• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

共有結合性有機骨格構造体の分子設計とCO2吸着・分離機能の開拓

Research Project

Project/Area Number 18J13699
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Polymer chemistry
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

LI Zhongping  北陸先端科学技術大学院大学, 先端科学技術研究科, 特別研究員(DC2)

Project Period (FY) 2018-04-25 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2019: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 2018: ¥800,000 (Direct Cost: ¥800,000)
KeywordsCOF / 二酸化炭素
Outline of Annual Research Achievements

For the final year, the ionic porous organic polymers (i-POPs) have been successfully synthesized via a facile Friedel-Crafts alkylation reaction and cost-effective process. The i-POPs were constructed through the natural building units (4,4'-bis(chloromethyl)-1,1'-biphenyl, BP) as a crosslinking agent and ionic building unit (1,1'-([1,1'-biphenyl]-4,4'-diyl)bis(N,N,N-trimethylmethanaminium) chloride, BPTM) under solvothermal conditions by FeCl3 as the catalyst. With the increment of the ionic unit, the i-POP-1, i-POP-2, and i-POP-3 were successfully synthesized under the same condition. The i-POPs indicated excellent porosity including the highest BET surface area (1491-1753 m2 g-1) and pore volume (2.19-2.94 cm3 g-1) among all reported ionic frameworks. At 273 K and 1 bar, i-POP-1 displayed high carbon dioxide uptake of 14.0 wt%.

Research Progress Status

令和元年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和元年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • Research Products

    (6 results)

All 2019 2018 Other

All Int'l Joint Research (3 results) Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (2 results)

  • [Int'l Joint Research] Dalian Institute of Chemical Physics(中国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] シンガポール国立大学(シンガポール)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Oak Ridge National Laboratory/University of Tennessee(米国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Light-Emitting Covalent Organic Frameworks: Fluorescence Improving via Pinpoint Surgery and Selective Switch-On Sensing of Anions2018

    • Author(s)
      Zhongping Li, Ning Huang, La Hung Lee, Yu Feng, Shanshan Tao, Qiuhong Jiang, Yuki Nagao, Stephan Irle, Donglin Jiang
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 140 Issue: 39 Pages: 12374-12377

    • DOI

      10.1021/jacs.8b08380

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Design of Cost-Effective Synthesis Sulfonated Porous Organic Polymer for Proton Conductivity2019

    • Author(s)
      Z. Li, Y. Nagao
    • Organizer
      日本化学会化近畿支部 北陸地区 講演会と研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Designing Covalent Organic Frameworks for Light emitting and Anion Sensing2019

    • Author(s)
      Z. Li, Y. Nagao, D. Jiang
    • Organizer
      The 99th CSJ Annual Meeting
    • Related Report
      2018 Annual Research Report

URL: 

Published: 2018-05-01   Modified: 2024-03-26  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi