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Construction of Magnetic Field-Modulation Near-Field AFM Surface Analyzing System and Its Application to Analysis of Polymer Thin Film-Water Interfaces

Research Project

Project/Area Number 19350055
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionUniversity of Toyama

Principal Investigator

KITANO Hiromi  University of Toyama, 大学院・理工学研究部(工学), 教授 (40115829)

Co-Investigator(Kenkyū-buntansha) GEMMEI-IDE MAKOTO  富山大学, 大学院・理工学研究部(工学), 助教 (70334711)
Project Period (FY) 2007 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2007: ¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
Keywords水 / 高分子膜 / 振動分光 / 磁場 / 赤外光 / 変調 / 赤外分光法 / Raman分光法 / 高分子ブラシ / 水素結合ネットワーク / 分子認識 / 局在表面プラズモン共鳴法 / 低温再結晶化
Research Abstract

高分子超薄膜-液界面のナノスケールでの水和状態に関する情報を、膜表面の微細構造、化学組成、さらには表面電位に関する情報と共にin situで捉えることを目的として、原子間力顕微鏡装置 (AFM) と掃引型核磁気共鳴装置を組み合わせた磁場変調型原子間力顕微鏡表面測定装置 (MFM-AFM) を試作した。さらに、特定官能基に水和した水のスペクトルの実験的な帰属の可能性に関する検討を行った。また、高分子ブラシや自己組織化単分子膜の機能と構造との相関についての検討や、高分子薄膜への収着水の構造解析も併せて行った。

Report

(3 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • Research Products

    (51 results)

All 2009 2008 2007

All Journal Article (37 results) (of which Peer Reviewed: 35 results) Presentation (9 results) Book (5 results)

  • [Journal Article] Anti-biofouling Properties of a Telomer Brush with Pendent Glucosylurea Groups2009

    • Author(s)
      Kitano, H.; Hayashi, A.; Takakura, H.; Suzuki, H.; Saruwatari, Y.; Kanayama, N.
    • Journal Title

      Langmuir (in press)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anti-Biofouling Property of Polymers with a Carboxybetaine Moiety2009

    • Author(s)
      Tada, S.; Inaba, C.; Mizukami, K.; Fujishita, S.; Gemmei-Ide, M,; Kitano, H.; Mochizuki, A.; Tanaka, M.; Matsunaga, T., Macromol.
    • Journal Title

      Biosci 9

      Pages: 63-70

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature Responsive Polymer Brush Constructed on a Colloidal Gold Monolayer2009

    • Author(s)
      Kitano, H.; Kago, H.; Matsuura, K., J
    • Journal Title

      Colloid Interface Sci 331

      Pages: 343-350

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic study on the binding of lectin to mannose residues in a polymer brush. Kitano, H.; Takahashi2009

    • Author(s)
      Y. ; Mizukami, K. ; Matsuura, K. Colloids Surfaces B
    • Journal Title

      Biointerfaces 70

      Pages: 91-97

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 生体適合性と水和2009

    • Author(s)
      北野博巳 源明誠
    • Journal Title

      高分子 58

      Pages: 74-77

    • NAID

      10024759045

    • Related Report
      2008 Final Research Report
  • [Journal Article] Anti-Biofouling Property of Polymers with a Carboxybetaine Moiety2009

    • Author(s)
      S. Tada, C. Inaba, K. Mizukami, S. Fujishita, M. Gemmei-Ide, H. Kitano, A. Mochizuki, M. Tanaka, T. Matsunaga
    • Journal Title

      Macromolecular Bioscience 9

      Pages: 63-70

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 生体適合性と水和2009

    • Author(s)
      北野博巳, 源明 誠
    • Journal Title

      高分子 58

      Pages: 74-77

    • NAID

      10024759045

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Structure of Water Incorporated in Amphoteric Polymer Thin Films As Studied by FTIR Spectro- scopy.2008

    • Author(s)
      Kitano, H. ; Nagaoka, K. ; Tada, S. ; Gemmei-Ide, M. ; Tanaka, M
    • Journal Title

      Macromol. Biosci 8

      Pages: 77-85

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Binding of Ricinus communis agglutinin to a galactose-carrying polymer brush on a colloidal gold monolayer2008

