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Self-Functional Nanofiber Prepared via Organic-to-Inorganic Conversion Process by Ion Beam Irradiation.

Research Project

Project/Area Number 19350115
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

SUGIMOTO Masaki  Japan Atomic Energy Agency, 量子ビーム応用研究部門, 研究副主幹 (90354943)

Co-Investigator(Kenkyū-buntansha) IDESAKI Akira  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究員 (10370355)
SEKI Syuhei  大阪大学, 大学院・工学研究科, 教授 (30273709)
ITOH Hiroshi  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 技術副主幹 (00414574)
YAMAMOTO Shyunya  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究主幹 (70354941)
YOSHIKAWA Masahito  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究主幹 (40354948)
Project Period (FY) 2007 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2008: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2007: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Keywordsナノファイバー / セラミックス / イオン照射 / 単一粒子ナノ加工 / 有機-無機転換 / 前駆体高分子 / 金属内包 / ナノメッシュ / SiCセラミックス / ポリカルボシラン / グラフト重合 / メタクリル酸グリシジル / ラジカル / パラジウム / 触媒担持 / 高セラミック収率 / ポリマーブレンド / 自立型ナノファイバー / 3Dナノメッシュ / イオンビーム / 線エネルギー付与(LET) / 多角度照射
Research Abstract

We have succeeded in synthesizing self-functional ceramic nano fibers from precursor polymers using Single Particle Nanofabrication Technique (SPNT). A thin film of the precursor polymer was cross-linked by MeV-order heavy-ion beam irradiation along ion tracks of nano-size in radius through the whole thickness of the thin film. Nano fibers were developed on the surface of the substrate by dissolution and washing away of un-crosslinked polymer. Subsequent pyrolysis converted polymeric into ceramic nano fibers. The radius, length and number density of nano fibers are controlled by liner energy transfer (LET) of ion beam, thickness of polymeric target and number of projected ions, respectively.

Report

(4 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report
  • Research Products

    (46 results)

All 2010 2009 2008 2007 Other

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (21 results) Remarks (2 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Synthesis of Ceramic Nano Fiber from Precursor Polymer by Single Particle Nano-fabrication Technique2010

    • Author(s)
      M. Sugimoto、A. Idesaki、M. Yoshikawa、S. Watanabe、S. Seki
    • Journal Title

      Ceramic Transactions Vol.213(掲載確定)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis Of A Catalyst-Loaded SiC Material from Si-Based Polymer2010

    • Author(s)
      A. Idesaki、M. Sugimoto、M. Yoshikawa
    • Journal Title

      Ceramic Transactions Vol.213(掲載確定)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ceramic Nano Fiber from Precursor Polymer by Single Particle Nano-fabrication Technique2010

    • Author(s)
      Masaki Sugimoto
    • Journal Title

      Ceramic Transactions 213(掲載確定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis Of A Catalyst-Loaded SiC Material from Si-Based Polymer2010

    • Author(s)
      Akira Idesaki
    • Journal Title

      Ceramic Transactions 213(掲載確定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sugar Nanowires Based on Cyclodextrin Prepared by Single Particle Nano-fabrication Technique2009

    • Author(s)
      S. Watanabe、S. Seki、M. Sugimoto、M. Yoshikawa、S. Tagawa、S. Tsukuda、S. Tanaka
    • Journal Title

      Radiat. Phys. Chem. 78

      Pages: 1071-1075

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sugar Nanowires Based on Cyclodextrin Prepared by Single Particle Nano-fabrication Technique2009

    • Author(s)
      Shougo Watanabe
    • Journal Title

      Radiat.Phys.Chem. 78

      Pages: 1071-1075

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of hybrid nano-structures by ion beam irradiation to the sol-gel film2009

    • Author(s)
      Satoshi Tsukuda
    • Journal Title

      J.Photopolym.Sci.Technol. 22

      Pages: 245-248

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ceramic Nano fiber from Precursor Polymers by Ion Beam Irradiation2008

    • Author(s)
      M. Sugimoto、M. Yoshikawa、S. Tsukuda、S. Seki
    • Journal Title

      Transactions of the Materials Research Society of Japan Vol.33[4]

      Pages: 1027-1030

    • NAID

      130007809524

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multi-Functional Polymer Nanowires with Ultra-high Aspect Ratio Produced by Single Particle Nano-fabrication Technique2008

    • Author(s)
      S. Seki、S. Watanabe、M. Sugimoto、S. Tagawa、S. Tsukuda
    • Journal Title

      J. Photopolym. Sci. Technol. Vol.21[4]

      Pages: 541-543

    • NAID

      40016109020

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ceramic Nano fiber from Precursor Polymers by Ion Beam Irradiation2008

    • Author(s)
      Masaki Sugimoto
    • Journal Title

      Transactions of the Materials Research Society of Japan 33[4]

