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High performance of solar cells by developing colloidal quantum dot superlattice film

Research Project

Project/Area Number 18K04972
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 30020:Optical engineering and photon science-related
Research InstitutionYokohama National University

Principal Investigator

Mukai Kohki  横浜国立大学, 大学院工学研究院, 教授 (10361867)

Project Period (FY) 2018-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2020: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2019: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2018: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords量子ドット / 超格子 / 太陽電池 / コロイド型 / 沈降法 / PbS / エネルギー変換効率 / キャリア寿命 / 配位子交換 / 超格子膜 / 発光寿命 / 高効率
Outline of Final Research Achievements

A solar cell using a QD superlattice, which is a three-dimensional array of highly uniform semiconductor quantum dots (QDs), is expected to have an extremely high energy conversion efficiency of 70% or more. Research has been carried out using epitaxial QDs, but breakthroughs are required for superlattice fabrication technology. In this study, we prepared a long-period QD superlattice by precipitating chemically synthesized colloidal PbS QDs on a template in a solvent. We solved the technical problem and made a good colloidal QD superlattice, and actually applied it to the QD superlattice organic solar cell. As a result, we have demonstrated that this technology is promising for achieving high energy conversion efficiency, and obtained results that indicate the direction of future research.

Academic Significance and Societal Importance of the Research Achievements

我々が本研究で提案しているコロイド型QD超格子太陽電池は、コロイド型QDが安価に大量生産できることや、導電性ポリマーと組み合わせることが容易などの特徴から、超高効率・安価・フレキシブル・軽量な、次世代エネルギー技術の基盤となり得る画期的な太陽電池を実現できる可能性がある。本研究の成果によってコロイド型QD超格子の重要性や将来性が認知され、類似の研究が国内外で進展するきっかけとなれば、学術的にも社会的にも非常に大きな意義がある。

Report

(4 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • Research Products

    (26 results)

All 2020 2019 2018

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 4 results) Presentation (20 results) (of which Int'l Joint Research: 7 results,  Invited: 5 results)

  • [Journal Article] Long carrier lifetime in faceted PbS quantum dot superlattice fabricated by sedimentation method2020

    • Author(s)
      Mukai Kohki、Kimura Ryota、Sugisaki Shunta、Sugimoto Takuya、Fujishima Masanobu、Watanabe Sui
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SG Pages: SGGH01-SGGH01

    • DOI

      10.7567/1347-4065/ab641b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modulation of the optical absorption edge of ε- and κ-Ga2O3 due to Co impurities caused by band structure changes: Work function measurements and first-principle calculations2020

    • Author(s)
      Yamanaka K.、Raebiger H.、Mukai K.、Shudo K.
    • Journal Title

      Journal of Applied Physics

      Volume: 127 Issue: 6 Pages: 065701-065701

    • DOI

      10.1063/1.5134521

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chemical synthesis and band gap control of Ga2O3:Co nanocrystals2019

    • Author(s)
      Mukai Kohki、Tsuno Akira、Shudo Ken-ichi、Otani Hiroyuki
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: SB Pages: SBBK05-SBBK05

    • DOI

      10.7567/1347-4065/ab0276

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Superlattice formation of faceted PbS quantum dots with three-dimensionally aligned crystal orientation2018

    • Author(s)
      Mukai Kohki、Fujimoto Satoshi、Suetsugu Fumimasa
    • Journal Title

      Applied Physics Express

      Volume: 11 Issue: 8 Pages: 085601-085601

    • DOI

      10.7567/apex.11.085601

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Improvement of Solar Cell Characteristics Using PbS Quantum Dot Superlattice Prepared by Sedimentation2018

    • Author(s)
      Mukai Kohki、Ishida Yoshikazu
    • Journal Title

      Journal of Nanomaterials

      Volume: 2018 Pages: 1-6

    • DOI

      10.1155/2018/3617687

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Formation of superlattice with aligned plane orientation of colloidal PbS quantum dots2018

    • Author(s)
      Mukai Kohki、Fujimoto Satoshi、Suetsugu Fumimasa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 4S Pages: 04FS02-04FS02

    • DOI

      10.7567/jjap.57.04fs02

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] シラン化プロセスの導入と逆ミセルサイズの調整によるシリカコートPbSQDの単分散性の向上2020

    • Author(s)
      池田航介、八田伶音、向井剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 超格子構造実現のための赤外発光コロイド型SnSe量子ドット合成技術の検討2020

    • Author(s)
      中山ケビン、向井剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Ga2O3ナノワイヤーの化学合成技術の開発2020

    • Author(s)
      廣田奎史郎、向井剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] CuInS2量子ドットの結晶構造及びバンドギャップの合成条件依存性2020

    • Author(s)
      中山 ケビン、池田 航介、船越 拓哉、向井 剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] PbS量子ドット超格子膜の面方位制御と有機太陽電池への応用2020

    • Author(s)
      木村亮太、向井剛輝
    • Organizer
      ナノテク交流シンポジウム
    • Related Report
      2019 Research-status Report
  • [Presentation] HCl添加による化学合成Ga2O3ナノワイヤーの長繊維化2020

    • Author(s)
      廣田 奎史郎、船越 拓哉、向井 剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] 沈降法を用いて作製したPbS量子ドット超格子膜の太陽電池への応用2020

    • Author(s)
      木村亮太、藤島将伸、向井剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] Extended carrier lifetime of faceted PbS quantum dots in superlattice film formed by sedimentation method2019

    • Author(s)
      Kohki Mukai, Ryota Kimura, Shunta Sugisaki, Takuya Sugimoto, and Masanobu Fujishima
    • Organizer
      Material Research Society Fall Meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Extended carrier lifetime in faceted PbS quantum dot superlattice fabricated by sedimentation method2019

    • Author(s)
      R. Kimura, S. Sugisaki, T. Sugimoto, M. Fujishima, S. Watanabe, K. Mukai
    • Organizer
      International Conference on Solid State Devices and Materials
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electronic states and band gap adjustment of Co-impurity doped ε-Ga2O3 and κ-Ga2O32019

    • Author(s)
      Kosuke Yamanaka, Hannes Raebiger, Kohki Mukai, Ken-ichi Shudo
    • Organizer
      30th International Conference on Defects in Semiconductors
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 化学合成によるGa2O3:Cdナノ結晶の作製とバンドギャップ制御2019

    • Author(s)
      船越拓哉, 築野晃, 大谷裕之, 首藤健一, 向井剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] Position control of colloidal quantum dots for future optoelectronics2019

    • Author(s)
      Kohki Mukai
    • Organizer
      International Conference on Materials Research and Nanotechnology conference
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 半導体量子ドットの形成と光デバイス応用2019

    • Author(s)
      向井剛輝
    • Organizer
      技術情報協会講演会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] 沈降法によって作製したファセット付きPbS量子ドット超格子の光学特性2019

    • Author(s)
      木村 亮太、杉崎 俊太、杉本 卓也、藤島 将伸、渡辺 彗、向井 剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 量子ドット超格子太陽電池の実現と高性能化2019

    • Author(s)
      藤島 将伸, 向井剛輝
    • Organizer
      ナノテク交流シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Methods for controlling colloidal quantum dots for future optoelectronics2018

    • Author(s)
      Kohki Mukai
    • Organizer
      20th World Summit on Nanotechnology and Expo
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Template method used for position control of individual silica-coated quantum dot and formation of quantum-dot perfect superlattice2018

    • Author(s)
      Kohki Mukai
    • Organizer
      4th World Congress on Materials Science & Engineering
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Colloidal Quantum-Dot Superlattice for Solar Cell Application2018

    • Author(s)
      Kohki Mukai
    • Organizer
      Asia Pacific Society for Materials Research 2018 Annual Meeting
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] PbS量子ドット超格子構造に対する量子ドット表面へのファセット付与とテンプレート使用の効果2018

    • Author(s)
      藤本 智士、 末続 文正、 藤島 将伸、 向井 剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 沈降法によって形成した量子ドット超格子による太陽電池性能の向上2018

    • Author(s)
      石田 圭利,向井 剛輝
    • Organizer
      春期応用物理学会講演会
    • Related Report
      2018 Research-status Report

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Published: 2018-04-23   Modified: 2022-01-27  

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