Study on Solvent Micro-Cluster Extraction and Separation Method

• Project/Area Number: 19350041
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Analytical chemistry
• Research Institution: Saga University
• Principal Investigator: TABATA Masaaki Saga University, 理工学部, 教授 (40039285)
• Co-Investigator(Kenkyū-buntansha): TAKAMUKU Toshiyuki 佐賀大学, 理工学部, 准教授 (70291838)
• Project Period (FY): 2007 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000); Fiscal Year 2008: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000); Fiscal Year 2007: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
• Keywords: 分離分析 / カラムレス分離分析 / 混合溶媒 / イオン液体 / 溶媒クラスター / カラム不要分離法 / 流れ分離分析法 / 中性子小角散乱 / カラムレス分離

Research Abstract

本研究の目的は混合溶媒中のミクロな不均一溶媒クラスターの生成とその選択的溶媒和に基づいて、新しい分離カラム不要の流れ分離分析法を構築することである。混合溶媒の種類と組成を変えて実験した結果、水とイオン液体の混合溶媒が最適な分離溶媒であることが分かった。中でも長鎖イオン液体と水との混合溶媒では4種のフェノール化合物をキャピラリーに流すだけで、数万の理論段数で分離が可能となった。新しい分離機能を持つ流れ分析法の始まりである。

Research Products

• [Journal Article] Optimized catalytic dechlorination of chlorobenzene compounds on fly ash ; role of metals, aqueous/organic solvents and temperatures (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata
  • Journal Title: Applied Catalysis B : Environmental 86 Pages: 52-158
• [Journal Article] Catalytic dechlorination of aromatic chlorides using flyash under mild conditions ; effects of metals ; mixed solvents and temperature (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata
  • Journal Title: Chemistry for Sustainable Development 17 Pages: 7-14
• [Journal Article] Dechlorination/Detoxification of aromatic chlorides using fly ash under mild conditions (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata
  • Journal Title: Waste Management (accepted)
• [Journal Article] Dechlorination of p-nitrochlorobenzene using fly ash ; effects of metals ; mixed solvents and temperature (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata
  • Journal Title: Reaction Kinetics and Catalysis Letters (in press)
• [Journal Article] Liquid 1-Ethyl-3-methylimidazolium Tetrafluoro borate Studied by Large Angle X-ray Scattering Experiment and Molecular Dynamics Simulations (2009)
  • Author(s): R. Kanzaki, T. Mitsugi, S. Fukuda, K. Fujii, M. Takeuchi, Y. Soejima, T. Takamuku, T. Yamaguchi, Y. Umebayashi, and S. Ishiguro
  • Journal Title: J. Mol. Liquids 147 Pages: 77-82
• [Journal Article] Effect of Methylation at the C2 Position of Imidazolium on the Liquid Structure of Ionic Liquids Revealed by Large Angle X-ray Scattering Experiments and MD Simulations (2009)
  • Author(s): K. Fujii, T. Mitsugi, T. Takamuku, T. Yamaguchi, Y. Umebayashi, and S.Ishiguro
  • Journal Title: Chem. Lett 38 Pages: 340-341
• [Journal Article] Equilibrium Studies on Lithium(I) Transfer into Ionic Liquid with a Water-soluble Octabromoporphyrin (H_2(OBTMPyP)^<4+>) from Aqueous Phase. (2009)
  • Author(s): Masaaki Tabata, Takuya Shimomura
  • Journal Title: J. Porphyrins and Phthalocyanines (In press)
  • Peer Reviewed
• [Journal Article] Optimized catalytic dechlorination of chlorobenzene compounds on fly ash ; role of metals, aqueous/organic solvents and temperatures. (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata.
  • Journal Title: Applied Catalysis B : Environmental 86 Pages: 52-158
  • Peer Reviewed
• [Journal Article] Catalytic dechlorination of aromatic chlorides using flyash under mild conditions ; effects of metals ; mixed solvents and temperature. (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata
  • Journal Title: Chemistry for Sustainable Development 17 Pages: 7-14
  • Peer Reviewed
• [Journal Article] Dechlorination/Detoxification of aromatic chlorides using fly ash under mild conditions. (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata
  • Journal Title: Waste Management (accepted)
  • Peer Reviewed
• [Journal Article] Dechlorination of p-nitrochlorobenzene using fly ash ; effects of metals ; mixed solvents and temperature. (2009)
  • Author(s): Abdul Ghaffar, Masaaki Tabata.
  • Journal Title: Reaction Kinetics and Catalysis Letters (accepted)
  • Peer Reviewed
• [Journal Article] Ion-ion Interaction in Room Temperature Ionic Liquid 1-Ethyl-3-methylimidazolium Tetrafluoroborate Studied by Large Angle X-ray Scattering Experiment and Molecular Dynamics Simulations (2009)
  • Author(s): R. Kanzaki
  • Journal Title: J. Mol. Liquids (印刷中)
  • Peer Reviewed
• [Journal Article] Effect of Methylation at the C2 Position of Imidazolium on the Liquid Structure of Ionic Liquids Revealed by Large Angle X-ray Scattering Experiments and MD Simulations (2009)
  • Author(s): K. Fujii
  • Journal Title: Chem. Lett. 38 Pages: 340-341
  • Peer Reviewed
• [Journal Article] Distribution of heavy metals in water and suspended particles at different sites in Ariake bay, Japan (2008)
  • Author(s): Abdul Ghaffar, Yui Eto, Jun Nishimoto, Koichi Yamamoto, Masaaki Tabata
  • Journal Title: J. of Environmental, Agricultural and Food Chemistry 7 Pages: 3065-3081
• [Journal Article] Takuya Shimomura Equilibrium Studies on Lithium(I) Transfer into Ionic Liquid with a Water-soluble Octabromoporphyrin (H_2(OBTMPyP)^<4+>) from Aqueous Phase (2008)
  • Author(s): Masaaki Tabata
  • Journal Title: J. Porphyrins and Phthalocyanines (accepted)
• [Journal Article] A Micro-solvent Cluster Extraction Using aqueous Mixed Solvents of Ionic Liquid (2008)
  • Author(s): Thiraporn Charoenraks, Msaaki Tabata, Kenta Fujii
  • Journal Title: Anal. Sci. 24 Pages: 1239-1244
  • NAID: 10025206939
• [Journal Article] Liquid Structure and the Ion-Ion Interactions of Ethylammonium Nitrate Ionic Liquid Studied by Large Angle X-ray Scattering and Molecular Dynamics Simulations (2008)
  • Author(s): Y. Umebayashi, W.-L. Chung, T. Mitsugi, S. Fukuda, M. Takeuchi, K. Fujii, T. Takamuku, R. Kanzaki, and S. Ishiguro
  • Journal Title: J. Comput. Chem. Jpn. 7 Pages: 124-135
  • NAID: 10023985811
• [Journal Article] Thermal Properties and Mixing State of Diol-Water Mixtures Studied by Calorimetry, Large-Angle X-ray Scattering, and NMR Relaxation (2008)
  • Author(s): T. Takamuku, Y. Tsutsumi, M. Matsugami, and T. Yamaguchi
  • Journal Title: J. Phys. Chem. B 112 Pages: 13300-13309
• [Journal Article] Aggregation of Imidazolium Ionic Liquids in Molecular Liquids Studied by Small-Angle Neutron Scattering and NMR (2008)
  • Author(s): T. Takamuku, Y. Honda, K. Fujii, and S. Kittaka
  • Journal Title: Anal. Sci 24 Pages: 1285-1290
  • NAID: 10025207190
• [Journal Article] Ionic Liquid Studied by Large Angle X-ray Scattering and Molecular Dynamics Simulations (2008)
  • Author(s): S. Fukuda, M. Takeuchi, K. Fujii, R. Kanzaki, T. Takamuku, K. Chiba, H. Yamamoto, Y. Umebayashi, and S. Ishiguro
  • Journal Title: J. Mol. Liquids 143 Pages: 2-7
• [Journal Article] Neutron Scattering and Dielectric Studies on Dynamics of Methanol and Ethanol Confined in MCM-41 (2008)
  • Author(s): S. Takahara, S. Kittaka, T. Mori, Y. Kuroda, T. Takamuku, and T. Yamaguchi
  • Journal Title: J. Phys. Chem. C 112 Pages: 14385-14393
• [Journal Article] Liquid Structure and Conformation of a Low-viscosity Ionic Liquid, N-Methyl- N-propylpyrrolidinium Bis(fluorosulfonyl)Imide Studied by High-energy X-ray Scattering (2008)
  • Author(s): K. Fujii, S. Seki, S. Fukuda, T. Takamuku, S. Kohara, Y. Kameda, Y. Umebayashi, and S. Ishiguro
  • Journal Title: J. Mol. Liquids 143 Pages: 64-69
• [Journal Article] A Micro-solvent Cluster Extraction Using aqueous Mixed Solvents of Ionic Liquid (2008)
  • Author(s): Thiraporn Charoenraks, Msaaki Tabata, Kenta Fuiii
  • Journal Title: Anal. Sci. 24 Pages: 1239-1244
  • NAID: 10025206939
  • Peer Reviewed
• [Journal Article] Distribution of heavy metals in water and suspended particles at different sites in Ariake bay, Japan (2008)
  • Author(s): Abdul Ghaffar, Yui Eto, Masaaki Tabata
  • Journal Title: J. of Environmental, Agricultural and Food Chemistry 7 Pages: 3065-3081
  • Peer Reviewed
• [Journal Article] Liquid Structure and the Ion-Ion Interactions of Ethylammonium Nitrate Ionic Liquid Studied by Large Angle X-ray Scattering and Molecular Dynamics Simulations (2008)
  • Author(s): Y. Umebayashi
  • Journal Title: J. Comput. Chem. Jpn. 7 Pages: 124-135
  • Peer Reviewed
• [Journal Article] Thermal Properties and Mixing State of Diol-Water Mixtures Studied by Calorimetry, Large-Angle X-ray Scattering, and NMR Relaxation (2008)
  • Author(s): T. Takamuku
  • Journal Title: J. Phys. Chem. B 112 Pages: 13300-13309
  • Peer Reviewed
• [Journal Article] Aggregation of Imidazolium Ionic Liquids in Molecular Liquids Studied by Small-Angle Neutron Scattering and NMR (2008)
  • Author(s): T. Takamuku
  • Journal Title: Anal. Sci. 24 Pages: 1285-1290
  • NAID: 10025207190
  • Peer Reviewed
• [Journal Article] Neutron Scattering and Dielectric Studies on Dynamics of Methanol and Ethanol Confined in MCM-41 (2008)
  • Author(s): S. Takahara
  • Journal Title: J. Phys. Chem. C 112 Pages: 14385-14393
  • Peer Reviewed
• [Journal Article] Liquid Structure and Conformation of a Low-viscosity Ionic Liquid, N-Methyl-N-propylpyrrolidinium Bis(fluorosulfonyl)Imide Studied by High-energy X-ray Scattering (2008)
  • Author(s): K. Fujii
  • Journal Title: J. Mol. Liquids 143 Pages: 64-69
  • Peer Reviewed
• [Journal Article] Liquid structure of N-Butyl-N-methylpyrrolidinium Bis-(trifluoromethanesulfonyl) Amide Ionic Liquid Studied by Large Angle X-ray Scattering and Molecular Dynamics Simulations (2008)
  • Author(s): S. Fukuda
  • Journal Title: J. Mol. Liquids 143 Pages: 2-7
  • Peer Reviewed
• [Journal Article] DMF-induced Phase Separation of HFIP-Water Mixtures (2008)
  • Author(s): T. Takamuku
  • Journal Title: Activity Report on Neutron Scattering Research 無
• [Journal Article] Alkyl-chain Dependence of Mixing State for Methanol Solutions of Imidazolium-based Ionic Liquids (2008)
  • Author(s): T. Takamuku
  • Journal Title: Activity Report on Neutron Scattering Research 無
• [Journal Article] Nano-Scale Aggregation Structure Formed in Room Temperature Ionic Liquid and Its Application to the New Reaction Field (2008)
  • Author(s): K. Fujii
  • Journal Title: Activity Report on Neutron Scattering Research 無
• [Journal Article] An Attempt to Discriminate between the Hydrophobic and Aromatic Interactions I the Copper(II)Ternary Complexes CuLA wuth L=1, 10-phenanthroline or 2, 2'-Bipyridyl and A= para-X-Sbustituted Phenylalaninates (2007)
  • Author(s): Motoharu Tanaka, Masaaki Tabata
  • Journal Title: Inorg. Chem 46 Pages: 9975-9978
• [Journal Article] Electrochemical behaviors of sulfhydryl compounds in the presence of elemental mercury (2007)
  • Author(s): M. Yamamoto, T. Charoenraks, H. Pan-Hou, A. Nakano, A. Apilux, M. Tabata
  • Journal Title: Chemosphere 69 Pages: 534-539
• [Journal Article] Distribution of heavy metals in interstitial water and sediments at different sites in Ariake bay, Japan (2007)
  • Author(s): Masaaki Tabata, Abdul Ghaffar, Yui Eto, Jun Nishimoto, Koichi Yamamoto
  • Journal Title: J. European Water Association, E-Water 6 Pages: 1-24
• [Journal Article] Separation of Cr(VI)from Cr(III)I CaCl_2 aqueous salt medium using hydrocarbon (as toluene, n-hexane, n-heptane or n-octane) mixed solvents of ter-butanol (2007)
  • Author(s): S. S. Samaratunga, J. Nishimoto, M. Tabata
  • Journal Title: Hydrometallugy 89 Pages: 207-216
• [Journal Article] Disinfectant Effects of Lactic Acid on Pythium porphyraoe and Acid Treatment Agent (2007)
  • Author(s): A. Akizuki, M. Tabata, Y. Kawamura
  • Journal Title: Aqua Culture Science 55 Pages: 325-330
• [Journal Article] Accumulation of metals in sediments of Ariake Bay, Japan (2007)
  • Author(s): Masaaki Tabata, Abdul Ghaffar, Jun nishimoto
  • Journal Title: Intern. J. Oceans and Oceanography Vol.2, Number1(in press)
• [Journal Article] Daisuke Yoshimura,Yoshinori Chikaura, An XAFS beamline at the SAGA Light Source (2007)
  • Author(s): Toshihiro Okajima, Kazuhiro Hara, Masaaki Tabata, Hiroyuki Setoyama
  • Journal Title: AIP Conference Proceedings(American Institute of Physics) Pages: 890-892
• [Journal Article] Microinhomogeneity for Aqueous Mixtures of Water-miscible Organic Solvents (2007)
  • Author(s): T. Takamuku, Y. Noguchi, M. Nakano, M. Matsugami, H. Iwase, and T. Otomo
  • Journal Title: J. Ceram. Soc. Japan 115 Pages: 861-866
