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Experimental determination of the dependence of some parameters on the generation of iodine molecules in gas phase by the photolysis of iodide ions.

Research Project

Project/Area Number 18K03740
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 17020:Atmospheric and hydrospheric sciences-related
Research InstitutionTokyo Gakugei University

Principal Investigator

NAKANO Yukio  東京学芸大学, 教育学部, 准教授 (50364112)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsヨウ素循環 / 地球温暖化 / エアロゾル / 高感度分光法 / 大気化学
Outline of Final Research Achievements

Once iodine molecules released into the atmosphere which causes the formation of iodine aerosols when they are. The photolysis of iodide ions in the ocean is considered as a candidate as a new process for the formation of iodine molecules in the atmosphere, However, the effect of this generation process on the atmosphere has not yet been evaluated. In this study, the dependence of each parameter on ocean conditions such as hydrogen ion index, dissolved oxygen amount, iodide ion concentration on the iodine molecules generation by this generation process study was investigated using a high-sensitivity spectrometric method. Using the results, we conducted model calculations and evaluated the impact of this generation process on the actual atmosphere.

Academic Significance and Societal Importance of the Research Achievements

本研究で対象とした海洋中のヨウ化物イオンの光分解過程は,大気中のヨウ素化合物の生成過程の一つである。この生成過程はヨウ素エアロゾル生成に大きく可能性があるが、今までその影響力の正確な評価はできていなかった。本研究の結果、この生成過程が大気中のヨウ素化合物の生成源として重要な役割を果たしていることが新たにわかった。大気中のヨウ素化合物はヨウ素エアロゾル生成を引き起こし、地球温暖化に影響を与える要因である。そのため、本研究成果は地球温暖化の将来予想の高精度化にも貢献するものである。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (3 results)

All 2019 2018 Other

All Int'l Joint Research (1 results) Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results) Presentation (1 results) (of which Int'l Joint Research: 1 results)

  • [Int'l Joint Research] Spanish National Research Council (CSIC)(スペイン)

    • Related Report
      2018 Research-status Report
  • [Journal Article] Experimental determination of the photooxidation of aqueous I- as a source of atmospheric I22019

    • Author(s)
      Kosuke Watanabe, Shohei Matsuda, Carlos A. Cuevas, Alfonso Saiz-Lopez, Akihiro Yabushita, Yukio Nakano
    • Journal Title

      ACS Earth and Space Chemistry

      Volume: 印刷中 Issue: 4 Pages: 669-679

    • DOI

      10.1021/acsearthspacechem.9b00007

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Measurement of effective quantum yields for the photolysis of aqueous I- and estimation of atmospheric I2 emission rate2018

    • Author(s)
      Kosuke Watanabe, Shohei Matsuda, Carlos A. Cuevas, Alfonso Saiz-Lopez, Akihiro Yabushita, Yukio Nakano
    • Organizer
      2018 joint 14th iCACGP Quadrennial Symposium and 15th IGAC Science Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research

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Published: 2018-04-23   Modified: 2022-01-27  

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