界のコミュニケーションと分子の働き2019

    • Author(s)
      鍋島達弥
    • Organizer
      大饗シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 複雑系を指向した機能性超分子システム2019

    • Author(s)
      鍋島達弥
    • Organizer
      第17回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 双腕型両官能性単量体を用いたサロフベルト大環状分子の合成とフラーレンの選択的包接2019

    • Author(s)
      中村貴志・佃真之介・鍋島達弥
    • Organizer
      第17回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] トリアゾリウムを集積させた三脚型らせん金属錯体によるイオン認識2019

    • Author(s)
      青木孝介・松岡亮太・鍋島達弥
    • Organizer
      第17回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] N2O4型ジピリンインジウム錯体によるアルカリ土類金属イオン認識2019

    • Author(s)
      住吉昭信・千葉湧介・松岡亮太・鍋島達弥
    • Organizer
      第17回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] ビピリジル基を導入したβシクロデキストリン誘導体の金属錯形成による単一異性体の合成と多量体錯体の形成2019

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第17回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Design and Synthesis of Artificial Supramolecular Systems Possessing Highly Cooperative Functions2019

    • Author(s)
      NABESHIMA, Tatsuya
    • Organizer
      3rd World Chemistry Conference and Exhibition (WCCE-2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Functions of Indium Complexes of N2O4-type Dipyrrins2019

    • Author(s)
      SUMIYOSHI, Akinobu; CHIBA, Yusuke; MATSUOKA, Ryota; NABESHIMA, Tatsuya
    • Organizer
      18th International Symposium on Novel Aromatic Compounds (ISNA-18)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アミド基を介して多数のビピリジルを導入したβシクロデキストリン誘導体の金属錯形成による単一なキラル構造の構築2019

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第10回サブウェイセミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] Unique Responding and Synergistic Molecular Recognition of Supramolecular Systems2019

    • Author(s)
      NABESHIMA, Tatsuya
    • Organizer
      1st International Conferences on Noncovalent Interactions (ICNI-2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アミド基を5位にもつシクロデキストリン誘導体の合成・構造と多点水素結合によるアニオン認識2019

    • Author(s)
      中村貴志・米村颯太・鍋島達弥
    • Organizer
      第36回シクロデキストリンシンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] シリル基とアルキル基で置換された非対称ジシレンの合成と反応性2019

    • Author(s)
      日比風弥・鍋島達弥・一戸雅聡
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] A Luminescent Zn(II) Complex of Oligodipyrrin Macrocycle with an Unsymmetrically Twisted Structure2019

    • Author(s)
      MATSUOKA, Ryota; HOJO, Tomohiro; NABESHIMA, Tatsuya
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 7つのビピリジルを持つシクロデキストリン誘導体の段階的錯形成によるキラルな巨大構造の構築2019

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] C3v型BODIPY環状三量体による擬ロタキサン形成の速度論的向き選択性と置換基効果2019

    • Author(s)
      松岡亮太・檜森宗・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] m-フェニレンをスペーサーとする環状ジピリン多量体の合成と錯化挙動2019

    • Author(s)
      増本正輝・千葉湧介・松岡亮太・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] トリアゾリウムを集積させた三脚型らせん金属錯体による水中アニオン認識2019

    • Author(s)
      青木孝介・松岡亮太・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 複数のビピリジンを集積させたキラル三重らせん超分子の合成2019

    • Author(s)
      石原拓磨・松岡亮太・千葉湧介・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 四級炭素ピボットを持つ三脚型ビピリジン配位子の金属錯形成と自己集積2019

    • Author(s)
      両角拓磨・松岡亮太・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 2,2’-ビピリジンをスペーサーに持つ新規環状ジピリン多量体の合成2019

    • Author(s)
      芹澤航平・千葉湧介・松岡亮太・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 発光性N2O4型ジピリン-インジウムおよびガリウム錯体の合成とイオン認識2019

    • Author(s)
      住吉昭信・松岡亮太・千葉湧介・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ビピリジル部位を内孔にもつ大環状配位子の合成とその多核金属錯体および超分子錯体の精密構築2019

    • Author(s)
      中村貴志・川島侑人・鍋島達弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] トリアゾリウムを集積させた三重らせん金属錯体によるイオン認識2019

    • Author(s)
      青木孝介・松岡亮太・鍋島達弥
    • Organizer
      CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 四級炭素ピボットを持つ含ビピリジルトリポダンドの金属錯形成と自己集積体の合成2019

    • Author(s)
      両角拓磨・松岡亮太・鍋島達弥
    • Organizer
      CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 多数のビピリジルを持つシクロデキストリン誘導体の金属錯形成によるキラル構造の構築と機能化2019

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] ビピリジンスペーサーを有するキラル三重らせん超分子の合成2019

    • Author(s)
      石原拓磨・松岡亮太・千葉湧介・鍋島達弥
    • Organizer
      CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] N2O4型ジピリン-インジウムおよびガリウム蛍光錯体の合成とイオン認識2019

    • Author(s)
      住吉昭信・松岡亮太・千葉湧介・鍋島達弥
    • Organizer
      CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] m-フェニレンスペーサーをもつ大環状ジピリンオリゴマーの合成と錯化挙動2019