  • NAID: 130000305458
• [Journal Article] Anion Conformation of Low-viscosity Room Temperature Ionic Liquid, 1-Ethyl-3-methyl imidazolium Bis(fluorosulfonyl)Imide (2007)
  • Author(s): K. Fujii, S. Seki, S. Fukuda, R. Kanzaki, T. Takamuku, Y. Umebayashi, and S. Ishiguro
  • Journal Title: J. Phys. Chem. B 111 Pages: 12829-12833
• [Journal Article] Heterogeneity of Acetonitrile-Water Mixtures in the Temperature Range 279-307 K Studied by Small-Angle Neutron Scattering Technique (2007)
  • Author(s): T. Takamuku, Y. Noguchi, M. Matsugami, H. Iwase, T. Otomo, and M. Nagao
  • Journal Title: J. Mol. Liquids 136 Pages: 147-155
• [Journal Article] Liquid Structure of Acetic Acid-Water and Trifluoroacetic Acid-Water Mixtures Studied by Large-Angle X-ray Scattering and NMR (2007)
  • Author(s): T. Takamuku, Y. Kyoshoin, H. Noguchi, S. Kusano, and T. Yamaguchi
  • Journal Title: J. Phys. Chem. B 111 Pages: 9270-9280
• [Journal Article] Structure and Dynamic Properties of Liquids Confined in MCM-41 Mesopores (2007)
  • Author(s): T. Yamaguchi, K. Yoshida, P. Smironv, T. Takamuku, S. Kittaka, S. Takahara, Y. Kuroda, and M.-C. Bellssent-Funel
  • Journal Title: Eur. Phys. J. Special Topics 141 Pages: 19-27
• [Journal Article] Alkali Chlorides-Induced Phase Separation of Acetonitrile-Water Mixtures Studied by Small-Angle Neutron Scattering (2007)
  • Author(s): T. Takamuku, Y. Noguchi, E. Yoshikawa, T. Kawaguchi, M. Matsugami, and T. Otomo
  • Journal Title: J. Mol. Liquids 131/132 Pages: 131-138
• [Journal Article] An Attempt to Discriminate between Hydrophobic and Aromatic π-π Interactions in Copper(II) Complexes CuLA with L = 1,2-phenanthlorin or 2,2'-Bipyridyl and A = p-X-Substituted Phenylalanines (2007)
  • Author(s): M.Tanaka, M.Tabata
  • Journal Title: Inorganic Chemistry 46 Pages: 9957-9978
  • Peer Reviewed
• [Journal Article] Separation of Cr(VI) from Cr(III) in CaCl_2 aqueous salt medium using hydro-carbon (as toluene, n-hexane, n-heptane or n-octane) mixed solvents of ter-buthanol (2007)
  • Author(s): S.S.Samaratunga, J.Nishimoto, M.Tabata
  • Journal Title: Hydrometallurgy 89 Pages: 207-216
  • Peer Reviewed
• [Journal Article] Liquid Structure of Acetic Acid-Water and Trifluoroacetic Acid-Water Mixtures Studied by Large-Angle X-ray Scattering and NMR (2007)
  • Author(s): T.Takamuku, et. al.
  • Journal Title: J.Physical Chemistry, B 111 Pages: 9270-9280
  • Peer Reviewed
• [Presentation] 混合溶液がつくるミクロな不均一性と溶媒和環境 (2009)
  • Author(s): 高椋利幸
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2009-03-30
• [Presentation] 混合溶液がつくるミクロな不均一性と溶 媒和環境 (2009)
  • Author(s): 高椋利幸
  • Organizer: 日本化学会第89回春季年会特別企画「非常態の水の機能と計測科学」
  • Place of Presentation: 船橋
• [Presentation] イミダゾリウム系イオン液体とメタノールとの混合状態 (2009)
  • Author(s): 下村拓也, 本田裕介, 高椋利幸
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 船橋
• [Presentation] A New Flow analysis Using Aqueous Mixed solvents of IonicLiquids (2009)
  • Author(s): Masaaki Tabata
  • Organizer: Bangladesh Chemical Congress 2008