    • Author(s)
      Mizukami, K. ; Takakura, H. ;Matsunaga, T. ; Kitano, H., Colloids Surfaces B
    • Journal Title

      Biointerfaces 66

      Pages: 110-118

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interaction of wheat germ agglutinin with an N-acetylglucosamine-carrying telomer brush accumulated on a colloidal gold monolayer2008

    • Author(s)
      Kitano, H. ; Nakada, H. ; Mizukami, K., Colloids Surfaces B
    • Journal Title

      Biointerfaces 61

      Pages: 17-24

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Drug Assessment Based on Detection of L-Glutamate Released from C6 Glioma Cells Using an Enzyme-Luminescence Method2008

    • Author(s)
      Zakir Hossain, S. M. ; Shinohara, H. ; Kitano, H
    • Journal Title

      Anal. Chem 80

      Pages: 3762-3768

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic Evidence of Phase Transition of Monomolecular Water in Solid Polystyrene.2008

    • Author(s)
      Gemmei-Ide, M. ; Kitano, H.
    • Journal Title

      J. Phys. Chem. B 112

      Pages: 2764-2766

    • NAID

      120006395332

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recrystallization of Water in a Non-Water- Soluble Polymer Examined by Fourier Transform Infrared Spectroscopy : Poly(2-methoxyethyl- acrylate) with Low Water Content2008

    • Author(s)
      Gemmei-Ide, M. ; Kitano, H.
    • Journal Title

      J. Phys. Chem,B 112

      Pages: 12863-12866

    • NAID

      120006395330

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Growth of Ice Ih by Re-vapor- deposition and Diffusion Suppression of Mono- molecular Water in a Polymer Solid : Spectro- scopic Observation of Phase Transition of Water Sorbed into Polystyrene2008

    • Author(s)
      Gemmei-Ide, M. ; Kitano, H
    • Journal Title

      J. Phys. Chem, B 112

      Pages: 13499-13502

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Zwitterionic Polymers on Wound Healing2008

    • Author(s)
      Fujishita, S. ; Inaba, C. ; Tada, S. ; Gemmei-Ide, M. ; Kitano, H. ; Saruwatari, Y., Biol
    • Journal Title

      Pharm. Bull 31

      Pages: 2309-2315

    • NAID

      110007005034

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 高分子材料の機能と水和構造の相関2008

    • Author(s)
      北野博巳 源明誠
    • Journal Title

      日本接着学会誌 44

      Pages: 485-490

    • NAID

      10024920238

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recrystallization of Water in a Non-Water-Soluble Polymer Examined by Fourier Transform Infrared Spectroscopy : Poly (2-methoxyethyl acrylate) with Low Water Content2008

    • Author(s)
      M. Gemmei-Ide H. Kitano
    • Journal Title

      The Journal of Physical Chemistry B 112

      Pages: 12863-12866

    • NAID

      120006395330

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Growth of Ice Ih by Revapor-Deposition and Diffusion Suppression of Monomolecular Water in Polymer Solid : Spectroscopic Observation of Phase Transition of Water Sorbed into Solid Polystyrene2008

    • Author(s)
      M. Gemmei-Ide H. Kitano
    • Journal Title

      The Journal of Physical Chemistry B 112

      Pages: 13499-13502

    • NAID

      120006395331

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Zwitterionic Polymers on Wound Healing2008

    • Author(s)
      S. Fujishita, C. Inaba, S. Tada, M. Gemmei-Ide, H. Kitano, Y. Saruwatari
    • Journal Title

      Biological & Pharmaceutical Bulletin 31

      Pages: 2309-2315

    • NAID

      110007005034

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高分子材料の機能と水和構造の相関2008

    • Author(s)
      北野 博巳, 源明 誠
    • Journal Title

      日本接着学会誌 44

      Pages: 485-490

    • NAID

      10024920238

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interaction of wheat germ agglutinin with an N-acetylglucosamine-carrying telomer brush accumulated on a colloidal gold monolayer2008

    • Author(s)
      H. Kitano, H. Nakada, K. Mizukami
    • Journal Title

      Collolds Surfaces B: Biointerfaces 66

      Pages: 17-24

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure of Water Ihcorporated in Amphoteric Polymer Thin Films As Revealed by FTIR Spectroscopy2008

    • Author(s)
      H. Kitano, K. Nagaoka S. TadaM.Gemmei-Ide, M. Tanaka
    • Journal Title

      Macromol.Biosci 12

      Pages: 722-726

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic Evidence of Phase Transition of Monomolecular Water in Solid Polystyrene2008

    • Author(s)
      M. Gemmei-Ide, H. Kitano
    • Journal Title

      J. Phys. Chem. B 112

      Pages: 2764-2766

    • NAID

      120006395332

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functionalization of Single-walled Carbon Nanotube by the Covalent Modification with Polymer Chains2007

    • Author(s)
      Kitano, H. ; Tachimoto, K. ; Anraku, Y.
    • Journal Title

      J. Colloid Interface Sci 306

      Pages: 28-33

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Functionalization of Single-walled Carbon Nanotube by the Covalent Modification with Polymer Chains2007

    • Author(s)
      Kitano, H. ; Tachimoto, K. ; Anraku, Y.
    • Journal Title

      J. Colloid Interface Sci 56

      Pages: 188-196

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Carboxybetaine Polymer Protected Gold Nanoparticles : High Dispersion Stability and Resistance against Non-specific Adsorption of Proteins.2007

    • Author(s)
      Matsuura, K. ; Ohno, K. ; Kagaya, S. ; Kitano, H
    • Journal Title

      Macromol. Chem. Phys 208

      Pages: 862-873

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recognition of sugars on surface-bound cap- shaped gold particles modified with a polymer brush2007

    • Author(s)
      Anraku, Y. ; Takahashi, Y. ; Kitano, H. ; Hakari, M., Colloids Surfaces B
    • Journal Title

      Biointerfaces 57

      Pages: 61-68

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Breaking of Supercooled State of Water by a Nanocavity with Disordered Atomic Configu- ration I : Freezing Behavior of Sorbed Water into Polymethylmethacrylate Film as Examined by Fourier Transform Infrared Spectroscopy2007

    • Author(s)
      Gemmei-Ide, M. ; Motonaga, T. ; Kitano, H
    • Journal Title

      J. Phys. Chem 111

      Pages: 5533-5535

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure of Water in the Vicinity of Amphoteric Polymers As Studied by Raman Spectroscopy2007

    • Author(s)
      Kitano, H. ; Nagaoka, K. ; Tada, S. ; Gemmei-Ide, M.
    • Journal Title

      J. Colloid Interface Sci 313

      Pages: 461-468

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Real-Time Detection of L-Glutamate Released from C6 Glioma Cells Using a Modified Enzyme-Luminescence Method2007

    • Author(s)
      Zakir Hossain, S. M. ; Shinohara, H. ; Kitano, H
    • Journal Title

      Anal. Bioanal. Chem 389

      Pages: 1961-1966

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydration Changes of Poly(2-(2-methoxy- ethoxy)ethyl methacrylate during Thermo- sensitive Phase Transition in Water2007

    • Author(s)
      Maeda, Y. ; Kubota, T. ; Yamauchi, H. ; Nakaji, T. ; Kitano, H.
    • Journal Title

      Langmuir 23

      Pages: 11259-11265

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Breaking of the Supercooled State of Water by a Nanocavity with Disordered Atomic Configuration.I: Freezing Behavior of Sorbed Waterinto Polymethylmethacrylate Film AsExamined by Fourier Infrared Spectroscopy2007

    • Author(s)
      M. Gemmei-Ide, T. Motonaga H. Kitano
    • Journal Title

      J. Phys. Chem. B 111

      Pages: 5533-5535

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stmcture of Water in the Vichlity of Amphoteric Polymers As Revealed by Raman Spectroscopy2007

    • Author(s)
      H. Kitano, K. Nagaoka, S. Tada, M. Gemmei-Ide
    • Journal Title

      J. Colloid Interface Sci 313

      Pages: 461-468

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recognition of Sugars on Surface-bound Cap-shaped Gold Particles Modified with a Polymer Brush2007

    • Author(s)
      Y. Anraku, Y. Takahashi, H. Kitano, M. Hakari
    • Journal Title

      Colloidg Surfaces B. Biointerfaces 57

      Pages: 61-48

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carboxybetaine Polymer-Protected Gold Nanoparticles: High DispersionAbilitv and Resistance agains Non-Specific Adsorption of Proteins2007