      Pages: 1027-1030

    • NAID

      130007809524

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multi-Functional Polymer Nanowires with Ultra-high Aspect Ratio Produced by Single Particle Nano-fabrication Technique2008

    • Author(s)
      Shu Seki
    • Journal Title

      J. Photopolym. Sci. Technol. 21[4]

      Pages: 541-543

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Isolated Ultrafine Optical Nanofibers by Single Particle Nanofabrication Technique2007

    • Author(s)
      S. Seki、S. Tsukuda、S. Tagawa、M. Sugimoto、A. Watanabe、M. Tokuji
    • Journal Title

      J of Photopolym. Sci. and Tech Vol.20

      Pages: 125-128

    • NAID

      130004833177

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanowires with controlled sizes formed by single ion track reactions in polymers2007

    • Author(s)
      S. Tsukuda、S. Seki、M. Sugimoto、S. Tagawa
    • Journal Title

      Surface & Coatings Technology Vol.201

      Pages: 8526-8530

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cross-linked silicon based polymer nano-wire formation by high energy charged particles2007

    • Author(s)
      S. Seki、S. Tsukuda、S. Tagawa、M. Sugimoto
    • Journal Title

      Surface & Coatings Technology Vol.201

      Pages: 8486-8489

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] 高分子材料の単一粒子ナノ加工と構造制御2007

    • Author(s)
      関 修平, 佃 諭志, 田川 精高, 杉本 雅樹
    • Journal Title

      放射線化学 83

      Pages: 10-20

    • NAID

      10018894585

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Isolated Ultrafine Optical Nanofibers by SingleParticle Nanofabrication Technique2007

    • Author(s)
      S. Seki, S. Tsukuda, S. Tagawa, M. Sugimoto, A. Watanabe, and M. Tokuji
    • Journal Title

      J of Photopolym.Sci.and Tech 20

      Pages: 125-128

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanowires with controlled sizes formed by single ion track reactions in polymers2007

    • Author(s)
      S. Tsukuda, S. Seki M. Sugimoto S. Tagawa
    • Journal Title

      Surface & Coatings Technology 201

      Pages: 8526-8530

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cross-linked silicon based polymer nano-wire formation by high energy charged particles2007

    • Author(s)
      S. Seki, S. Tsukuda, S. Tagawa, M. Sugimoto
    • Journal Title

      Surface&Coatings Technology 201

      Pages: 8486-8489

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sugar Nanowires Based on Cyclodextrin Prepared by Single Particle Nano-fabrication Technique

    • Author(s)
      S. Watanabe
    • Journal Title

      Radiat. Phys. Chem. (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] イオン照射による金属内包セラミック・ナノファイバーの合成II2010

    • Author(s)
      杉本雅樹、吉村公男、出崎亮、吉川正人、麻野敦資、関修平
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      東京・東京農工大学
    • Year and Date
      2010-03-23
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 量子ビームを駆使したポリカルボシランへの機能性付与2009

    • Author(s)
      吉村 公男
    • Organizer
      東北大学金属材料研究所ワークショップ
    • Place of Presentation
      宮城・東北大学金属材料研究所
    • Year and Date
      2009-12-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis and Properties of Metal-Chelating Polycarbosilane Polymer Prepared by Radiation Grafting2009

    • Author(s)
      Kimio Yoshimura
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      神奈川・横浜市開港記念会館
    • Year and Date
      2009-12-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] イオン照射による前駆体高分子からの金属担持セラミックナノファイバーの形成2009

    • Author(s)
      杉本雅樹
    • Organizer
      第4回高崎量子応用研究シンポジウム
    • Place of Presentation
      群馬・高崎シティーギャラリー
    • Year and Date
      2009-10-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] イオン照射による金属内包セラミック・ナノファイバーの合成2009

    • Author(s)
      杉本雅樹
    • Organizer
      日本セラミックス協会 第22回秋季シンポジウム
    • Place of Presentation
      愛媛・愛媛大学
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリカルボシランと酢酸パラジウムからなるプレカーサーのセラミックス化過程2009

    • Author(s)
      杉本雅樹
    • Organizer
      日本セラミックス協会 第22回秋季シンポジウム
    • Place of Presentation
      愛媛・愛媛大学
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis of Ceramic Nano Fiber from Precursor Polymer by Single Particle Nano-fabrication Technique2009

    • Author(s)
      M. Sugimoto、A. Idesaki、M. Yoshikawa、S. Watanabe、S. Seki
    • Organizer
      8th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM8)
    • Place of Presentation
      バンクーバー・カナダ
    • Year and Date
      2009-06-04
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Synthesis Of A Catalyst-Loaded SiC Material from Si-Based Polymer2009

    • Author(s)
      A. Idesaki、M. Sugimoto、M. Yoshikawa
    • Organizer
      8th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM8)
    • Place of Presentation
      バンクーバー・カナダ
    • Year and Date
      2009-06-04
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] プレカーサー法による触媒担持SiC系材料の合成2009

