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The impact of electron-phonon coupling on the electron localization of molecular assemble

Research Project

Project/Area Number 18H03904
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 32:Physical chemistry, functional solid state chemistry, and related fields
Research InstitutionInstitute for Molecular Science

Principal Investigator

Kera Satoshi  分子科学研究所, 光分子科学研究領域, 教授 (10334202)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥44,070,000 (Direct Cost: ¥33,900,000、Indirect Cost: ¥10,170,000)
Fiscal Year 2020: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2019: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2018: ¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Keywords有機半導体 / 電子フォノン相互作用 / 光電子分光 / シンクロトロン放射光 / 電子状態 / 表面界面物性 / 電荷輸送 / 準位接合 / 分子集合体 / 波動関数
Outline of Final Research Achievements

We investigated the electronic state of the surface and interface of molecular thin films in which semiconductor functions are expected by high-sensitivity ultraviolet photoelectron spectroscopy (UPS) and high-resolution angle-resolved UPS using synchrotron radiation. The correlation between the adsorption structure and the electronic state due to weak van der Waals interaction was precisely evaluated by making full use of various analytical methods, and the mechanism of function and materials properties was discussed from the viewpoint of electron localization. We also succeeded in evaluating the localization of conduction band structure for the first time for organic-inorganic hybrid perovskite crystal, which is expected as next-generation energy conversion materials.

Academic Significance and Societal Importance of the Research Achievements

機能分子関連の複雑な薄膜の集合構造を最適化することで物理現象を整理し、各種電子状態の精密計測に成功した。弱い相互作用やフォノン(分子振動)が電子の局在性に及ぼす影響を実験的に検出し、その重要性を見出すことに成功した。柔らかな物質系に対する既存の概念に基づく近似的な物理モデルを打破する必要性が明確になり、今後の理論的な発展や分子デバイスへの応用展開における設計指針を与える点で社会的貢献があった。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (51 results)

All 2021 2020 2019 2018 Other

All Int'l Joint Research (11 results) Journal Article (21 results) (of which Int'l Joint Research: 14 results,  Peer Reviewed: 21 results,  Open Access: 7 results) Presentation (18 results) (of which Int'l Joint Research: 12 results,  Invited: 16 results) Remarks (1 results)

  • [Int'l Joint Research] 揚州大学(中国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] イエナ大学/フンボルト大学(ドイツ)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] リンショーピン大学(スウェーデン)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] 揚州大学/蘇州大学(中国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] イエナ大学/ユーリッヒ総合研究機構/フンボルト大学ベルリン(ドイツ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] アリゾナ州立大学(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] モントリオール大学(カナダ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] イエナ大学/ユーリッヒ研究所/チュービンゲン大学(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] 蘇州大学(中国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ワイツマン研究所(イスラエル)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] アリゾナ大学(米国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Accessing the Conduction Band Dispersion in CH3NH3PbI3 Single Crystals2021

    • Author(s)
      Yang Jinpeng、Sato Haruki、Orio Hibiki、Liu Xianjie、Fahlman Mats、Ueno Nobuo、Yoshida Hiroyuki、Yamada Takashi、Kera Satoshi
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 12 Issue: 15 Pages: 3773-3778

    • DOI

      10.1021/acs.jpclett.1c00530

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Experimental Observation of Anisotropic Valence Band Dispersion in Dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophene (DNTT) Single Crystals2021

    • Author(s)
      Takeuchi Riku、Izawa Seiichiro、Hasegawa Yuri、Tsuruta Ryohei、Yamaguchi Takuma、Meissner Matthias、Ideta Shin-ichiro、Tanaka Kiyohisa、Kera Satoshi、Hiramoto Masahiro、Nakayama Yasuo
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 125 Issue: 5 Pages: 2938-2943

    • DOI

      10.1021/acs.jpcc.0c09239

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Soluble CsPbBr3 Perovskite Quantum Dots for Solution-Processed Light-Emission Devices2021

    • Author(s)
      Liu Yongfeng、Tang Shi、Fan Junpeng、Gracia-Espino Eduardo、Yang Jinpeng、Liu Xianjie、Kera Satoshi、Fahlman Mats、Larsen Christian、Wagberg Thomas、Edman Ludvig、Wang Jia
    • Journal Title

      ACS Applied Nano Materials

      Volume: 4 Issue: 2 Pages: 1162-1174

    • DOI

      10.1021/acsanm.0c02797

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bulk and Surface Band Dispersion Mapping of the Au(111) Surface by Acceptance-cone Tunable PES System2020