    • Author(s)
      K. Matsuura, K. ohno, S. Kagaya, H. Kitano
    • Journal Title

      Macromol. Chem. Phys 208

      Pages: 862-873

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functionalization of Single-walled Carbon Nanotube by the Covalent Modification with Polymers Chains2007

    • Author(s)
      H. Kitano, K. Tachimoto, Y. Anraku
    • Journal Title

      J. Colloid Interface Sci 306

      Pages: 28-33

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Resistance of Surface-confined Telomers with Pendent Glucosylurea-Groups-against Non-specific Adsorption of Proteins2007

    • Author(s)
      H. Kitano, M. Gemmei-Ide, Y. Anraku, Y. Saruwatari
    • Journal Title

      Collolds Surfaces B: Biointerfaces 56

      Pages: 188-196

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] テレケリック高分子膜表面への繊維芽細胞の付着特性2008

    • Author(s)
      源明 誠, 石坂 拓也, 稲葉 央, 北野 博巳
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] 赤外分光法から観た固体高分子中の水の相転移挙動と材料の生体適合性との相関2008

    • Author(s)
      源明 誠, 大矢 厚志, 北野 博巳
    • Organizer
      第57回高分子学会討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] 局在表面プラズモン共鳴法を用いるアルパルチルプロテアーゼのセンシングデバイスの構築2008

    • Author(s)
      斉藤 大輔, 今井 直美, 源明 誠, 北野博巳
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] テレケリックポリマー表面へのタンパク質吸着/繊維芽細胞付着特性に関する研究2008

    • Author(s)
      源明 誠, 稲葉 央, 北野博巳
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 固体高分子中の単分子水の相転移挙動2008

    • Author(s)
      源明 誠, 北野博巳
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 赤外分光法による生体適合性高分子材料中の水の相転移に関する研究2007

    • Author(s)
      源明 誠・萩原 晃・北野 博巳
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 両性イオン基を有する高分子水溶液中の水構造と生体適合性に関する研究2007

    • Author(s)
      稲葉 央・多田 晋・源明 誠・北野 博巳・田中 賢・望月 明・猿渡 欣幸
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 固体高分子中の水の相転移に関する研究2007

    • Author(s)
      源明 誠・本永 哲也・北野 博巳
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] 両性イオン基を有する高分子の生体適合性に関する研究2007

    • Author(s)
      稲葉 央・多田 晋・源明 誠・北野 博巳・田中 賢・望月 明・猿渡 欣幸
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-30
    • Related Report
      2007 Annual Research Report
  • [Book] Sensing Capabilities of Self-assembled Monolayer Using Localized Surface Plasmon Spectroscopy in "Bottom-Up Nanofabrication : Supramolecules, Self-Assemblies, and Organized Films. Vol. 3" (Ariga, K. ; Nalwa, H. S.. Eds.)2009

    • Author(s)
      Kitano, H. ; Mizukami, K.
    • Publisher
      American Scientific Publishers
    • Related Report
      2008 Final Research Report
  • [Book] 「高分子の化学」(荻野和子 竹内茂彌 柘植秀樹 編)「環境と化学」第2版 第7章2009

    • Author(s)
      竹内茂彌 北野博巳
    • Publisher
      東京化学同人
    • Related Report
      2008 Final Research Report
  • [Book] Sensing Capabilities of Self-assembled Monolayer Using Localized Surface Plasmon Spectroscopy in “Bottom-Up Nanofabrication : Supramolecules, Self-Assemblies, and Organized Films. Vol. 3"2009

    • Author(s)
      H. Kitano, K. Mizukami
    • Total Pages
      21
    • Publisher
      American Scientific Publishers
    • Related Report
      2008 Annual Research Report
  • [Book] 「高分子の化学」(著者 功刀滋 宮本真敏 前田寧 伊藤研策 福田光完 北野博巳)2008

    • Author(s)
      北野博巳 功刀滋編
    • Publisher
      三共出版
    • Related Report
      2008 Final Research Report
  • [Book] 高分子の化学2008

    • Author(s)
      北野, 博巳 功刀, 滋 編著
    • Total Pages
      254
    • Publisher
      三共出版
    • Related Report
      2007 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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