    • Author(s)
      出崎亮、杉本雅樹、吉川正人
    • Organizer
      日本セラミックス協会2009年年会
    • Place of Presentation
      野田・千葉大学
    • Related Report
      2009 Final Research Report
  • [Presentation] プレカーサー法による触媒担持SiC系材料の合成2009

    • Author(s)
      出崎亮
    • Organizer
      日本セラミックス協会2009年年会
    • Place of Presentation
      野田(千葉県)
    • Related Report
      2008 Annual Research Report
  • [Presentation] イオン照射による機能性セラミック・ナノファイバーの合成2008

    • Author(s)
      杉本雅樹、吉川正人、渡辺省伍、関修平
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      小倉市・北九州国際会議場
    • Related Report
      2009 Final Research Report
  • [Presentation] イオン照射による自立セラミック・ナノファイバーの合成2008

    • Author(s)
      杉本雅樹、吉川正人、渡辺省伍、関修平
    • Organizer
      日本セラミックス協会2008年年会
    • Place of Presentation
      新潟・長岡技術科学大学
    • Related Report
      2009 Final Research Report
  • [Presentation] SiC系セラミックプレカーサーとしてのケイ素系ポリマーブレンドの放射線酸化2008

    • Author(s)
      出崎亮
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      小倉(福岡県)
    • Related Report
      2008 Annual Research Report
  • [Presentation] イオン照射による機能性セラミック・ナノファイバーの合成2008

    • Author(s)
      杉本雅樹
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      小倉(福岡県)
    • Related Report
      2008 Annual Research Report
  • [Presentation] セラミック前駆体高分子薄膜へのイオン照射効果2008

    • Author(s)
      杉本雅樹
    • Organizer
      第3回高崎量子応用研究シンポジウム
    • Place of Presentation
      高崎(群馬県)
    • Related Report
      2008 Annual Research Report
  • [Presentation] イオン照射による自立セラミヅク・ナノファイバーの合成2008

    • Author(s)
      杉本 雅樹, 吉川 正人, 渡辺 省吾, 関 修平
    • Organizer
      日本セラミックス協会2008年年会
    • Place of Presentation
      長岡
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Ceramic Nano fiber from Precursor Polymers by Ion Beam Irradiation2007

    • Author(s)
      M. Sugimoto, M. Yoshikawa, S. Tukuda、S. Seki
    • Organizer
      第18回日本MRS学術シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2009 Final Research Report
  • [Presentation] 単一の粒子による高分子の3次元ナノ構造制御性2007

    • Author(s)
      関修平、田川精一、杉本雅樹
    • Organizer
      高分子学会第56回高分子討論会
    • Place of Presentation
      愛知・名古屋大学
    • Related Report
      2009 Final Research Report
  • [Presentation] イオンビームにより合成されるセラミックナノワイヤーの形態制御2007

    • Author(s)
      杉本 雅樹, 吉川 正人, 佃 諭志, 関 修平, 田川 精一
    • Organizer
      日本セラミックス協会
    • Place of Presentation
      名古屋
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Ceramic Nano fiber from Precursor Polymers by lon Beam Irradiation2007

    • Author(s)
      Masaki Sugimoto, Masahito Yoshikawa, Satoshi Tukudal, Shu Seki
    • Organizer
      第18回日本MRS学術シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 単一の粒子による高分子の3次元ナノ構造制御性2007

    • Author(s)
      関 修平, 田川 精一, 杉本 雅樹
    • Organizer
      高分子学会第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Remarks]

    • URL

      http://www.taka.jaea.go.jp/eimr_div/AdvCeram/index_j.html

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~cmpc-lab/

    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] ケイ素系ポリマーから高収率で炭化ケイ素材料を合成する方法2009

    • Inventor(s)
      出崎亮、杉本雅樹、田中陵二、吉川正人
    • Industrial Property Rights Holder
      日本原子力研究開発機構
    • Industrial Property Number
      2009-046288
    • Filing Date
      2009-02-27
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] ケイ素系ポリマーから高収率で炭化ケイ素材料を合成する方法2009

    • Inventor(s)
      出崎亮, 他
    • Industrial Property Rights Holder
      日本原子力研究開発機構
    • Industrial Property Number
      2009-046288
    • Filing Date
      2009-02-27
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] ナノファイバー及びその製造法2008

    • Inventor(s)
      杉本雅樹、出崎亮、吉川正人、関修平、渡辺省伍
    • Industrial Property Rights Holder
      日本原子力研究開発機構
    • Industrial Property Number
      2008-236572
    • Filing Date
      2008-09-16
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] ナノファイバー及びその製造法2008

    • Inventor(s)
      杉本雅樹, 他
    • Industrial Property Rights Holder
      日本原子力研究開発機構、大阪大学
    • Industrial Property Number
      2008-236572
    • Filing Date
      2008-09-16
    • Related Report
      2008 Annual Research Report

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Published: 2007-04-01   Modified: 2016-04-21  

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