    • Author(s)
      Matsui Fumihiko、Makita Seiji、Matsuda Hiroyuki、Ueba Takahiro、Horigome Toshio、Yamane Hiroyuki、Tanaka Kiyohisa、Kera Satoshi、Kosugi Nobuhiro
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 18 Issue: 0 Pages: 18-23

    • DOI

      10.1380/ejssnt.2020.18

    • NAID

      130007795888

    • ISSN
      1348-0391
    • Year and Date
      2020-02-08
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Temperature-dependent band structure evolution determined by surface geometry in organic halide perovskite single crystals2020

    • Author(s)
      Yang Jinpeng、Meissner Matthias、Yamaguchi Takuma、Xi Bin、Takahashi Keishi、Rahman Shed A. Abd.、Liu Xianjie、Yoshida Hiroyuki、Fahlman Mats、Kera Satoshi
    • Journal Title

      Physical Review B

      Volume: 102 Issue: 24

    • DOI

      10.1103/physrevb.102.245101

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Role of Initial and Final States in Molecular Spectroscopies: Example of Tetraphenyldibenzoperiflanthene (DBP) on Graphite2020

    • Author(s)
      Kirchhuebel Tino、Kera Satoshi、Munakata Toshiaki、Ueno Nobuo、Shiraishi Ryo、Yamaguchi Takuma、Yonezawa Keiichirou、Ueba Takahiro、Bussolotti Fabio、Yang Jinpeng、Yamada Takashi、Mori Ryosuke、Kunieda Shogo、Huempfner Tobias、Gruenewald Marco、Forker Roman、Fritz Torsten
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 36 Pages: 19622-19638

    • DOI

      10.1021/acs.jpcc.0c05448

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photoelectron Momentum Microscope at BL6U of UVSOR-III synchrotron2020

    • Author(s)
      Matsui Fumihiko、Makita Seiji、Matsuda Hiroyuki、Yano Takayuki、Nakamura Eiken、Tanaka Kiyohisa、Suga Shigemasa、Kera Satoshi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: 6 Pages: 067001-067001

    • DOI

      10.35848/1347-4065/ab9184

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrostatic Interactions Shape Molecular Organization and Electronic Structure of Organic Semiconductor Blends2020

    • Author(s)
      D’Avino Gabriele、Duhm Steffen、Della Valle Raffaele Guido、Heimel Georg、Oehzelt Martin、Kera Satoshi、Ueno Nobuo、Beljonne David、Salzmann Ingo
    • Journal Title

      Chemistry of Materials

      Volume: 32 Issue: 3 Pages: 1261-1271

    • DOI

      10.1021/acs.chemmater.9b04763

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Valence band dispersion measured in the surface normal direction of CH3NH3PbI3 single crystals2019

    • Author(s)
      Yang Jin-Peng、Ren Si-Xian、Yamaguchi Takuma、Meissner Matthias、Cheng Li-wen、Zhou Lei、Ideta Shinichiro、Tanaka Kiyohisa、Kera Satoshi
    • Journal Title

      Applied Physics Express

      Volume: 13 Issue: 1 Pages: 011009-011009

    • DOI

      10.7567/1882-0786/ab6134

    • NAID

      210000157799

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Acceptance-cone-tunable electron spectrometer for highly-efficient constant energy mapping2019

    • Author(s)
      Yamane Hiroyuki、Matsui Fumihiko、Ueba Takahiro、Horigome Toshio、Makita Seiji、Tanaka Kiyohisa、Kera Satoshi、Kosugi Nobuhiro
    • Journal Title

      Review of Scientific Instruments

      Volume: 90 Issue: 9 Pages: 093102-093102

    • DOI

      10.1063/1.5109453

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Well-Ordered Monolayer Growth of Crown-Ether Ring Molecules on Cu(111) in Ultra-High Vacuum: An STM, UPS, and DFT Study2019

    • Author(s)
      Nemoto Ryohei、Kr?ger Peter、Putri Hartini Ayu Novita、Hosokai Takuya、Horie Masaki、Kera Satoshi、Yamada Toyo Kazu
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 31 Pages: 18939-18950

    • DOI

      10.1021/acs.jpcc.9b03335

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Gap states induce soft Fermi level pinning upon charge transfer at ZnO/molecular acceptor interfaces2019

    • Author(s)
      Schlesinger Raphael、Bussolotti Fabio、Yang Jinpeng、Sadofev Sergey、Vollmer Antje、Blumstengel Sylke、Kera Satoshi、Ueno Nobuo、Koch Norbert
    • Journal Title

