| Budget Amount *help |
¥43,030,000 (Direct Cost: ¥33,100,000、Indirect Cost: ¥9,930,000)
Fiscal Year 2022: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2021: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2020: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2018: ¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
|
|---|
| Outline of Final Research Achievements |
Structurally constrained multinuclear metal assemblies are important functional modules for atomically precise nano-structured molecular devices. This project utilized multidentate phosphine ligands to establish fine-tunable molecular designs of dimensionally controlled multinuclear transition metal systems with new functions, and carried out (1) synthesis of systematic linear tetraphosphine ligands containing PCP and PNP units, that have been applied to the studies on (2) low-valent Pd and Pt molecular matallic chains and their reactions and property through 1D self-assembly, (3) synthesis of d10 and d8 closed-shell metal centers and their reactions and property, and (4) multinuclear copper hydride complexes and their utilization in catalytic hydrogenation of carbon dioxide and decomposition of formic acid.
|
