• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of next generation OLED materials by multiple resonance effect

Research Project

Project/Area Number 18H02051
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 35030:Organic functional materials-related
Research InstitutionKwansei Gakuin University

Principal Investigator

Hatakeyama Takuji  関西学院大学, 理工学部, 教授 (90432319)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2020: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2019: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2018: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Keywords有機合成 / 有機EL / 熱活性化遅延蛍光 / 多重共鳴効果 / 有機導体 / 熱活性化遅延蛍
Outline of Final Research Achievements

Recently, we have succeeded in minimizing the energy gap between the excited singlet state and the excited triplet state and suppressing the structural change in the excited state by the "multiple resonance effect" of boron and nitrogen atoms to develop pure blue thermally activated delayed fluorescence (TADF) materials with a photoluminescence quantum yield of >90%. In this study, based on this design guideline, we have developed new-DABNA, which exhibits ultra-narrowband blue emission comparable to that of inorganic luminescent materials, and OAB-ABP-1 and CzB2-M/P as pure green TADF materials. Both materials exhibit high external quantum efficiency of 20-35%, and are expected to be put to practical use in the near future.

Academic Significance and Societal Importance of the Research Achievements

本研究を通じて確立したホウ素と窒素の「多重共鳴効果」による分子設計,また,それらを可能とする合成手法は,今後,様々な発光材料の開発指針となり,有機エレクトロニクス分野の発展に寄与するものと考えられる。また,開発した発光材料を用いた素子は,従来材料を用いた素子と比較して色純度と外部量子効率に優れており,今後の実用化研究を通じて,有機ELディスプレイの省電力化,高輝度化,高精彩化などが期待できる。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (55 results)

All 2021 2020 2019 2018 Other

All Journal Article (15 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 15 results,  Open Access: 2 results) Presentation (39 results) (of which Int'l Joint Research: 9 results,  Invited: 14 results) Remarks (1 results)

  • [Journal Article] Stable pure-blue hyperfluorescence organic light-emitting diodes with high-efficiency and narrow emission2021

    • Author(s)
      Chin-Yiu Chan; Masaki Tanaka; Yi-Ting Lee; Yiu-Wing Wong; Hajime Nakanotani; Takuji Hatakeyama; Chihaya Adachi
    • Journal Title

      Nat. Photonics

      Volume: 15 Issue: 3 Pages: 203-207

    • DOI

      10.1038/s41566-020-00745-z

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hot Vibrational States in a High-Performance Multiple Resonance Emitter and the Effect of Excimer Quenching on Organic Light-Emitting Diodes2021

    • Author(s)
      Stavrou Kleitos、Danos Andrew、Hama Toshiki、Hatakeyama Takuji、Monkman Andrew
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 13 Issue: 7 Pages: 8643-8655

    • DOI

      10.1021/acsami.0c20619

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Development of One-Shot/One-Pot Borylation Reactions toward Organoboron-Based Materials2021

    • Author(s)
      Oda Susumu、Hatakeyama Takuji
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 94 Issue: 3 Pages: 950-960

    • DOI

      10.1246/bcsj.20200372

    • NAID

      130008021806

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Investigating HOMO Energy Levels of Terminal Emitters for Realizing High-Brightness and Stable TADF-Assisted Fluorescence Organic Light-Emitting Diodes2021

    • Author(s)
      Yi-Ting Lee; Chin-Yiu Chan; Masaki Tanaka; Masashi Mamada; Umamahesh Balijapalli; Youichi Tsuchiya; Hajime Nakanotani; Takuji Hatakeyama; Chihaya Adachi
    • Journal Title

      Advanced Electronic Materials

      Volume: 7 Issue: 4 Pages: 2001090-2001090

    • DOI

      10.1002/aelm.202001090

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solution‐Processable Pure Green Thermally Activated Delayed Fluorescence Emitter Based on the Multiple Resonance Effect2020

    • Author(s)
      Ikeda Naoya、Oda Susumu、Matsumoto Ryuji、Yoshioka Mayu、Fukushima Daisuke、Yoshiura Kazuki、Yasuda Nobuhiro、Hatakeyama Takuji
    • Journal Title