  • Place of Presentation: Dhaka, Bangladesh
• [Presentation] HFIP-水混合溶液がつくる溶媒和環境と相分離 (2008)
  • Author(s): 高椋利幸
  • Organizer: 第31回溶液学シンポジウム
  • Place of Presentation: 東大阪
  • Year and Date: 2008-11-13
• [Presentation] 各種分子性液体とイミダゾリウム系イオン液体との混合 (2008)
  • Author(s): 下村拓也
  • Organizer: 第31回溶液学シンポジウム
  • Place of Presentation: 東大阪
  • Year and Date: 2008-11-13
• [Presentation] 1-アルキル-3-メチルイミダゾリウム系イオン液体のナノ相分離構造に関する実験および理論的研究 (2008)
  • Author(s): 藤井健太
  • Organizer: 第31回溶液学シンポジウム
  • Place of Presentation: 東大阪
  • Year and Date: 2008-11-12
• [Presentation] Alkyl-chain Dependence on Meso-and Micro-scale Liquid Structure of Imidazolium Based Room Temperature Ionic Liquid (2008)
  • Author(s): K. Fujii
  • Organizer: EUCHEM 2008 Conference on Molten Salts and Ionic Liquids
  • Place of Presentation: Copenhagen, Denmark
  • Year and Date: 2008-08-24
• [Presentation] A New Flow analysis Using Aqueous Mixed solvents of Ionic Liquids (2008)
  • Author(s): Masaaki Tabata
  • Organizer: Bangladesh Chemical Congress
  • Place of Presentation: Dhaka, Bangladesh
• [Presentation] 混合溶媒のミクロ溶媒クラスター抽出分離(2) : イオン液体を用いる中性有機化合物の分離分析 (2008)
  • Author(s): 田端正明, Charoenraks, Thiraporn
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
• [Presentation] 混合溶媒のミクロ溶媒クラスター抽出分離分析法(3) : 種々の混合溶媒の効果 (2008)
  • Author(s): 田端正明, Charoenraks Thiraporn, 藤井健太
  • Organizer: 第69回分析化学討論会
  • Place of Presentation: 名古屋
• [Presentation] 混合溶媒のミクロ相分離機能に基づく新規キャピラリーフロー分離分析法 (2008)
  • Author(s): 田端正明, Charoenraks, Thiraporn
  • Organizer: 日本分析化学会第57年会
  • Place of Presentation: 福岡
• [Presentation] 混合溶媒を流すだけで分かれる分離カラム不要の新しい分離分析法 (2008)
  • Author(s): 田端正明, Charoenraks, Thiraporn
  • Organizer: 東京コンファレンス2008
  • Place of Presentation: 幕張
• [Presentation] Equilibrium Studies on Selective Phase Transfer reaction of Li(I) into Ionic Liquid with Water-Soluble Octabromoporphyrin (2008)
  • Author(s): Masaaki Tabata, Takuya Shimomura, Jun Nishimoto
  • Organizer: Fifth International Conference onPorphyrins and Phthalocyanines
  • Place of Presentation: Moscow(Russia)
• [Presentation] Enhanced DNA Cleavage by Trace Metals, Metalloporphyrins and"Good Buffers" (2008)
  • Author(s): Masaaki Tabata, Elvis Nyarko, Ahsan Habib
  • Organizer: Fourth Conference on Metals and Genetics
  • Place of Presentation: Paris, France
• [Presentation] A New Capillary Flow Analysis with Separation Function using Aqueous Mixed Solvents of Ionic Liquids (2008)
  • Author(s): Thiraporn Charoenraks, Kenta Fujii, Masaaki Tabata
  • Organizer: 15 the ICFIA & 25^<th> Anniversary Meeting of JAFIA
  • Place of Presentation: Nagoya, Japan
• [Presentation] A New Separation Method Using Aqueous Mixed Solvents (2008)
  • Author(s): Masaaki Tabata
  • Organizer: The 34 the Congress on Science and Technology of Thailand
  • Place of Presentation: Bangkok, Thailand
• [Presentation] アミド誘起によるフッ化アルコール-水混合溶液の相分離の研究 (2008)
  • Author(s): 高椋利幸, 下村拓也, 藤井健太, 和田浩, 立川真衣, 飛石真理絵
  • Organizer: 中性子科学会第8回年会
  • Place of Presentation: 名古屋
• [Presentation] HFIP-水混合溶液がつくる溶媒和環境と相分離 (2008)