    • Author(s)
      増本正輝・千葉湧介・松岡亮太・鍋島達弥
    • Organizer
      CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 2,2’-ビピリジンをスペーサーとする新規大環状ジピリン多量体の合成2019

    • Author(s)
      芹澤航平・千葉湧介・松岡亮太・鍋島達弥
    • Organizer
      CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] Design and Synthesis of Molecular and Supramolecular Systems with Unique Functions2019

    • Author(s)
      NABESHIMA, Tatsuya
    • Organizer
      The chemistry seminar (King Abdullah University of Science and Technology)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Creation of Unique Structures and Functions by Utilizing Coordination Bonds2019

    • Author(s)
      NABESHIMA, Tatsuya
    • Organizer
      Joint Symposium on Nanomaterials for Energy Applications (the University of Duisburg-Essen)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] トリアゾリウムを集積させた三重らせん金属錯体による水中アニオン認識2019

    • Author(s)
      青木孝介・松岡亮太・鍋島達弥
    • Organizer
      第46回有機典型元素化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 2,2’-ビピリジンをスペーサーにもつ環状ジピリン多量体およびそのBODIPY誘導体の合成2019

    • Author(s)
      芹澤航平・千葉湧介・鍋島達弥
    • Organizer
      第46回有機典型元素化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] サロフを壁面に持つベルト状大環状分子によるフラーレン包接2019

    • Author(s)
      佃真之介・中村貴志・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] C3v型BODIPY大環状三量体による擬ロタキサン形成の速度論的向き選択性2019

    • Author(s)
      檜森宗・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大環状ジピリン多量体およびそのBODIPY誘導体の分子認識能2019

    • Author(s)
      北條智大・松岡亮太・中村貴志・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] N2O4型ジピリンインジウム錯体の合成と光学特性2019

    • Author(s)
      住吉昭信・千葉湧介・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] C-ピボット型三重らせん金属錯体を用いた超分子ケージの合成2019

    • Author(s)
      両角拓磨・松岡亮太・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 7つのビピリジル基をもつシクロデキストリン誘導体の金属錯形成による単一異性体の生成2019

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 2,2’-ビピリジンをスペーサーに持つ環状ジピリンの合成2019

    • Author(s)
      芹澤航平・千葉湧介・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 1,3-ジメトキシ-m-フェニレンをスペーサーとする環状ジピリンの合成2019

    • Author(s)
      増本正輝・千葉湧介・鍋島達弥
    • Organizer
      日本化学会第99回春季年会(2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Functional Supramolecular Systems Synthesized by Using Coordination and/or Dynamic Covalent Bonds2019

    • Author(s)
      Tatsuya Nabeshima
    • Organizer
      Symposium for the Promotion of Applied Research Collaboration in Asia
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 2,2´-ビピリジンを導入した三角形大環状配位子および配位サイトを精密集積した多核錯体の合成2018

    • Author(s)
      中村貴志・川島侑人・鍋島達弥
    • Organizer
      第16回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] ユニークにねじれた大環状骨格を有するパラジウム六核錯体の合成2018

    • Author(s)
      永井瑛・中村貴志・鍋島達弥
    • Organizer
      第16回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミド基を集積したβシクロデキストリン誘導体の特異な構造とアニオン認識能2018

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第16回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] テトラポッド型らせん金属錯体を用いたケージ超分子の合成2018

    • Author(s)
      両角拓磨・松岡亮太・鍋島達弥
    • Organizer
      第16回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 階層的および相乗的機能創出のための超分子の構築2018

    • Author(s)
      鍋島達弥
    • Organizer
      早稲田大学理工学部/大学院理工学研究科講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Unique Optical Properties of Thiophenyl and Selenophenyl BODIPYs2018

    • Author(s)
      Tatsuya Nabeshima, Daisuke Taguchi, Makoto Saikawa, Sousuke Saino, Takashi Nakamura, Hiroaki Horiuchi
    • Organizer
      28th International Symposium on the Organic Chemistry of Sulfur(ISOCS-28)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 相乗的・階層的機能のための分子システムの構築2018

    • Author(s)
      鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] アミドシクロデキストリン誘導体の合成とその非対称化された空孔における多点水素結合による分子認識能2018

    • Author(s)
      中村貴志・米村颯太・鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大環状ジピリン多量体およびそのBODIPY誘導体の構造多様性と分子認識2018

    • Author(s)
      松岡亮太・北條智大・野田卓夢・鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 環状ジピリン四量体を配位子とした亜鉛錯体の合成と性質2018

    • Author(s)
      北條智大・松岡亮太・鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 三重らせん金属錯体を用いた動的集積による超分子の構築2018

    • Author(s)
      武藤圭汰・松岡亮太・鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] N2O4型ジピリン典型元素錯体の合成と機能化2018

    • Author(s)
      住吉昭信・松岡亮太・鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] テトラポッド型らせん金属錯体を用いた超分子集積体の合成2018

    • Author(s)
      両角拓磨・松岡亮太・鍋島達弥
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大環状サロフベルト錯体の合成と不飽和脂肪酸の位置選択的エポキシ化2018

    • Author(s)
      佃真之介・中村貴志・鍋島達弥
    • Organizer
      第12回バイオ関連化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミド基を多数導入したβ-シクロデキストリン誘導体によるアニオンの非対称的な認識2018

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第12回バイオ関連化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 動的共有結合を用いた元素ブロック自己集積体の構築とそのユニークな機能2018

    • Author(s)
      鍋島達弥
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 多色発光を示すBODIPYマイクロ結晶と光学ヘテロ構造の形成2018

    • Author(s)
      岡田大地・Asaithambi Aswin・Prinz Gunther ・佐藤寛泰・佐伯昭紀・中村貴志・鍋島達弥・Lorke Axel・山本洋平
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多色発光を示すBODIPYマイクロ結晶と光学ヘテロ構造の作成2018

    • Author(s)
      岡田大地・Vijai Aswin・Prinz Gunther・佐藤寛泰・佐伯昭紀・中村貴志・鍋島達弥・Lorke Axel・山本洋平
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Design, Synthesis and Novel Functions of BODIPY Derivatives2018

    • Author(s)
      Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Functional Main-Group-Element Complexes of N2O4-Type Dipyrrins2018

    • Author(s)
      Akinobu Sumiyoshi, Ryota Matsuoka, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Supramolecular Self-Assembly of Helical Metal Complexes with a Tetrapodal Scaffold2018

    • Author(s)
      Takuma Morozumi, Ryota Matsuoka, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of macrocyclic saloph-belt ligands from a bifunctional monomer and function of their Mn complexes2018

    • Author(s)
      Shinnosuke Tsukuda, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and uniquely twisted shape of a macrocyclic hexanuclear palladium complex with labile coordination sites in its inner cavity2018

    • Author(s)
      Akira Nagai, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetic Control of Pseudorotaxane Formation by Bowl-Shaped Cyclic BODIPY Trimer2018

    • Author(s)
      Sou Himori, Ryota Matsuoka, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of a Tetranuclear Zinc Complex of a Macrocyclic Dipyrrin Tetramer2018

    • Author(s)
      Tomohiro Hojo, Ryota Matsuoka, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Construction of Supramolecular Tetrahedral Cages via Dynamic Assembly Utilizing Triple Helical Complexes2018

    • Author(s)
      Keita Muto, Ryota Matsuoka, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of supramolecular cages based on Schiff-base formation using a tris(2-pyridylmethyl)amine derivative2018

    • Author(s)
      Takuma Kawashima, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Anion Recognition by Multiple Hydrogen Bonds with Amide Groups Accumulated on β-Cyclodextrin2018

    • Author(s)
      Sota Yonemura, Takashi Nakamura, Tatsuya Nabeshima
    • Organizer
      Tsukuba Global Science Week (TGSW) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 多様な機能をもつジピリン錯体の設計と合成2018

    • Author(s)
      鍋島達弥
    • Organizer
      第5回次世代の有機化学・広島シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 両官能性単量体を用いた大環状サロフベルト配位子の合成およびそのMn錯体の機能2018

    • Author(s)
      佃真之介・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 内孔に配位部位を持つ大環状六核パラジウム錯体の合成とそのねじれ形状2018

    • Author(s)
      永井瑛・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] ボウル型構造を有するBODIPY環状三量体による擬ロタキサン形成の速度論的向き選択性2018

    • Author(s)
      檜森宗・松岡亮太・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 環状ジピリン四量体を用いたユニークな亜鉛錯体の合成と性質2018

    • Author(s)
      北條智大・松岡亮太・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] シッフ塩基形成を利用した動的集積によるケージ超分子の構築2018

    • Author(s)
      武藤圭汰・松岡亮太・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 動的共有結合を用いたトリス(2-ピリジルメチル)アミン部位を頂点とする超分子ケージの構築2018

    • Author(s)
      川島拓馬・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 機能性N2O4型ジピリン典型元素錯体の合成2018

    • Author(s)
      住吉昭信・松岡亮太・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] テトラポッド型らせん金属錯体を用いた超分子集積体の合成と性質2018

    • Author(s)
      両角拓磨・松岡亮太・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミド基を非対称に配置したシクロデキストリン誘導体の多数の水素結合による選択的ゲスト認識2018

    • Author(s)
      米村颯太・中村貴志・鍋島達弥
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] Unique Functions of Complexes of Oligodipyrrins and Oligoimines2018

    • Author(s)
      Tatsuya Nabeshima
    • Organizer
      The 18th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 特異な8の字構造を有する大環状オリゴジピリン亜鉛錯体の合成と発光特性2018

    • Author(s)
      松岡亮太・北條智大・鍋島達弥
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] N2O4型ジピリン13族元素錯体の合成と光学特性2018

    • Author(s)
      住吉昭信・松岡亮太・鍋島達弥
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Remarks] 筑波大学数理物質系化学域 鍋島研究室(超分子化学研究室)

    • URL

      http://www.chem.tsukuba.ac.jp/nabesima/

    • Related Report
      2018 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2022-01-27  

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