      Advanced Materials

      Volume: 32 Issue: 40 Pages: 2004072-2004072

    • DOI

      10.1002/adma.202004072

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbazole‐Based DABNA Analogues as Highly Efficient Thermally Activated Delayed Fluorescence Materials for Narrowband Organic Light‐Emitting Diodes2020

    • Author(s)
      Oda Susumu、Kumano Wataru、Hama Toshiki、Kawasumi Ryosuke、Yoshiura Kazuki、Hatakeyama Takuji
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 6 Pages: 2882-2886

    • DOI

      10.1002/anie.202012891

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiple Electrophilic C-H Borylation of Arenes Using Boron Triiodide2020

    • Author(s)
      Oda Susumu、Ueura Kenta、Kawakami Bungo、Hatakeyama Takuji
    • Journal Title

      Organic Letters

      Volume: 22 Issue: 2 Pages: 700-704

    • DOI

      10.1021/acs.orglett.9b04483

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvent‐Vapor‐Induced Reversible Single‐Crystal‐to‐Single‐Crystal Transformation of a Triphosphaazatriangulene‐Based Metal-Organic Framework2020

    • Author(s)
      Nakatsuka Soichiro、Watanabe Yusuke、Kamakura Yoshinobu、Horike Satoshi、Tanaka Daisuke、Hatakeyama Takuji
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 4 Pages: 1435-1439

    • DOI

      10.1002/anie.201912195

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Role of Reverse Intersystem Crossing Using a TADF‐Type Acceptor Molecule on the Device Stability of Exciplex‐Based Organic Light‐Emitting Diodes2020

    • Author(s)
      Thanh Ba Nguyen, Hajime Nakanotani, Takuji Hatakeyama, Chihaya Adachi
    • Journal Title

      Advanced Materials

      Volume: 32 Issue: 9 Pages: 1906614-1906614

    • DOI

      10.1002/adma.201906614

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Narrowband deep-blue organic light-emitting diode featuring an organoboron-based emitter2019

    • Author(s)
      Kondo Yasuhiro、Yoshiura Kazuki、Kitera Sayuri、Nishi Hiroki、Oda Susumu、Gotoh Hajime、Sasada Yasuyuki、Yanai Motoki、Hatakeyama Takuji
    • Journal Title

      Nature Photonics

      Volume: 13 Issue: 10 Pages: 678-682

    • DOI

      10.1038/s41566-019-0476-5

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiple Resonance Effect-Induced Sky-Blue Thermally Activated Delayed Fluorescence with a Narrow Emission Band2019

    • Author(s)
      Oda Susumu、Kawakami Bungo、Kawasumi Ryosuke、Okita Ryota、Hatakeyama Takuji
    • Journal Title

      Organic Letters

      Volume: 21 Issue: 23 Pages: 9311-9314

    • DOI

      10.1021/acs.orglett.9b03342

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tetracoordinate Boron-Fused Double [5]Helicenes as Cathode Active Materials for Lithium Batteries2019

    • Author(s)
      Oda Susumu、Shimizu Takeshi、Katayama Takazumi、Yoshikawa Hirofumi、Hatakeyama Takuji
    • Journal Title

      Organic Letters

      Volume: 21 Issue: 6 Pages: 1770-1773

    • DOI

      10.1021/acs.orglett.9b00337

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiple hetero-atom substitution to Graphene Nanoribbon2018

    • Author(s)
      S. Kawai, S. Nakatsuka, T. Hatakeyama, R. Pawlak, T, Meier, J. Tracey, E. Meyer, and A. S. Foster
    • Journal Title

      Science Advances

      Volume: 4 Issue: 4

    • DOI

      10.1126/sciadv.aar7181

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Triangulene-based Efficient Exciton Blocking Material for Organic Light-emitting Diodes2018

    • Author(s)
      Gotoh Hajime、Nakatsuka Soichiro、Kondo Yasuhiro、Sasada Yasuyuki、Hatakeyama Takuji
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 7 Pages: 920-922

