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Development of metallic conduction and molecular insertion in one-dimensional metal complexes

Research Project

Project/Area Number 18J13022
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Inorganic chemistry
Research InstitutionTohoku University

Principal Investigator

Mian Mohammad Rasel  東北大学, 材料科学高等研究所, 特別研究員(PD)

Project Period (FY) 2018-04-25 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥800,000 (Direct Cost: ¥800,000)
Keywordscrystalligraphy / synthesis / coordination polymer / chain complex / metal-organic-framework / conductivity / catalysis / gas uptake / One-dimension sysmetm / Pd chain / Pt chain / halogen-bridged / infinite structure / optical gap / Raman spectrocopy
Outline of Annual Research Achievements

Recently, organic-inorganic hybrids materials have been researchers’ interest due to their tunable structure and switching physical properties. Solid-state hybrid materials are very promising in the field for fundamental and applied sciences.
I prepared halogen-bridged 1D Pd/Pt chain complexes (MX-chain) as multifunctional materials. Pd and Pt-based MX-chain complexes usually show M(II)/M(IV) mixed-valance (MV) state due to the small on-site coulomb repulsion. I developed new method for realize uncommon Pd(III) AV state, [Pd(dabdOH)2Br]Br2 (dabdOH =(2S,3S)-2,3-diaminobutane-1,4-diol), so-called "multiple-hydogen-bond” approach (J. Am. Chem. Soc. 2017, 39, 6562). Electronic state Pt ions are in MV state using same strategy. However, this method is very promising for shortening metal-metal distance, resulting good conducting materials (Inorg. Chem, 2019, 58, 114). Moreover, this method is also applicable for large size counters anion. Pd(III) ions was isolated with sulfate ions via this method (CryEngComm, 2020, Submitted).
Currently, I extended my work into two or three-dimensional (2D or 3D) hybrid materials (MOFs). I was able to growth and control copper nano particle (CuNPs) size into MOFs. For example, NU-901 and NU-907, with distinct pore diameters that serve as templates for the controlled growth of CuNPs of different sizes (~1.5 nm and ~0.9 nm, respectively). These MOF-supported CuNPs were shown to be competent catalysts for selective acetylene semihydrogenation with a TOF of 13.5 and 7.7 h-1, respectively (Chem. Mat. 2020, 10.1021/acs.chemmater.0c00059).

Research Progress Status

令和元年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和元年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (9 results)

All 2020 2019 2018

All Journal Article (8 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (1 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Tuning the Redox Activity of Metal-Organic Frameworks for Enhanced, Selective O2 Binding: Design Rules and Ambient Temperature O2 Chemisorption in a Cobalt-Triazolate Framework2020

    • Author(s)
      Andrew S Rosen, Mohammad Rasel Mian, Timur Islamoglu, Haoyuan Chen, Omar K Farha, Justin M Notestein, Randall Q Snurr
    • Journal Title

      Journal of the American Chemical Society

      Volume: 142 Issue: 9 Pages: 4317-4328

    • DOI

      10.1021/jacs.9b12401

    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] Metal-Organic Frameworks against Toxic Chemicals2020

    • Author(s)
      Timur Islamoglu, Zhijie Chen, Megan C Wasson, Cassandra T Buru, Kent O Kirlikovali, Unjila Afrin, Mohammad Rasel Mian, Omar K Farha
    • Journal Title

      Chemical Review

      Volume: soon Issue: 16 Pages: 8130-8160

    • DOI

      10.1021/acs.chemrev.9b00828

    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] Precise Control of Cu Nanoparticle Size and Catalytic Activity through Pore Templating in Zr Metal-Organic Frameworks2020

    • Author(s)
      Mohammad Rasel Mian, Louis R Redfern, Saied Md Pratik, Debmalya Ray, Jian Liu, Karam B Idrees, Timur Islamoglu, Laura Gagliardi, Omar K Farha
    • Journal Title

      Chemistry of Materials

      Volume: soon Issue: 7 Pages: 3078-3086

    • DOI

      10.1021/acs.chemmater.0c00059

    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] MX-type single chain complexes with an aromatic in-plane ligand: incorporation of aromatic interactions for stabilizing the chain structure2019

    • Author(s)
      Afrin Unjila、Iguchi Hiroaki、Mian Mohammad Rasel、Takaishi Shinya、Yamakawa Hiromichi、Terashige Tsubasa、Miyamoto Tatsuya、Okamoto Hiroshi、Yamashita Masahiro
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 22 Pages: 7828-7834

    • DOI

      10.1039/c9dt00784a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Observation of charge bistability in quasi-one-dimensional halogen-bridged palladium complexes by X-ray absorption spectroscopy2019

    • Author(s)
      Takefumi Yoshida, Shinya Takaishi, Shohei Kumagai, Hiroaki Iguchi, Mohammad Rasel Mian, Masahiro Yamashita
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 31 Pages: 11628-11631

    • DOI

      10.1039/c9dt01684h

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Smallest Optical Gap for Pt(II)?Pt(IV) Mixed-Valence Pt?Cl and Pt?Br Chain Complexes Achieved by Using a Multiple-Hydrogen-Bond Approach2019

    • Author(s)
      Mian M. Rasel、Iguchi H.、Takaishi S.、Afrin U.、Miyamoto T.、Okamoto H.、Yamashita M.
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 1 Pages: 114-120

    • DOI

      10.1021/acs.inorgchem.8b01910

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Vanadyl β-tetrabromoporphyrin: synthesis, crystal structure and its use as an efficient and selective catalyst for olefin epoxidation in aqueous medium2019

    • Author(s)
      Tawseef Ahmad Dar, Reshu Tomar, Rasel Mohammad Mian, Muniappan Sankar and Mannar Ram Maurya
    • Journal Title

      RSC Advances

      Volume: 9 Issue: 18 Pages: 10405-10413

    • DOI

      10.1039/c8ra09825e

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhancement of electrocatalytic abilities for reducing carbon dioxide: Functionalization with a redox-active ligand-coordinated metal complex2018

    • Author(s)
      Habib Md. Ahsan, Brian K. Breedlove, Santivongskul Piangrawee, Mohammad Rasel Mian, Ahmed Fetoh, Goulven Cosquer and Masahiro Yamashita
    • Journal Title

      Dalton Transactions

      Volume: 47 Issue: 33 Pages: 11313-11316

    • DOI

      10.1039/c8dt02288g

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Multiple-Hydrogen-Bond Approach to Control the Oxidation State of Pd in MX Complexes2018

    • Author(s)
      Mohammad Rasel Mian, Masahiro Yamashita
    • Organizer
      43rd Interanational Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2018-05-01   Modified: 2024-03-26  

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