      Physical Review Materials

      Volume: 3 Issue: 7

    • DOI

      10.1103/physrevmaterials.3.074601

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electronic band dispersion determination in azimuthally disordered transition-metal dichalcogenide monolayers2019

    • Author(s)
      Park S.、Schultz T.、Han A.、Aljarb A.、Xu X.、Beyer P.、Opitz A.、Ovsyannikov R.、Li L.-J.、Meissner M.、Yamaguchi T.、Kera S.、Amsalem P.、Koch N.
    • Journal Title

      Communications Physics

      Volume: 2 Issue: 1

    • DOI

      10.1038/s42005-019-0166-0

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] The role of initial and final states in molecular spectroscopies2019

    • Author(s)
      Kirchhuebel Tino、Monti Oliver L. A.、Munakata Toshiaki、Kera Satoshi、Forker Roman、Fritz Torsten
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 21 Issue: 24 Pages: 12730-12747

    • DOI

      10.1039/c8cp07318j

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Widely Dispersed Intermolecular Valence Bands of Epitaxially Grown Perfluoropentacene on Pentacene Single Crystals2019

    • Author(s)
      Nakayama Yasuo、Tsuruta Ryohei、Moriya Naoki、Hikasa Masataka、Meissner Matthias、Yamaguchi Takuma、Mizuno Yuta、Suzuki Toshiyasu、Koganezawa Tomoyuki、Hosokai Takuya、Ueba Takahiro、Kera Satoshi
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 10 Issue: 6 Pages: 1312-1318

    • DOI

      10.1021/acs.jpclett.8b03866

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular parameters responsible for thermally activated transport in doped organic semiconductors2019

    • Author(s)
      Schwarze Martin、Gaul Christopher、Scholz Reinhard、Bussolotti Fabio、Hofacker Andreas、Schellhammer Karl Sebastian、Nell Bernhard、Naab Benjamin D.、Bao Zhenan、Spoltore Donato、Vandewal Koen、Widmer Johannes、Kera Satoshi、Ueno Nobuo、Ortmann Frank、Leo Karl
    • Journal Title

      Nature Materials

      Volume: 18 Issue: 3 Pages: 242-248

    • DOI

      10.1038/s41563-018-0277-0

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Modification of TiO2(110)/organic hole transport layer interface energy levels by a dipolar perylene derivative2018

    • Author(s)
      Winkler Stefanie、Xin Qian、Li Chen、Kera Satoshi、Mullen Klaus、Ueno Nobuo、Koch Norbert、Duhm Steffen
    • Journal Title

      Electronic Structure

      Volume: 1 Issue: 1 Pages: 015007-015007

    • DOI

      10.1088/2516-1075/aada95

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Anisotropic valence band dispersion of single crystal pentacene as measured by angle-resolved ultraviolet photoelectron spectroscopy2018

    • Author(s)
      Nakayama Yasuo、Hikasa Masataka、Moriya Naoki、Meissner Matthias、Yamaguchi Takuma、Yoshida Koki、Murata Mimi、Mase Kazuhiko、Ueba Takahiro、Kera Satoshi
    • Journal Title

      Journal of Materials Research

      Volume: 33 Issue: 20 Pages: 3362-3370

    • DOI

      10.1557/jmr.2018.315

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Band Dispersion and Hole Effective Mass of Methylammonium Lead Iodide Perovskite2018

    • Author(s)
      Yang Jin-Peng、Meissner Matthias、Yamaguchi Takuma、Zhang Xiu-Yun、Ueba Takahiro、Cheng Li-Wen、Ideta Shinichiro、Tanaka Kiyohisa、Zeng Xiang-Hua、Ueno Nobuo、Kera Satoshi
    • Journal Title

      Solar RRL

      Volume: 2 Issue: 10 Pages: 1800132-1800132

    • DOI

      10.1002/solr.201800132

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Probing Triplet Excited States and Managing Blue Light Emission of Neutral Tetradentate Platinum(II) Complexes2018

    • Author(s)
      You Cong、Xia Fang、Zhao Yue、Zhang Yin、Sheng Yongjian、Wu Yipei、Hang Xiao-Chun、Chen Fei、Ma Huili、Shen Kang、Sun Zhengyi、Ueba Takahiro、Kera Satoshi、Zhang Cong、Zhang Honghai、Chen Zhi-Kuan、Huang Wei
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 9 Issue: 9 Pages: 2285-2292

    • DOI

      10.1021/acs.jpclett.8b00797

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The Evolution of Intermolecular Energy Bands of Occupied and Unoccupied Molecular States in Organic Thin Films2018

    • Author(s)
      Yuki Kashimoto, Keiichirou Yonezawa, Matthias Meissner, Marco Gruenewald, Takahiro Ueba, Satoshi Kera, Roman Forker, Torsten Fritz, Hiroyuki Yoshida
    • Journal Title

      J. Phys. Chem. C (ACS editors' choice)

      Volume: 未定 Issue: 22 Pages: 12090-12097

    • DOI

      10.1021/acs.jpcc.8b02581

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Soft-X-ray photoelectron momentum microscopy for selective atomic/molecular orbital excitation2020

    • Author(s)
      F. Matsui, S. Makita, H. Matsuda, Y. Okano, T. Yano, E. Nakamura, S. Suga, Y. Hasegawa, S. Kera
    • Organizer
      Next generation spectro-microscopy and micro-spectroscopy workshop
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Twisted bilayer graphene with clean interface by direct transfer of CVD graphene2020

    • Author(s)
      H. Imamura, R. Uotani, A. Visikovskiy, T. Iimori, T. Miyamachi, K. Nakatsuji, K. Mase, K. Horiba, T. Shirasawa, S. Kera, F. Komori, S. Tanaka
    • Organizer
      Graphene2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoelectron spectroscopy of semiconducting organic molecules2019

    • Author(s)
      解良 聡
    • Organizer
      18th European Conference on Applications of Surface and interface Analysis (ECASIA)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Evolution of pi orbital state upon assembling the molecules on the surface2019

    • Author(s)
      解良 聡
    • Organizer
      14th International Symposium on Functional pi-electron Systems (FP14)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Energy and spatial distribution of frontier orbital state for organic thin films2019

    • Author(s)
      解良 聡
    • Organizer
      2nd International Conference on Materials research and Innovation (ICMARI)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A perspective of frontier orbital state for weakly bound molecules on the surface2019

    • Author(s)
      解良 聡
    • Organizer
      25th Users' Meeting & Workshops at NSRRC
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機半導体の輸送電荷の特徴:光電子分光法による電子状態測定から2019

    • Author(s)
      解良 聡
    • Organizer
      第4回固体化学フォーラム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 有機半導体分子の電子状態の特徴とその局在性の変遷2019

    • Author(s)
      解良 聡
    • Organizer
      日本学術振興会マイクロビームアナリシス第141委員会第176回研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 分子集合体における電子局在性2019

    • Author(s)
      解良 聡
    • Organizer
      第17回SPring-8ユーザー協同体 顕微ナノ材料科学研究会合同シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 有機半導体結晶における電子格子相互作用2019

    • Author(s)
      解良 聡
    • Organizer
      第32回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 分子性結晶の電子状態の特徴:局在性の変遷2018

    • Author(s)
      解良 聡
    • Organizer
      第79回応用物理学会秋季学術講演会(シンポジウム)
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 紫外光電子分光法による有機半導体の物性・機能評価2018

    • Author(s)
      解良 聡
    • Organizer
      日本物理学会2018年秋季年会(シンポジウム:有機半導体の構造・キャリア輸送制御の最前線)
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Electronic band dispersion of perovskite single crystal: MAPbI32018

    • Author(s)
      Satoshi Kera
    • Organizer
      International Workshop on Organic Semiconductors and Related Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Evolution of electron localization upon assembling the molecules on the surface2018

    • Author(s)
      Satoshi Kera
    • Organizer
      9th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Charge delocalization upon molecular assembly2018

    • Author(s)
      Satoshi Kera
    • Organizer
      9th International Workshop on Low Enerfgy Electron Diffraction and Related Techniques
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Exploring function and property of organic materials by photoelectron spectroscopy2018

    • Author(s)
      Satoshi Kera
    • Organizer
      Recent Progress of Organic Electronics in Japan and Korea
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Impacts of charge relaxation on the energy-level alignment: Tin(IV)phthalocyanine dichloride monolayer on graphite2018

    • Author(s)
      Satoshi Kera
    • Organizer
      The 9th International Conference on Thechnological Advances of Thin Films and Surface Coatings
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Evolution of Electron Localization upon Molecular Assembling2018

    • Author(s)
      Satoshi Kera
    • Organizer
      International Symposium on Spectroscopy and Dynamics at Surface and Interface
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 研究室サイト

    • URL

      https://groups.ims.ac.jp/organization/kera_g/

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report 2018 Annual Research Report

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Published: 2018-04-23   Modified: 2022-01-27  

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