    • DOI

      10.1246/cl.180314

    • NAID

      130007402788

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Four-Step Synthesis of B2N2-Embedded Corannulene2018

    • Author(s)
      Nakatsuka Soichiro、Yasuda Nobuhiro、Hatakeyama Takuji
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 42 Pages: 13562-13565

    • DOI

      10.1021/jacs.8b08197

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] One-Shotホウ素化による七員環を有する含BN多環芳香族化合物の合成2021

    • Author(s)
      青山明生・小田晋・畠山琢次
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 高色純度青色蛍光を示す含BNO多環芳香族化合物の合成と応用2021

    • Author(s)
      山崎雄暉・小田晋・畠山琢次
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 多重共鳴効果を鍵とした次世代の高色純度発光材料の開発2020

    • Author(s)
      畠山琢次
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Multiple Resonance Effect-Based Narrowband TADF Emitters2020

    • Author(s)
      Takuji Hatakeyama
    • Organizer
      The 27th International Display Workshops (IDW’20)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 多重共鳴効果を利用した超高色純度熱活性化遅延蛍光材料の開発2020

    • Author(s)
      畠山琢次
    • Organizer
      日本学術振興会光電相互変換第125委員会セミナー
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] タンデムヘテロFriedel-Crafts反応が拓く新材料化学2020

    • Author(s)
      畠山琢次
    • Organizer
      明治大学理工学部講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 含BPNコランニュレン誘導体の合成2020

    • Author(s)
      大矢 遥花,中塚 宗一郎,畠山 琢次
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] シアノ基を有するDABNA誘導体の合成と物性2020

    • Author(s)
      杉谷 拓己,田中 裕之,田端 敬太,畠山 琢次
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 脱芳香族化を伴うホウ素化反応による含BNヘキサベンゾコロネンの合成2020

    • Author(s)
      山本 健寛,阿部 紘明,後藤 玄,中塚 宗一郎,小田 晋,畠山 琢次
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高色純度青色蛍光を示す含BNO多環芳香族化合物の合成と応用2020

    • Author(s)
      上田 悠太,小田 晋,畠山 琢次
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 超高色純度青色熱活性化遅延蛍光材料の開発2020

    • Author(s)
      畠山琢次
    • Organizer
      第379回蛍光体同学会講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] タンデムボラFriedel-Crafts反応が拓く新材料化学2019

    • Author(s)
      畠山琢次
    • Organizer
      大阪府立大学白鷺セミナー
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] タンデムボラFriedel-Crafts反応を鍵とした有機エレクトロニクス材料の開発2019

    • Author(s)
      畠山琢次
    • Organizer
      富士フイルム有機合成化学研究所講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Development of DABNA and beyond2019

    • Author(s)
      Takuji Hatakeyama
    • Organizer
      Samsung Display講演会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高色純度青色熱活性化遅延蛍光材料の開発2019

    • Author(s)
      畠山琢次
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] タンデムボラFriedel-Crafts反応を鍵とした有機エレクトロニクス材料の開発2019

    • Author(s)
      畠山琢次
    • Organizer
      第116回有機合成シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 超高色純度熱活性化遅延蛍光材料の開発2019

    • Author(s)
      畠山琢次
    • Organizer
      第5回統合物質創製化学研究機構シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Physical Properties of Triangulenes Containing Group 14 Elements at the Center2019

    • Author(s)
      Hajime Gotoh, Soichiro Nakatsuka, Takuji Hatakeyama
    • Organizer
      International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Physical Properties of Antimony-Centered Triangulene2019

    • Author(s)
      Hajime Gotoh, Soichiro Nakatsuka, Keisuke Kinoshita, Nobuhiro Yasuda, Takuji Hatakeyama
    • Organizer
      The 18th International Symposium on Novel Aromatic Compounds (ISNA-18)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Physical Properties of Tetracoordinate Boron-Fused Double Helicenes2019