  • Author(s): 高椋利幸, 和田浩, 藤井健太, 竹内宗孝
  • Organizer: 第31回溶液学シンポジウム
  • Place of Presentation: 大阪
• [Presentation] 1-アルキル-3-メチルイミダゾリウム系イオン液体のナノ相分離構造に関する実験および理論的研究 (2008)
  • Author(s): 藤井健太, 高椋利幸, 梅林泰宏, 金久保光央, 亀田恭男, 石黒慎一
  • Organizer: 第31回溶液学シンポジウム
  • Place of Presentation: 大阪
• [Presentation] 各種分子性液体とイミダゾリウム系イオン液体との混合 (2008)
  • Author(s): 下村拓也, 高椋利幸
  • Organizer: 第31回溶液学シンポジウム
  • Place of Presentation: 大阪
• [Presentation] SANSおよびNMR法による分子性液体中でのイミダゾリウム系イオン液体の会合体形成 (2008)
  • Author(s): 高椋利幸, 本田裕介, 藤井健太
  • Organizer: 日本分析化学会第57回年会
  • Place of Presentation: 福岡
• [Presentation] イオン液体中で形成する特殊反応場構造とそのアルキル鎖長依存性 (2008)
  • Author(s): 藤井健太, 福田周平, 高椋利幸, 小原真司, 金久保光央, 亀田恭男, 梅林泰宏, 石黒慎一
  • Organizer: 日本分析化学会第57回年会
  • Place of Presentation: 福岡
• [Presentation] イミダゾリウム系イオン液体のC2メチル化が液体構造に及ぼす効果 (2008)
  • Author(s): 光木卓志, 福田周平, 藤井健太, 高椋利幸, 山口敏男, 梅林泰宏, 石黒慎一
  • Organizer: 日本分析化学会第57回年会
  • Place of Presentation: 福岡
• [Presentation] イミダゾリウム系イオン液体の液体構造とそのアルキル鎖長依存性 (2008)
  • Author(s): 藤井健太, 福田周平, 高椋利幸, 小原真司, 金久保光央, 亀田恭男, 梅林泰宏, 石黒慎一
  • Organizer: 電気化学会第75回大会
  • Place of Presentation: 甲府
• [Presentation] 広角X線散乱実験およびMDシミュレーションによるイオン液体, 1-ethyl-3-methyl imidazolium bis-(trifluoromethansulfonyl)imideの液体構造解析 (2008)
  • Author(s): 藤井健太, 福田周平, 高椋利幸, 神崎亮, 梅林泰宏, 石黒慎一
  • Organizer: 電気化学会第75回大会
  • Place of Presentation: 甲府
• [Presentation] Alkyl-chain Dependence on Meso- and Micro-scale Liquid Structure of Imidazolium Based Room Temperature Ionic Liquid (2008)
  • Author(s): K. Fujii, T. Takamuku, S. Fukuda, R. Kanzaki, M. Kanakubo, Y. Kameda, Y. Umebayashi, S. Ishiguro
  • Organizer: EUCHEM 2008 Conference on Molten Salts and Ionic Liquids
  • Place of Presentation: Copenhagen, Denmark
• [Presentation] Microwave Assisted Synthesis and Reactivities of Water-Soluble Rh(III) Porphyrin and it β-Pyrrole Brominated Derivatives (2008)
  • Author(s): Nanda Gunawardhana, 田端正明
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢
• [Presentation] Rh(III)OBTMpyPと還元剤によるDNA開裂反応 (2008)
  • Author(s): 保見真悟, Nanda Gunawardhana, 田端正明
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢
• [Presentation] Equilibrium Studies on Selective Phase-Transfer reaction of Li(I) into Ionic Liquid with Water-Soluble Octabromoporphyrin (2008)
  • Author(s): Masaaki Tabata, Takuya Shimomura, Jun Nishimoto
  • Organizer: Fifth International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Moscow (Russia)
• [Presentation] Enhanced DNA Cleavage by Trace Metals, Metalloporphyrins and “Good Buffers" (2008)
  • Author(s): Masaaki Tabata, Elvis Nyarko, Ahsan Habib
  • Organizer: Fourth Conference on Metals and Genetics
  • Place of Presentation: Paris, France
• [Presentation] Micro-solvent Cluster Extraction Mechanism Using Ionic Liquids (2007)
  • Author(s): M.Tabata, T.Charoenraks, T.Fujii
  • Organizer: IMLG/JMLG/SSC Joint Symposium
  • Place of Presentation: 日本、福岡
• [Remarks] 田端正明
  • URL: http://www2.cc.saga-u.ac.jp/saga-u/riko/chem/anal/tabata/tabata-j.html
• [Remarks] 高椋利幸
  • URL: http://solution.chem.saga-u.ac.jp/