    • Author(s)
      Susumu Oda, Takeshi Shimizu, Takazumi Katayama, Hirofumi Yoshikawa, Takuji Hatakeyama
    • Organizer
      The 18th International Symposium on Novel Aromatic Compounds (ISNA-18)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高色純度緑色熱活性化遅延蛍光を示す含BNO多環芳香族化合物の合成2019

    • Author(s)
      池田 尚矢,吉浦 一基,小田 晋,畠山 琢次
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高色純度青色発光を示す含BNO多環芳香族化合物の合成2019

    • Author(s)
      上田 悠太,小森 崇央,吉浦 一基,小田 晋,畠山 琢次
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] One-Shot多重ホウ素化反応による含BNヘリセンの合成2019

    • Author(s)
      川上 文吾,中塚 宗一郎,小田 晋,畠山 琢次
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis and Physical Properties of Tetracoordinate Boron-Fused Double Helicenes2019

    • Author(s)
      Susumu Oda, Takeshi Shimizu, Takazumi Katayama, Hirofumi Yoshikawa, Takuji Hatakeyama
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] カルバゾール環を有するDABNA誘導体の合成と物性2019

    • Author(s)
      熊野 航,吉浦 一基,松井 晃平,小田 晋,畠山 琢次
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 4配位ホウ素を中心に有するスピロ化合物への置換基導入による物性制御2019

    • Author(s)
      濵 俊輝,亀田 麻由,木寺 紗友里,畠山 琢次
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ボロン酸エステルおよび超原子価ヨウ素を有する多環芳香族化合物の合成2019

    • Author(s)
      山本 健寛,中塚 宗一郎,畠山 琢次
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多重共鳴効果を利用した高色純度熱活性化遅延蛍光材料の開発2018

    • Author(s)
      畠山琢次
    • Organizer
      2018年度有機エレクトロニクスシンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] タンデムボラFriedel-Crafts反応が拓く新材料化学2018

    • Author(s)
      畠山琢次
    • Organizer
      第53回有機反応若手の会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Development of Ultrapure Blue TADF Materials by Multiple Resonance Effect2018

    • Author(s)
      Takuji Hatakeyama
    • Organizer
      19th International Workshop on Inorganic and Organic Electroluminescence (EL2018) & 2018 International Conference on the Science and Technology of Emitting Displays and Lighting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of BN-embedded Corannulene via Electrophilic C-H Borylation2018

    • Author(s)
      Soichiro Nakatsuka, Takuji Hatakeyama
    • Organizer
      16th Boron Chemistry Meeting in the Americas (BORAM XVI)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-Shot Multiple Borylation toward BN-Doped Nanographenes2018

    • Author(s)
      Susumu Oda, Kohei Matsui, Kazuki Yoshiura, Takuji Hatakeyama
    • Organizer
      16th Boron Chemistry Meeting in the Americas (BORAM XVI)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-shot Multiple Borylation toward BN-Doped Nanographenes and Corannulenes2018

    • Author(s)
      Takuji Hatakeyama
    • Organizer
      The 13th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-13)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 求電子的 C-Hホウ素反応による含BNコランニュレンの合成2018

    • Author(s)
      中塚 宗一郎,畠山 琢次
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多重ホウ素化反応による含BNナノグラフェンの短段階合成2018

    • Author(s)
      小田 晋,松井 晃平,吉浦 一基,畠山 琢次
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 中心に高周期14族元素を有するトリアンギュレン類縁体の合成と物性2018

    • Author(s)
      後藤 玄,畠山 琢次
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高色純度熱活性化遅延蛍光を示す含BN多環芳香族化合物の合成2018

    • Author(s)
      吉浦 一基,小田 晋,畠山 琢次
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 4配位ホウ素を中心に有するスピロ化合物の合成と物性2018

    • Author(s)
      亀田 麻由,中塚 宗一郎,畠山 琢次
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] フェノキサボリン類縁体の合成と青色有機EL素子用ホスト材料としての応用2018

    • Author(s)
      木寺 紗友里,後藤 玄,畠山 琢次
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://sci-tech.ksc.kwansei.ac.jp/~hatakeyama/index.html

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report

URL: 

Published: 2018-04-23   Modified: 2024-12-25  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi